Safety Data Sheet Murin Forte Block

Transcription

1 dated 11/2/2016, version 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Authorization of Ministry of Health n : Italian Ministry of health n IT/2013/000185/AUT 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use: rodenticide Uses advised against: All uses not listed in the Recommended uses 1.3. Details of the supplier of the safety data sheet Company: VEBI Istituto Biochimico Srl Via Desman, Borgoricco (PD) - Italy 1.4. Emergency telephone number Antipoison Center - Centro Antiveleni di Milano (Ospedale Niguarda) VEBI ISTITUTO BIOCHIMICO customer assistance: Tel :00-12:00-13:00-17:00 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture EC regulation criteria 1272/2008 (CLP) The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements The product is not classified as dangerous according to Regulation EC 1272/2008 (CLP). Symbols: Hazard statements: Precautionary statements: P102 Keep out of reach of children. P103 Read label before use. P270 Do no eat, drink or smoke when using this product. P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/... P501 Dispose of contents in accordance with national regulation. Special Provisions: Special provisions according to Annex XVII of REACH and subsequent amendments: Page n. 1 of 9

2 2.3. Other hazards vpvb Substances: - PBT Substances: Other Hazards: No other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Hazardous components within the meaning of the CLP regulation and related classification: Qty Name Ident. Number Classification 50 ppm Bromadiolone CAS: /1/Dermal Acute Tox. 1 EC: H /1/Inhal Acute Tox. 1 H /1 STOT RE 1 H /A1 Aquatic Acute 1 H /C1 Aquatic Chronic 1 H ppm Denantonium Benzoate CAS: EC: /1/Oral Acute Tox. 1 H /4/Oral Acute Tox. 4 H /2 Skin Irrit. 2 H /2 Eye Irrit. 2 H /3 STOT SE 3 H335 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Wash with plenty of water and soap. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. In case of Inhalation: Remove casualty to fresh air and keep warm and at rest Most important symptoms and effects, both acute and delayed Active ingredient is a so-called second generation anticoagulant rodenticide, which like other Coumarin derivatives, is a vitamin K antagonist. It disrupts the normal blood clotting mechanisms resulting in profuse internal haemorrhage and death. - Harmful to skin contact; could be absorbed and cause internal hemorrhage. - Harmful if swallowed; serious risk of internal hemorrhage - Harmful if inhaled; serious risk of internal hemorrhage - Soil and water could be contaminated. - Symptoms may be associated to increased bleeding tendency. Page n. 2 of 9

3 4.3. Indication of any immediate medical attention and special treatment needed Treatment: The anticoagulant rodenticide active substances work by blocking the regeneration of vitamin K 2,3-epoxide to vitamin K hydroquinone. Since, the amount of vitamin K in the body is finite, the progressive block of the regeneration of vitamin K will lead to an increasing probability of a fatal hemorrhage. 1.To check the prothrombinic activity many times, also after a few days, particularly if the quantity swallowed is high. Diagnosis: changes in prothrombin time (symptoms and clotting tests) 2.Treatment: vitamin K1. 3. In animals and particularly in pets, vitamin K1 can be given even in absence of alterations of the coagulation, because of the gravity of the hemorrhage which can appear in case of ingestion. Other Medical data: No significant effects caused by active ingredient in personnel with occupational exposure have been observed. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: in particular Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke Advice for firefighters Use suitable breathing apparatus. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove all sources of ignition. Remove persons to safety. See protective measures under point 7 and Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand 6.3. Methods and material for containment and cleaning up Wash with plenty of water. Page n. 3 of 9

4 6.4. Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhaltion of vapours and mists. Do not eat or drink while working. See also section 8 for recommended protective equipment Conditions for safe storage, including any incompatibilities Avoid temperatures > 50 C Avoid light and sunlight exposure Keep away from food, drink and feed. Incompatible materials: in particular. Instructions as regards storage premises: Adequately ventilated premises Specific end use(s) in particular SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values PNEC Exposure Limit Values 8.2. Exposure controls Eye protection: Not needed for normal use. Anyway, operate according good working practices. Protection for skin: No special precaution must be adopted for normal use. Protection for hands: Butyl caoutchouc (butyl rubber). Respiratory protection: Not needed for normal use. Thermal Hazards: Environmental exposure controls: Appropriate engineering controls: SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Properties Value Method: Notes Appearance and colour: Red solid Odour: butter Odour threshold: Not Relevant ph: Page n. 4 of 9

5 Melting point / freezing point: Initial boiling point and boiling range: Flash point: Evaporation rate: Not Relevant Solid/gas flammability: Not flammable Upper/lower flammability Not Relevant or explosive limits: Vapour pressure: Not Relevant Vapour density: Not Relevant Relative density: g/ml Solubility in water: Non soluble Solubility in oil: Not soluble Partition coefficient Not Relevant (n-octanol/water): Auto-ignition temperature: >200 C Decomposition temperature: Viscosity: Not Relevant Explosive properties: Not explosive Oxidizing properties: Not oxidant Other information Properties Value Method: Notes Miscibility: Not Relevant Fat Solubility: Not Relevant Conductivity: Not Relevant Not Relevant SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability The product is stable for 2 years Possibility of hazardous reactions Conditions to avoid Stable under normal conditions Incompatible materials in particular Hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Toxicological information of the mixture: Page n. 5 of 9

6 a) acute toxicity: Test: LD50 - Route: Skin - Species: Rat > 2000 mg/kg b) skin corrosion/irritation: Test: Skin Irritant - Route: Skin - Species: Rabbit Negative c) serious eye damage/irritation: Test: Eye Irritant - Species: Rabbit Negative d) respiratory or skin sensitisation: Test: Skin Sensitization - Route: Skin - Species: vebi1 Negative Toxicological information of the main substances found in the mixture: Bromadiolone - CAS: a) acute toxicity: Test: LD50 - Route: Oral - Species: Rat = 1.31 mg/kg Test: LD50 - Route: Skin - Species: Rat = 8.1 mg/kg Test: LC50 - Route: Inhalation - Species: Rat = ml/l c) serious eye damage/irritation: Test: Eye Corrosive - Species: Rabbit Negative Denantonium Benzoate - CAS: a) acute toxicity: Test: LD50 - Route: Oral - Species: Rat = 584 mg/kg If not differently specified, the information required in Regulation (EU)2015/830 listed below must be considered as : a) acute toxicity; b) skin corrosion/irritation; c) serious eye damage/irritation; d) respiratory or skin sensitisation; e) germ cell mutagenicity; f) carcinogenicity; g) reproductive toxicity; h) STOT-single exposure; i) STOT-repeated exposure; j) aspiration hazard. SECTION 12: Ecological information Toxicity Adopt good working practices, so that the product is not released into the environment. Bromadiolone - CAS: a) Aquatic acute toxicity: Endpoint: EC50 - Species: Daphnia = 5.79 mg/l - Duration h: 48 - Notes: Daphnia magna Endpoint: LC50 - Species: Fish = 2.86 mg/l - Duration h: 96 - Notes: Oncorhynchus mykiss Endpoint: EC50 - Species: Algae = 1.14 mg/l - Duration h: 72 - Notes: Pseudokirchneriella subcapitata d) Terrestrial toxicity: Endpoint: LC50 = 918 mg/l - Notes: Eisenia fetida 13d f) Effects in sewage plants: Endpoint: EC50 = mg/l - Duration h: Persistence and degradability Bioaccumulative potential Page n. 6 of 9

7 12.4. Mobility in soil Results of PBT and vpvb assessment vpvb Substances: - PBT Substances: Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force. SECTION 14: Transport information UN number Not classified as dangerous in the meaning of transport regulations UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Marine pollutant: No Special precautions for user Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013 Regulation (EU) 2015/830 Regulation (EU) n. 286/2011 (ATP 2 CLP) Regulation (EU) n. 618/2012 (ATP 3 CLP) Regulation (EU) n. 487/2013 (ATP 4 CLP) Regulation (EU) n. 944/2013 (ATP 5 CLP) Regulation (EU) n. 605/2014 (ATP 6 CLP) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Restrictions related to the product: Page n. 7 of 9

8 No restriction. Restrictions related to the substances contained: No restriction. Where applicable, refer to the following regulatory provisions : Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II): WGK Classification (Water hazard class ) WGK3 - Highly hazardous for water Chemical safety assessment No SECTION 16: Other information Full text of phrases referred to in Section 3: H310 Fatal in contact with skin. H330 Fatal if inhaled. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H300 Fatal if swallowed. H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU. This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. ADR: CAS: CLP: DNEL: EINECS: GefStoffVO: GHS: European Agreement concerning the International Carriage of Dangerous Goods by Road. Chemical Abstracts Service (division of the American Chemical Society). Classification, Labeling, Packaging. Derived No Effect Level. European Inventory of Existing Commercial Chemical Substances. Ordinance on Hazardous Substances, Germany. Globally Harmonized System of Classification and Labeling of Page n. 8 of 9

9 IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: Chemicals. International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients. Explosion coefficient. Lethal concentration, for 50 percent of test population. Lethal dose, for 50 percent of test population. Long-term exposure. Predicted No Effect Concentration. Regulation Concerning the International Transport of Dangerous Goods by Rail. Short-term exposure. Short Term Exposure limit. Specific Target Organ Toxicity. Threshold Limiting Value. Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). German Water Hazard Class. Page n. 9 of 9