Issuing Date 06-Jun-2011 Revision Date Revision Number 0 Section 1. Identification of the substance/mixture and of the company/undertaking

Transcription

1 SAFETY DATA SHEET Issuing Date 06-Jun-2011 Revision Number 0 Section 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Code(s) , , , , Product Name Rain-X Anti Fog 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Uses advised against For use on interior glass and mirrors 1.3. Details of the supplier of the safety data sheet Importer Kraco Car Care International Ltd. Grosvenor House 20 Barrington Road WA14 1HB Altrincham Cheshire United Kingdom TEL: +44 (0) For further information, please contact Address Supplier Kraco Car Care International Ltd. Grosvenor House 20 Barrington Road WA14 1HB Altrincham Cheshire, UK TEL: +44 (0) KCCI-orders@Kraco.com 1.4. Emergency telephone number Emergency Telephone Number Europe 112 Section 2. Hazards identification 2.1. Classification of the substance or mixture REGULATION (EC) No 1272/2008 Classification according to EU Directives 67/548/EEC or 1999/45/EC For the full text of the R-phrases mentioned in this Section, see Section 16 The preparation is classified as dangerous in accordance with Directive 1999/45/EC. Symbol(s) R-code(s) Xi - Irritant F - Highly flammable F;R11 - Xi;R36 - R Label Elements Page 1 / 9

2 Indication of danger Xi - Irritant F - Highly flammable R-phrase(s) R11 - Highly flammable R36 - Irritating to eyes R67 - Vapors may cause drowsiness and dizziness S-phrase(s) S 2 - Keep out of the reach of children S46 - If swallowed, seek medical advice immediately and show this container or label S 9 - Keep container in a well-ventilated place S16 - Keep away from sources of ignition - No smoking S33 - Take precautionary measures against static discharges 2.3. Other information 3.1. Substances Not applicable 3.2. Mixtures Section 3. Composition/information on ingredients Chemical Name EC-No CAS-No Weight % Classification EU - GHS Substance Classification F;R11 Xi;R36 R67 Flam. Liq. 2 (H225) STOT SE 3 (H336) Eye Irrit. 2 (H319) REACH No. For the full text of the R-phrases mentioned in this Section, see Section 16 For the full text of the H-Statements mentioned in this Section, see Section 16 Section 4. First aid measures 4.1. of first-aid measures General Advice Eye Contact Skin Contact Ingestion Inhalation Show this safety data sheet to the doctor in attendance. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Call a physician immediately. Wash off immediately with soap and plenty of water. If skin irritation persists, call a physician. Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. Move to fresh air in case of accidental inhalation of vapors. If symptoms persist, call a physician. Page 2 / 9

3 Protection of First-aiders Remove all sources of ignition Most important symptoms and effects, both acute and delayed Most Important Symptoms/Effects Drowsiness. Dizziness. Central nervous system depression Liver and kidney injuries may occur 4.3. Indication of immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Section 5. Fire-fighting measures 5.1. Extinguishing media Suitable Extinguishing Media CO2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons 5.2. Special hazards arising from the substance or mixture Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases Flammable. Keep product and empty container away from heat and sources of ignition. Will be easily ignited by heat, sparks or flames. Vapors may travel to source of ignition and flash back Advice for firefighters Special protective equipment for fire-fighters Wear self-contained breathing apparatus and protective suit Section 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. Ensure adequate ventilation. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Advice for emergency responders Ensure adequate ventilation For personal protection see section Environmental precautions Prevent further leakage or spillage if safe to do so. Prevent product from entering drains Methods and materials for containment and cleaning up Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labeled containers Reference to other sections See Section 12 for additional information. Section 7. Handling and storage 7.1. Precautions for Safe Handling Handling Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of ignition. Do not smoke. Avoid contact with skin, eyes and clothing. Hygiene Measures When using, do not eat, drink or smoke. Page 3 / 9

4 7.2. Conditions for safe storage, including any incompatibilities Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children Specific end use(s) Exposure Scenario Other Guidelines 8.1. Control parameters Exposure Limits Section 8. Exposure controls/personal protection Chemical Name EU The United Kingdom France Spain Germany VLCT: 400 ppm VLCT: 980 mg/m 3 STEL: 500 ppm STEL: 1250 mg/m 3 TWA: 400 ppm TWA: 999 mg/m 3 VLA-EC: 500 ppm VLA-EC: 1250 mg/m 3 VLA-ED: 400 ppm VLA-ED: 998 mg/m 3 MAK: 200 ppm MAK: 500 mg/m 3 Ceiling / Peak: 400 ppm Ceiling / Peak: 1000 mg/m 3 TWA: 500 mg/m 3 Chemical Name Italy Portugal The Netherlands Finland Denmark STEL: 400 ppm TWA: 500 mg/m 3 STEL: 250 ppm STEL: 620 mg/m 3 TWA: 490 mg/m 3 Chemical Name Austria Switzerland Poland Norway Ireland STEL 800 ppm STEL 2000 mg/m 3 MAK: 200 ppm MAK: 500 mg/m 3 STEL: 400 ppm STEL: 1000 mg/m 3 MAK: 200 ppm MAK: 500 mg/m 3 NDSCh: 1200 mg/m 3 NDS: 900 mg/m 3 Skin TWA: 100 ppm TWA: 245 mg/m 3 STEL: 150 ppm STEL: mg/m 3 STEL: 400 ppm Skin Chemical Name European Union United Kingdom France Spain Germany 50 mg/l whole blood end of shift Acetone 50 mg/l urine end of shift Acetone Chemical Name Italy Portugal Netherlands Finland Denmark (ACGIH:) 40 mg/l urine end of shift at end of workweek Acetone Background, nonspecific Chemical Name Romania Slovakia Latvia Bulgaria 50 mg/l urine end of shift Acetone 50 mg/l blood end of exposure or work shift Acetone 50 mg/l urine end of exposure or work shift Acetone Page 4 / 9

5 Derived No Effect Level Predicted No Effect Concentration (PNEC) 8.2. Exposure controls Engineering Measures Personal protective equipment Eye Protection Skin and Body Protection Hand Protection Respiratory Protection Environmental Exposure Controls Ensure adequate ventilation, especially in confined areas. If splashes are likely to occur, wear: Goggles Long sleeved clothing. Protective gloves. None required under normal usage. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Do not allow material to contaminate ground water system. Section 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical State Odor Liquid Typical of IPA Appearance Clear Colorless. Property Values ph Melting Point/Range Boiling Point/Boiling Range 35 C Flash Point 12 C Evaporation rate Flammability (solid, gas) Remarks/ Method Vapor Pressure Vapor Density Relative Density Specific Gravity / A@ 20 C Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Explosive Properties Oxidizing Properties 9.2. Other information VOC Content (%) Section 10. Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions None under normal processing. Page 5 / 9

6 10.4. Conditions to avoid Heat, flames and sparks Incompatible materials Hazardous decomposition products Carbon oxides. Section 11. Toxicological information Acute Toxicity Product Information Inhalation Eye Contact Skin Contact Ingestion Product does not present an acute toxicity hazard based on known or supplied information. There is no data available for this product. There is no data available for this product. There is no data available for this product. There is no data available for this product. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation = 4396 mg/kg ( Rat ) mg/kg ( Rat ) 72.6 mg/l ( Rat ) 4 h mg/kg ( Rabbit ) Eye damage/irritation Sensitization Mutagenic Effects Carcinogenic Effects Reproductive Toxicity Developmental Toxicity STOT - single exposure STOT - repeated exposure Target Organ Effects Aspiration Hazard Irritating to eyes. No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Eyes. Respiratory system. Skin. Section 12. Ecological information Toxicity Ecotoxicity Effects Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) EC50 72 h: > 1000 mg/l (Desmodesmus subspicatus) EC50 96 h: > 1000 mg/l (Desmodesmus subspicatus) LC50 96 h: = mg/l static (Pimephales promelas) LC50 96 h: = 9640 mg/l flowthrough (Pimephales promelas) LC50 96 h: > µg/l (Lepomis macrochirus) EC50 48 h: = mg/l (Daphnia magna) Persistence and degradability Bioaccumulative potential. Page 6 / 9

7 Chemical Name Log Pow Mobility in soil Adsorbs on soil Results of PBT and vpvb assessment Other adverse effects This product does not contain any known or suspected endocrine disruptors. Section 13. Disposal considerations Waste treatment methods Waste from Residues / Unused Products Contaminated Packaging Dispose of in accordance with the European Directives on waste and hazardous waste. Do not re-use empty containers. Empty containers pose a potential fire and explosion hazard. Do not cut, puncture or weld containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. Waste product packaging contaminated by residues of hazardous contents should be consigned for disposal as hazardous waste. In this case, the European Waste Catalogue Code is packaging containing residues of or contaminated by dangerous substances. Other Information According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. Section 14. Transport information IMDG/IMO UN-Number UN Proper Shipping Name Alcohols, n.o.s Hazard Class Packing Group II UN1987, Alcohols, n.o.s.( ),3,PG II, FP 12C Marine Pollutant None. EmS No. F-E, S-D Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code RID UN-Number UN Proper Shipping Name Alcohols, n.o.s Hazard Class Packing Group II UN1987 Alcohols, n.o.s.( ),3,II Environmental hazard None. Page 7 / 9

8 Section 14. Transport information Classification Code F1 ADR UN-Number UN Proper Shipping Name Alcohols, n.o.s Hazard Class Packing Group II UN1987 Alcohols, n.o.s.( ),3,II Environmental hazard None. Classification Code F1 ICAO UN-Number ID Proper shipping name Consumer commodity Hazard Class Packing Group Not regulated. ID8000,Consumer commodity, Environmental hazard None. IATA UN-Number ID Proper Shipping Name Consumer commodity Hazard Class Packing Group Not regulated. ID8000,Consumer commodity, Environmental hazard None. ERG Code 9L Safety, health and environmental regulations/legislation specific for the substance or mixture International Inventories TSCA EINECS/ELINCS DSL/NDSL PICCS ENCS IECSC AICS KECL Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances Chemical Safety Assessment Page 8 / 9

9 Section 16. Other information Full text of R-phrases referred to under Sections 2 and 3 R11 - Highly flammable R67 - Vapors may cause drowsiness and dizziness R36 - Irritating to eyes Key literature references and sources for data Issuing Date 06-Jun-2011 Revision Note Initial Release. This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text End of Safety Data Sheet Page 9 / 9