MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Product name Synonym(s) P/N CAS # Product Use Manufacturer 1. Product and Company Identification Gumout Battery Protector & Sealer Mixture Coating ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON L7G 0C6 CA Phone: Emergency Telephone: Hazards Identification Emergency overview DANGER Extremely Flammable Aerosol. Contents under pressure. Containers may explode when heated. CAUSES EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CONTAINS MATERIAL WHICH MAY CAUSE CANCER. Contains a potential teratogen. Potential short term health effects Routes of exposure Eyes Skin Ingestion Target organs Chronic effects Signs and symptoms Eye, Skin contact,, Ingestion. Causes irritation. May cause irritation. Potential environmental effects See section 12. May cause respiratory irritation. Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Not a normal route of exposure. May cause stomach distress, nausea or vomiting. Eyes. Skin. Respiratory system. Lungs. Liver. Kidney. Brain. Central nervous system. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, oedema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. This material can enter the lungs during swallowing or vomiting and cause lung inflammation and /or damage. Aspiration into the lungs can cause pneumonia which can be fatal. 3. Composition/Information on Ingredients Components CAS # Percent Acetone Propane Xylene Distillates (petroleum), light hydrotreated Oil, mineral Ethylbenzene < < <5 #25161 Page: 1 of 8

2 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Immediately flush with cool water for 15 minutes while removing contaminated clothing and shoes. Discard or wash well before reuse. Obtain medical attention if irritation persists. If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Flammable by WHMIS criteria. Containers may explode when heated. Flammable aerosol by flame projection test. Foam. Carbon dioxide. Dry chemical. Contents under pressure. Pressurised container may explode when exposed to heat or flame. Cool containers with flooding quantities of water until well after fire is out. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Prevent further leakage or spillage if safe to do so. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Prevent entry into waterways, sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Remove sources of ignition. Although the chance of a significant spill or leak is unlikely in aerosol containers, in the event of such an occurrence, absorb spilled material with a non-flammable absorbent such as sand or vermiculite. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. #25161 Page: 2 of 8

3 7. Handling and Storage Handling Storage Pressurised container: Do not pierce or burn, even after use. Avoid contact with eyes. Avoid contact with skin and clothing. Avoid breathing vapours or mists of this product. Use only with adequate ventilation. Use good industrial hygiene practices in handling this material. Wash thoroughly after handling. When using, do not eat, drink or smoke. Keep away from heat, sparks, and flame. Do not expose to temperatures exceeding 122 F (50 C). Protect from sunlight. Store in a closed container away from incompatible materials. Keep out of reach of children. 8. Exposure Controls/Personal Protection Occupational exposure limits ACGIH Biological Exposure Indices Components Ethylbenzene (CAS ) US. ACGIH Threshold Limit Values Components Ethylbenzene (CAS ) Oil, mineral (CAS ) Exposure limits Engineering controls Personal protective equipment Eye/Face protection Hand protection Type BEI BEI BEI Type STEL TWA TWA Value 50 mg/l 0.7 g/g 1.5 g/g Value 750 ppm 500 ppm 20 ppm Form TWA 5 mg/m3 Inhalable fraction. STEL TWA 150 ppm 100 ppm Chemicals listed in section 3 that are not listed here do not have established limit values for ACGIH. General ventilation normally adequate. Wear safety glasses with side shields. Rubber gloves. Confirm with a reputable supplier first. Neoprene or Nitrile Protective gloves are recommended. Skin and body protection As required by employer code. Respiratory protection General hygiene considerations Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practices. When using do not eat or drink. 9. Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Aerosol Purple Aerosol. Solvent Liquid. Not applicable > 38 C (> F) #25161 Page: 3 of 8

4 Pour point Evaporation rate > 1 Flash point Auto-ignition temperature Flammability Limits in Air, Upper, % by Volume Flammability Limits in Air, Lower, % by Volume Heat of combustion Vapour pressure Vapour density Flame Projection: >15cm, <100cm 12.8 % 1 % Specific gravity 0.83 Partition coefficient (n-octanol/water) Solubility (Water) Relative density Viscosity VOC Percent volatile 10. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products This product may react with strong oxidising agents. Hazardous polymerisation does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Aerosol containers are unstable at temperatures above 49 C (120.2 F). Extremes of temperature and direct sunlight. Heat, open flames, static discharge, sparks and other ignition sources. Strong oxidising agents. May include and are not limited to: Oxides of carbon. 11. Toxicological Information Toxicological data Components LD50 LD50 Species Rabbit Mouse Rat Human Mouse Rabbit Rat mg/kg 20 ml/kg mg/m3/4h 76 mg/l, 4 Hours 50.1 mg/l, 8 Hours 39 mg/l/4h 2857 mg/kg 3000 mg/kg 5340 mg/kg 5800 mg/kg #25161 Page: 4 of 8

5 Components Species Distillates (petroleum), light hydrotreated (CAS ) LD50 Rabbit Rat LD50 Rat Ethylbenzene (CAS ) LD50 Rabbit Rat LD50 Rat Oil, mineral (CAS ) LD50 Rat LD50 Rat Rat Propane (CAS ) LD50 Rat LD50 LD50 Rabbit Mouse Rat LD50 Mouse > 2000 mg/kg > 2.8 mg/l/4h > 5000 mg/kg mg/kg 4000 ppm, 4 Hours 5460 mg/kg 3500 mg/kg > 2000 mg/kg 5000 mg/kg > 2.2 mg/l, 4 Hours > mg/l, 15 Minutes >= 1700 mg/kg 3907 ppm, 6 Hours 6350 ppm, 4 Hours 29.1 mg/l, 4 Hours 27.6 mg/l, 4 Hours 21.7 mg/l, 4 Hours 5251 ml/kg 1590 mg/kg #25161 Page: 5 of 8

6 Components Species Rat mg/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitisation Chronic effects Carcinogenicity ACGIH Carcinogens Ethylbenzene (CAS ) Causes irritation. May cause irritation. May cause respiratory irritation. Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effects (headache, dizziness). Not a normal route of exposure. May cause stomach distress, nausea or vomiting. Non-hazardous by WHMIS criteria. Non-hazardous by WHMIS criteria. See below. Oil, mineral (CAS ) IARC Monographs. Overall Evaluation of Carcinogenicity Mutagenicity Ethylbenzene (CAS ) Oil, mineral (CAS ) Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Non-hazardous by WHMIS criteria. Non-hazardous by WHMIS criteria. A4 Not classifiable as a human carcinogen. A3 Confirmed animal carcinogen with unknown relevance to humans. A4 Not classifiable as a human carcinogen. A4 Not classifiable as a human carcinogen. Volume 77-2B Possibly carcinogenic to humans. Volume 33, Supplement 7-3 Not classifiable as to carcinogenicity to humans. Volume 47, Volume 71-3 Not classifiable as to carcinogenicity to humans. Xylene is considered fetotoxic in humans, based on observations of reduced fetal weight, delayed ossification and persistent behavioural effects in animal studies in the absence of maternal toxicity. 12. Ecological Information Ecotoxicity Ecotoxicological data Components Crustacea Aquatic Crustacea Fish See below EC50 EC50 Species Daphnia Distillates (petroleum), light hydrotreated (CAS ) Aquatic Fish Ethylbenzene (CAS ) Algae Crustacea Aquatic Crustacea Fish IC50 EC50 EC50 Water flea (Daphnia magna) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Rainbow trout,donaldson trout (Oncorhynchus mykiss) Algae Daphnia Water flea (Daphnia magna) Fathead minnow (Pimephales promelas) mg/l, 48 Hours mg/l, 48 hours mg/l, 96 hours 2.9 mg/l, 96 hours 4.6 mg/l, 72 Hours 2.1 mg/l, 48 Hours mg/l, 48 hours mg/l, 96 hours #25161 Page: 6 of 8

7 Components Aquatic Fish Species Bluegill (Lepomis macrochirus) mg/l, 96 hours Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Acetone Ethylbenzene 3.15 Propane 2.36 Xylene Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. 14. Transport Information Transportation of Dangerous Goods (TDG- Canada) Basic shipping requirements: UN number UN1950 Proper shipping name Aerosols, flammable Hazard class Limited Quantity - Canada Special provisions 80 TDG Canadian federal regulations 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number Distillates (petroleum), light hydrotreated (CAS ) Oil, mineral (CAS ) Propane (CAS ) Canada WHMIS Ingredient Disclosure: Threshold limits WHMIS status 1 TONNES 1 TONNES 1 TONNES 1 TONNES 1 % Ethylbenzene (CAS ) 0.1 % Oil, mineral (CAS ) 1 % WHMIS Classification Controlled Class B - Division 5; Flammable Aerosol, Class D - Division 2A, 2B #25161 Page: 7 of 8

8 WHMIS labeling Inventory status Country(s) or region Inventory Name On Inventory (Yes/No)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No *A"Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION * X Disclaimer Issue date Effective date Expiry Date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 09-September September September-2017 Prepared by Dell Tech Laboratories Ltd. Phone: (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. This MSDS conforms to the ANSI Z400.1/Z Standard. #25161 Page: 8 of 8