Risalah Data Keselamatan Safety data sheet

Transcription

1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/22 1. Pengenalan bahan kimia dan pembekal Efka IO 6780 Kegunaan: bahan kimia industri Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Cecair mudah terbakar: Kat. 3 Ketoksikan akut: Kat. 4 (oral) Kakisan/kerengsaan kulit: Kat. 1B Kerengsaan mata/ kerosakan mata yang serius: Kat. 1 Pendedahan tunggal STOT: Kat. 3 (Wap boleh menyebabkan rasa mengantuk dan pening.) Bahaya akut kepada persekitaran akuatik: Kat. 1 Unsur label dan pernyataan berjaga-jaga: Piktogram:

2 Mukasurat (Page): 2/22 Kata Isyarat: bahaya Pernyataan Bahaya: Cecair dan wap mudah terbakar. Memudaratkan jika tertelan. Boleh menyebabkan rasa mengantuk atau pening. Menyebabkan luka terbakar pada kulit dan kerosakan mata yang teruk. Sangat toksik kepada hidupan akuatik. Pernyataan Berjaga-jaga (Pencegahan): Pakai sarung tangan pelindung/ pakaian pelindunga/perlindungan mata/perlindungan muka. Elakkan pelepasan bahan ke persekitaran. Gunakan hanya di luar bangunan atau di dalam kawasan yang dialihudarakan dengan baik. Jauhkan daripada haba/percikan api/nyalaan terbuka/permukaan panas. Dilarang merokok. Ambil langkah berjaga-jaga terhadap nyahcas statik. Jangan bernafaskan habuk/gas/kabut/wap. Gunakan kelengkapan elektrik/pengalihudaraan/pencahayaan yang tahan letupan. Basuh bersih-bersih selepas mengendalikan bahan. Jangan makan, minum atau merokok semasa menggunakan produk ini. Gunakan hanya alat yang tidak mengeluarkan percikan api. Bumikan/ikat bekas dan kelengkapan terimaan. Pernyataan Berjaga-jaga (Tindak Balas): Segera hubungi PUSAT RACUN atau doktor/pakar perubatan. JIKA TERKENA MATA: Bilas berhatihati dengan air selama beberapa minit.tanggalkan kanta lekap, jika ada dan dapat dilakukan dengan mudah. Teruskan membilas. JIKA TERKENA KULIT (atau rambut): Tanggalkan segera semua pakaian yang tercemar. Basuh dengan sabun dan air yang banyak. JIKA TERSEDUT: Pindahkan mangsa ke kawasan berudara segar dan pastikan mangsa selesa bernafas. JIKA TERKENA KULIT (atau rambut): Segera tanggalkan/buka semua pakaian yang tercemar. Basuh kulit dengan air/ pancuran air. JIKA TERTELAN: bilas mulut. JANGAN paksa mangsa muntah. JIKA DITELAH: bilas mulut. Pungut tumpahan. Jika berlaku kebakaran: Gunakan busa atau serbuk kering untuk memadam kebakaran. Pernyataan Berjaga-jaga (Penyimpanan): Simpan di tempat yang dialihudarakan dengan baik. Simpan di tempat sejuk Pastikan bekas ditutup dengan ketat. Simpan di tempat berkunci. Pernyataan Berjaga-jaga (Pelupusan): Lupuskan kandungan/ bekas ke tempat pengumpulan sisa berbahaya atau khusus. Bahaya lain yang tidak menyebabkan pengelasan: Tiada bahaya khusus yang diketahui jika peraturan/nota tentang penyimpanan dan pengendalian diberikan perhatian. 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Larutan berdasarkan : bahan tambah, pelarut

3 Mukasurat (Page): 3/22 Ramuan berbahaya Dodecylethyldimethylammonium ethyl sulphate Kandungan (berat/berat): >= 80 % - <= 85 % Nombor CAS: Acute Tox.: Kat. 4 (oral) Skin Corr./Irrit.: Kat. 1B Eye Dam./Irrit.: Kat. 1 Aquatic Acute: Kat. 1 n-butanol Kandungan (berat/berat): >= 15 % - <= 20 % Nombor CAS: Flam. Liq.: Kat. 3 Skin Corr./Irrit.: Kat. 2 Eye Dam./Irrit.: Kat. 1 STOT SE: Kat. 3 (drowsiness and dizziness) STOT SE: Kat. 3 (irr. to respiratory syst.) Bagi pengelasan yang tidak ditulis dengan penuh dalam bahagian ini, teks lengkap boleh didapati di bahagian Langkah-Langkah Pertolongan Cemas Nasihat am: Segera tanggalkan pakaian yang tercemar. Jika pesakit mungkin akan tidak sedarkan diri, pastikan pesakit dalam keadaan mengiring (kedudukan pemulihan) dan pindahkan pesakit. Kakitangan bantuan kecemasan hendaklah memberikan perhatian kepada keselamatan mereka sendiri. Jika tersedut: Jika kesukaran berlaku selepas tersedut wap/aerosol, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan. Apabila terkena kulit: Segera basuh bersih-bersih dengan air yang banyak, gunakan balutan steril, rujuk pakar kulit. Apabila terkena mata: Segera basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air dengan membuka mata, rujuk pakar mata. Apabila tertelan: Segera basuh mulut dan kemudian minum banyak air, jangan paksa mangsa muntah, dapatkan rawatan perubatan. Nota kepada doktor: Gejala: Gejala dan kesan terpenting yang diketahui diterangkan didalam label (lihat bahagian 2) dan/atau bahagian 11., Gejala dan kesan penting selanjutnya tidak diketahui setakat ini. Nota kepada doktor: Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui.

4 Mukasurat (Page): 4/22 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: serbuk kering, busa Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap. Maklumat lanjut: Tahap risiko ditentukan oleh bahan yang terbakar dan keadaan kebakaran. Air pemadam api yang tercemar mestilah dilupuskan mengikut peraturan rasmi. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Perlindungan pernafasan diperlukan. Langkah berjaga-jaga untuk alam sekitar: Bendung air yang tercemar/air yang digunakan untuk memadam kebakaran. Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah besar: Pam produk. Bagi baki: Kutip dengan bahap penyerap yang sesuai. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Pastikan pengalihudaraan menyeluruh di kawasan simpanan dan di tempat kerja. Perlindungan terhadap kebakaran dan letupan: Jauhkan dari sumber pencucuhan. Ambil langkah berjaga-jaga terhadap luahan statik. Jika dihantar di dalam bungkusan plastik, suhu tertinggi yang dibenarkan semasa mengosongkannya ialah 5 Kelvin di bawah takat kilat. Penyimpanan Maklumat lanjut tentang keadaan penyimpanan: Simpan di tempat dingin. Pastikan bekas sentiasa bertutup rapat.

5 Mukasurat (Page): 5/22 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja n-butanol, ; Nilai TWA 20 ppm (ACGIHTLV) CLV 152 mg/m3 ; 50 ppm (OEL (Peraturan USECHH Malaysia)) Nama kulit (OEL (Peraturan USECHH Malaysia)) Bahan boleh diserap melalui kulit. Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan yang sesuai bagi kepekatan yang tinggi atau kesan jangka panjang: Penapis gas bagi gas/wap sebatian organik (takat didih >65 C, cth EN Jenis A) Perlindungan tangan: Sarung tangan keselamatan kalis bahan kimia. Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): getah nitril (NBR) mm ketebalan salutan Nota tambahan : Spesifikasi adalah berdasarkan ujian ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian. Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai. Perlindungan mata: Gogal keselamatan yang betul-betul muat (cth gogal tertutup) (EN 166) dan pelindung muka Perlindungan badan: Perlindungan badan mestilah dipilih berdasarkan tahap aktiviti dan pendedahan., alat pernafasan asid. Apron kalis lai, contohnya getah (cth. menurut EN 14605), but pelindung, cth. getah (cth. menurut EN 20346), sut pelindung kimia (sebagai contoh menurut EN 14605) Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: cecair tidak berwarna hingga seperti kuning seperti alkohol Tidak ditentukan disebabkan oleh bahaya kesihatan yang mungkin melalui penyedutan. nilai ph: (1 %(m))

6 Mukasurat (Page): 6/22 takat beku: tidak ditentukan takat didih: C Takat kilat: 46 C (NFT 60103, cawan tertutup) Tahap penyejatan: tidak ditentukan Kemudahbakaran (pepejal/gas): Had letupan bawah: 1.5 %(V) Had letupan atas: 9.4 %(V) Suhu pencucuhan: 340 C Mudah terbakar. Penguraian terma: tidak ditentukan pencucuhan sendiri: Tidak swacucuh. Jenis ujian: Swanyalaan spontan pada suhu bilik. Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: 6.7 hpa (20 C) Kepekatan: 0.95 g/cm3 (20 C) Ketumpatan relatif: 0.95 (20 C) Ketumpatan wap relatif (udara): tidak ditentukan Keterlarutan dalam air: terlarut Higroskopi: Produk belum diuji. Pekali petakan n-oktanol/air (log Pow): tidak berkenaan untuk campuran Tegangan permukaan: Tiada data diperoleh. Kelikatan, dinamik: mpa.s (20 C) 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: tidak ditentukan Bahan yang perlu dielakkan: agen pengoksida yang kuat, bes kuat, asid kuat

7 Mukasurat (Page): 7/22 Tindak balas berbahaya: Tiada tindakbalas berbahaya jika disimpan dan dikendalikan seperti yang dinyatakan. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Data eksperimen/dikira: LD50 tikus (melalui mulut): > 500-2,000 mg/kg Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. LC50 tikus (melalui penyedutan): > 20 mg/l 4 h Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. LD50 tikus (dermal): > 5,000 mg/kg Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Kerengsaan Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: Mengakis Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Kerosakkan/kerengsaan mata yang serius arnab: kerosakan tak berbalik Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Pemekaan pernafasan/kulit Data eksperimen/dikira: marmut: Tidak memeka Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Kemutagenan sel germa Penilaian kemutagenan: Tiada data diperoleh tentang kesan mutagen. Maklumat tentang : n-butanol Penilaian kemutagenan: Bahan tidak mutagen dalam bakteria. Bahan tidak mutagen dalam kultur sel mamalia. Bahan tidak mutagen dalam kajian dengan mamalia Kekarsinogenan Penilaian kekarsinogenan: Tiada data diperoleh.

8 Mukasurat (Page): 8/22 Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Tiada data diperoleh. Maklumat tentang : n-butanol Penilaian ketoksikan pembiakan: Keputusan kajian haiwan tidak menunjukkan kesan gangguan kesuburan Ketoksikan perkembangan Penilaian keteratogenan: Tiada data diperoleh. Maklumat tentang : n-butanol Penilaian keteratogenan: Kajian haiwan tidak menunjukkan kesan yang menjejaskan kesuburan pada dos yang tidak toksik kepada haiwan induk Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Kemungkinan berlaku kesan narkotik (rasa mengantuk atau pening) Catatan: Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Tiada data diperoleh. Bahaya penyedutan Tiada bahaya penyedutan dijangka. 12. Maklumat Ekologi Keekotoksikan Ketoksikan kepada ikan: LC50 (96 h) > mg/l, Ikan Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Invertebrat air: EC50 (48 h) > mg/l, daphnia Produk belum diuji. Penyataan diambil daripada ciri setiap komponen.

9 Mukasurat (Page): 9/22 Tumbuhan akuatik: EC50 (72 h) > mg/l, alga Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC50 (0.5 h) > mg/l, bakteria Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Ketoksikan kronik kepada ikan: Tiada data diperoleh. Ketoksikan kronik kepada invertebrata akuatik: Tiada data diperoleh. Penilaian ketoksikan daratan: Tiada data didapati berkenaan dengan ketoksikan daratan. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Tiada data diperoleh. Keterusan dan boleh keterdegradasikan Penilaian biodegradasi dan penyingkiran (H2O): Terbiodegradasikan secara semula jadi Potensi Biotumpukan Penilaian potensi bioakumilasi: Produk belum diuji. Maklumat tambahan Perhatian tambahan bagi nasib pada alam sekitar & laluan: Rawatan didalam loji rawatan air sisa biologi mestilah dijalankan menurut peraturan dan pentadbiran setempat. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya. 14. Maklumat Pengangkutan Pengangkutan domestik: Kelas bahaya: 8

10 Mukasurat (Page): 10/22 Kumpulan pembungkusan: II Nombor-ID: UN 2920 Label Bahaya: 8, 3, EHSM Nama penghantaran yang betul: CECAIR MENGAKIS, MUDAH TERBAKAR, N.O.S. (mengandungi DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Maklumat lanjut Kod Hazchem:3W Nombor IERG:18 Pengangkutan laut IMDG Kelas bahaya: 8 Kumpulan pembungkusan: II Nombor-ID: UN 2920 Label Bahaya: 8, 3, EHSM Bahan pencemar laut: YA Nama penghantaran yang betul: CECAIR MENGAKIS, MUDAH TERBAKAR, N.O.S. (mengandungi DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Pengangkutan udara IATA/ICAO Kelas bahaya: 8 Kumpulan pembungkusan: II Nombor-ID: UN 2920 Label Bahaya: 8, 3 Nama penghantaran yang betul: CECAIR MENGAKIS, MUDAH TERBAKAR, N.O.S. (mengandungi DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Pengangkutan secara pukal menurut Lampiran II MARPOL73/78 dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan

11 Mukasurat (Page): 11/ Maklumat lain Disebabkan oleh penggabungan syarikat CIBA dengan kumpulan BASF semua Risalah Data Keselamatan telah disemak semula berdasarkan maklumat yang digabungkan. Ini mungkin menyebabkan perubahan kepada Risalah Data Keselamatan tersebut. Sekiranya anda mempunyai sebarang pertanyaan mengenai perubahan tersebut sila hubungi kami di alamat yang tertera di Bahagian I. Teks penuh pengelasan, simbol bahaya dan pernyataan bahaya, jika dinyatakan dalam seksyen 2 atau 3: Acute Tox. Skin Corr./Irrit. Eye Dam./Irrit. Aquatic Acute Flam. Liq. STOT SE Ketoksikan akut Kakisan/kerengsaan kulit Kerengsaan mata/ kerosakan mata yang serius Bahaya akut kepada persekitaran akuatik Cecair mudah terbakar Pendedahan tunggal STOT Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

12 Mukasurat (Page): 12/22 1. Identification of the chemical and of the supplier Efka IO 6780 Use: industrial chemicals Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Flammable liquids: Cat. 3 Acute toxicity: Cat. 4 (oral) Skin corrosion/irritation: Cat. 1B Serious eye damage/eye irritation: Cat. 1 Specific target organ toxicity single exposure: Cat. 3 (Vapours may cause drowsiness and dizziness.) Hazardous to the aquatic environment - acute: Cat. 1 Label elements and precautionary statement: Pictogram: Signal Word: Danger Hazard Statement: Flammable liquid and vapour. Harmful if swallowed. May cause drowsiness or dizziness. Causes severe skin burns and eye damage. Very toxic to aquatic life. Precautionary Statements (Prevention): Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Use only outdoors or in a well-ventilated area. Keep away from heat, hot surfaces,

13 Mukasurat (Page): 13/22 sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Do not breathe dust/gas/mist/vapours. Use explosion-proof electrical/ventilating/lighting/equipment. Wash with plenty of water and soap thoroughly after handling. Do not eat, drink or smoke when using this product. Use only non-sparking tools. Ground/bond container and receiving equipment. Precautionary Statements (Response): Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF SWALLOWED: rinse mouth. Collect spillage. In case of fire: Use foam or dry powder for extinction. Precautionary Statements (Storage): Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Solution based on: additives, solvent(s) Hazardous ingredients Dodecylethyldimethylammonium ethyl sulphate Content (W/W): >= 80 % - <= 85 % CAS Number: Acute Tox.: Cat. 4 (oral) Skin Corr./Irrit.: Cat. 1B Eye Dam./Irrit.: Cat. 1 Aquatic Acute: Cat. 1 n-butanol Content (W/W): >= 15 % - <= 20 % CAS Number: Flam. Liq.: Cat. 3 Skin Corr./Irrit.: Cat. 2 Eye Dam./Irrit.: Cat. 1 STOT SE: Cat. 3 (drowsiness and dizziness) STOT SE: Cat. 3 (irr. to respiratory syst.) For the classifications not written out in full in this section the full text can be found in section 16.

14 Mukasurat (Page): 14/22 4. First-Aid Measures General advice: Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). First aid personnel should pay attention to their own safety. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Note to physician: Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Note to physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Breathing protection required.

15 Mukasurat (Page): 15/22 Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. If delivered in plastic packing, highest permissable emptying temperature is 5 Kelvin below the flash point. Storage Further information on storage conditions: Keep container tightly closed and in a cool place. 8. Exposure controls and personal protection Components with occupational exposure limits n-butanol, ; TWA value 20 ppm (ACGIHTLV) CLV 152 mg/m3 ; 50 ppm (OEL (MY)) Skin Designation (OEL (MY)) The substance can be absorbed through the skin. Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.

16 Mukasurat (Page): 16/22 temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield. Body protection: Body protection must be chosen based on level of activity and exposure., acid- resp. lye-proof apron, e.g. of rubber (f.e. according to EN 14605), protection boots, f.e. of rubber (e.g. according to EN 20346), chemical-protection suit (f.e. according to EN 14605) General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: liquid colourless to slightly yellow alcohol-like Not determined due to potential health hazard by inhalation. ph value: (1 %(m)) Freezing point: not determined Boiling point: C Flash point: 46 C (NFT 60103, closed cup) Evaporation rate: not determined Flammability (solid/gas): Flammable. Lower explosion limit: 1.5 %(V) Upper explosion limit: 9.4 %(V) Ignition temperature: 340 C Thermal decomposition: not determined Self ignition: not self-igniting Test type: Spontaneous selfignition at room-temperature. Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: Density: 6.7 hpa (20 C) 0.95 g/cm3 (20 C)

17 Mukasurat (Page): 17/22 Relative density: 0.95 (20 C) Relative vapour density (air): not determined Solubility in water: soluble Hygroscopy: The product has not been tested. Partitioning coefficient n-octanol/water (log Pow): not applicable for mixtures Surface tension: No data available. Viscosity, dynamic: mpa.s (20 C) 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: not determined Substances to avoid: strong oxidizing agents, strong bases, strong acids Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Experimental/calculated data: LD50 rat (oral): > 500-2,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. LC50 rat (by inhalation): > 20 mg/l 4 h The product has not been tested. The statement has been derived from the properties of the individual components. LD50 rat (dermal): > 5,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. Irritation

18 Mukasurat (Page): 18/22 Experimental/calculated data: Skin corrosion/irritation rabbit: Corrosive. The product has not been tested. The statement has been derived from the properties of the individual components. Serious eye damage/irritation rabbit: irreversible damage The product has not been tested. The statement has been derived from the properties of the individual components. Respiratory/Skin sensitization Experimental/calculated data: guinea pig: Non-sensitizing. The product has not been tested. The statement has been derived from the properties of the individual components. Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Information on: n-butanol Assessment of mutagenicity: The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell culture. The substance was not mutagenic in studies with mammals Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: No data available. Information on: n-butanol Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect Developmental toxicity Assessment of teratogenicity: No data available. Information on: n-butanol Assessment of teratogenicity: Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals

19 Mukasurat (Page): 19/22 Specific target organ toxicity (single exposure): Assessment of STOT single: Possible narcotic effects (drowsiness or dizziness). Remarks: The product has not been tested. The statement has been derived from the properties of the individual components. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: No data available. Aspiration hazard No aspiration hazard expected. 12. Ecological Information Ecotoxicity Toxicity to fish: LC50 (96 h) > mg/l, Fish The product has not been tested. The statement has been derived from the properties of the individual components. Aquatic invertebrates: EC50 (48 h) > mg/l, daphnia The product has not been tested. The statement has been derived from the properties of the individual components. Aquatic plants: EC50 (72 h) > mg/l, algae The product has not been tested. The statement has been derived from the properties of the individual components. Microorganisms/Effect on activated sludge: EC50 (0.5 h) > mg/l, bacteria The product has not been tested. The statement has been derived from the properties of the individual components. Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity.

20 Mukasurat (Page): 20/22 Mobility Assessment transport between environmental compartments: No data available. Persistence and degradability Assessment biodegradation and elimination (H2O): Inherently biodegradable. Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. Additional information Add. remarks environm. fate & pathway: Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Hazard class: 8 Packing group: II ID number: UN 2920 Hazard label: 8, 3, EHSM Proper shipping name: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (contains DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Further information Hazchem Code:3W IERG Number:18 Sea transport IMDG Hazard class: 8

21 Mukasurat (Page): 21/22 Packing group: II ID number: UN 2920 Hazard label: 8, 3, EHSM Marine pollutant: YES Proper shipping name: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (contains DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Air transport IATA/ICAO Hazard class: 8 Packing group: II ID number: UN 2920 Hazard label: 8, 3 Proper shipping name: CORROSIVE LIQUID, FLAMMABLE, N.O.S. (contains DODECYLETHYLDIMETHYLAMMONIUM ETHYL SULPHATE, N- BUTANOL) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information 16. Other Information Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3: Acute Tox. Skin Corr./Irrit. Eye Dam./Irrit. Aquatic Acute Flam. Liq. STOT SE Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Hazardous to the aquatic environment - acute Flammable liquids Specific target organ toxicity single exposure Vertical lines in the left hand margin indicate an amendment from the previous version.

22 Mukasurat (Page): 22/22 The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.