1. Substance/preparation and manufacturer/supplier identification

Transcription

1 Safety data sheet Page: 1/9 1. Substance/preparation and manufacturer/supplier identification Paliogen Blue L 6385 Use: Colorants for the Paints, lacquers and varnishes industry Manufacturer/supplier: BASF Vietnam Co. Ltd. 12 Tu do Boulevard, Vietnam-Singapore IP Thuan An, Binh Duong, VIETNAM Telephone: Telefax number: address: dinhnam.nguyen@basf.com Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Acute toxicity: Cat. 5 (Inhalation - dust) Label elements and precautionary statement: Signal Word: Warning Hazard Statement: May be harmful if inhaled. Precautionary Statements (Response): IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.

2 Page: 2/9 Other hazards which do not result in classification: The product is under certain conditions capable of dust explosion. 3. Composition/information on ingredients Chemical nature indanthrone pigment C.I. Pigment Blue 60 Hazardous ingredients 5,9,14,18-Anthrazinetetrone, 6,15-dihydro- Content (W/W): >= 75 % - <= 100 % CAS Number: Acute Tox.: Cat. 5 (Inhalation - dust) 4. First-Aid Measures General advice: Remove contaminated clothing. If inhaled: If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. On ingestion: Rinse mouth and then drink plenty of water. Note to physician: Symptoms: No significant reaction of the human body to the product known. Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Unsuitable extinguishing media for safety reasons: carbon dioxide Additional information: Avoid whirling up the material/product because of the danger of dust explosion.

3 Page: 3/9 Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Avoid dust formation. Use personal protective clothing. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For small amounts: Pick up with suitable appliance and dispose of. For large amounts: Contain with dust binding material and dispose of. Avoid raising dust. 7. Handling and Storage Handling Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Avoid dust formation. Take precautionary measures against static discharges. Storage Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. 8. Exposure controls and personal protection Components with occupational exposure limits Barium sulfate, ; TWA value 5 mg/m3 (ACGIHTLV), Inhalable fraction The value is for particulate matter containing no asbestos and <1% crystalline silica.

4 Page: 4/9 Personal protective equipment Respiratory protection: Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2) Hand protection: See section 8 General safety and hygiene measures Eye protection: Safety glasses with side-shields. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. In order to prevent contamination while handling, closed working clothes and working gloves should be used. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: powder blue odourless ph value: 6-9 (50 g/l, 20 C) (DIN EN ISO 787-9) Melting temperature: > 300 C (1,013 hpa) Boiling point: not determined Flash point: Evaporation rate: The product is a non-volatile solid. Flammability (solid/gas): not highly flammable not highly flammable Lower explosion limit: (Regulation 440/2008/EC, A.10) For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Ignition temperature: > 500 C (VDI 2263, sheet 1, 2.6) Thermal decomposition: Not a substance liable to selfdecomposition according to UN transport regulations, class 4.1.

5 Page: 5/9 Self ignition: Temperature: 220 C No self ignition was observed up to the specified temperature. (Method: VDI 2263, sheet 1, 1.4.1) Self heating ability: It is not a substance capable of spontaneous heating according to UN transport regulations class 4.2. (VDI 2263, sheet 1, 1.4.1) Explosion hazard: not explosive Fire promoting properties: not fire-propagating Density: approx g/cm3 (20 C) Relative density: approx Bulk density: approx. 140 kg/m3 Relative vapour density (air): (pyknometer) Solubility in water: insoluble Solubility (quantitative) : insoluble Partitioning coefficient n-octanol/water (log Pow): Study does not need to be conducted. Viscosity, dynamic: Solids content: >= 98.5 g/l (DIN EN ISO 787-2) Molar mass: g/mol 10. Stability and Reactivity Conditions to avoid: Avoid dust formation. Avoid deposition of dust. Avoid sources of ignition. Thermal decomposition: Not a substance liable to self-decomposition according to UN transport regulations, class 4.1. Substances to avoid: No substances known that should be avoided. Hazardous reactions: Dust explosion hazard. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information

6 Page: 6/9 Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Experimental/calculated data: LD50 rat (oral): > 5,000 mg/kg LC50 rat (by inhalation): > 5.5 mg/l 4 h (OECD Guideline 403) The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Tested as dust aerosol. LD50 rat (dermal): > 1,050 mg/kg (OECD Guideline 402) No mortality was observed. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. The product has not been tested. The statement has been derived from the properties of the Germ cell mutagenicity Assessment of mutagenicity: No mutagenic effect was found in various tests with bacteria and mammalian cell culture. The product has not been tested. The statement has been derived from the properties of the individual components. Carcinogenicity Assessment of carcinogenicity: Results from poorly documented long-term studies in rats gave no indication of a carcinogenic potential. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Reproductive toxicity Assessment of reproduction toxicity:

7 Page: 7/9 The results of animal studies gave no indication of a fertility impairing effect. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Developmental toxicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Remarks: The product has not been tested. The statement has been derived from the properties of the Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No substance-specific organtoxicity was observed after repeated administration to animals. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. Aspiration hazard 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: There is a high probability that the product is not acutely harmful to aquatic organisms. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. Toxicity to fish: LC50 (96 h) > 100 mg/l, Leuciscus idus Aquatic invertebrates: EC50 (48 h), Daphnia magna (OECD Guideline 202, part 1) No toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from the properties of the

8 Page: 8/9 Aquatic plants: EC50 (72 h) (growth rate), Scenedesmus subspicatus (OECD Guideline 201) No toxic effects occur within the range of solubility. The product has not been tested. The statement has been derived from the properties of the Microorganisms/Effect on activated sludge: EC50 (0.5 h) > 100 mg/l, activated sludge Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available. Mobility Assessment transport between environmental compartments: The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is not expected. The ecological data given are those of the active ingredient. Persistence and degradability Elimination information: % colour reduction (Static test) (activated sludge) Easily eliminated from water. Bioaccumulation potential Assessment bioaccumulation potential: The product will not be readily bioavailable due to its consistency and insolubility in water. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations

9 Page: 9/9 Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Other regulations 16. Other Information Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.