SAFETY DATA SHEET MULTI-SURFACE PEROXIDE. 1. Identification. 2. Hazard(s) identification. Product number: EVSCHEM230

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product number Recommended use Recommended restrictions MULTI-SURFACE PEROXIDE EVSCHEM230 Multi Hard Surface Cleaner None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Medline Industries, Inc. Address One Medline Place Mundelein, IL Telephone Phone: Emergency phone number CHEMTREC Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Not classified. Serious eye damage/eye irritation Specific target organ toxicity, repeated exposure Not classified. Not classified. Category 1 Category 2 GHS label elements Hazard statement Label elements Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Signal word Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger Observe good industrial hygiene practices. Wear safety glasses with side shields (or goggles). Wear impervious gloves for prolonged contact. Do not breathe mist or vapor. IF IN EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses if present and safe to do so. Continue rinsing. Get medical attention if irritation develops or persists. IF ON SKIN: Wash off immediately with plenty of soap and water. Remove and wash contaminated clothing before reuse. Get medical attention if irritation develops or persists. High concentration may temporarily whiten the skin. IF SWALLOWED: Move to fresh air. If a person feels unwell, contact a physician or medical personnel. IF INHALED: Rinse mouth thoroughly with water. Drink plenty water to dilute contents of stomach. If large amount is ingested, contact a poison control center immediately. If a person feels unwell, consult a physician. Store away from incompatible materials. Keep out of the reach of children. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. Not applicable. 1 / 6

2 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Hydrogen peroxide Other components below reportable levels <10 >80 Composition comments The manufacturer has claimed the percentage of one or more ingredients as trade secret. 4. First-aid measures Eye contact Skin contact Ingestion Inhalation Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses if present and safe to do so. Continue rinsing. Get medical attention if irritation develops or persists. Wash off immediately with plenty of soap and water. Remove and wash contaminated clothing before reuse. Get medical attention if irritation develops or persists. High concentration may temporarily whiten the skin. Rinse mouth thoroughly with water. Drink plenty water to dilute contents of stomach. If large amount is ingested, contact a poison control center immediately. If a person feels unwell, consult a physician. Move to fresh air. If a person feels unwell, contact a physician or medical personnel. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Prolonged exposure may cause chronic effects. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Not applicable, non-combustible. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Do not get this material in contact with eyes. Avoid prolonged or repeated contact with skin. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Do not mix with other chemicals. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Keep at temperatures between 4 and 49 C. Keep out of the reach of children. 2 / 6

3 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Hydrogen peroxide (CAS ) Type TWA US. NIOSH: Pocket Guide to Chemical Hazards Components Type Hydrogen peroxide (CAS ) Control parameters TWA US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type Value 1 ppm Value 1.4 mg/m3 1 ppm Value Hydrogen peroxide (CAS ) Appropriate engineering controls PEL 1.4 mg/m3 1 ppm Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Respiratory protection General hygiene considerations Wear impervious gloves for prolonged contact. Not normally needed. 9. Physical and chemical properties Appearance Color Odor Odor threshold ph Melting point/freezing point Boiling point Flash point Evaporation rate Flammability (solid, gas) Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. clear liquid Clear, colourless Fresh Floral fragrance added 4-6 (5-8 at 1:256 to 1:20 dilution) 32 F (0 C) 212 F (100 C) None to boiling Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapor pressure Vapor density 0.22 hpa estimated Solubility(ies) Solubility (water) 100 % 3 / 6

4 Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Specific gravity 1.03 VOC (Weight %) 0 % 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. High temperatures. Hydrogen peroxide can break down when contact with strong alkalies, bleach, iron oxides, inorganic acid chlorides, reducing agents and aluminum. Carbon oxides. Nitrogen oxides (NOx). and oxygen 11. Toxicological information Information on likely routes of exposure Eye contact Causes serious eye damage. Skin contact Ingestion Inhalation Symptoms related to the physical, chemical and toxicological characteristics Acute toxicity Carcinogenicity Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis. High concentration may temporarily whiten the skin. Expected to be a low ingestion hazard. No adverse effects due to inhalation are expected. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. IARC Monographs. Overall Evaluation of Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Hydrogen peroxide (CAS ) 3 Not classifiable as to carcinogenicity to humans. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Chronic effects Toxicological information 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Other adverse effects This product is not expected to cause reproductive or developmental effects. Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure. Meets GS-37 requirements for skin and eye irritation at the as-used dilution. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Based on the biodegradability data of the components, this material is expected to be biodegradable. This material does not contain chemicals that have known bioaccumulative potential. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 4 / 6

5 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose in accordance with all applicable regulations. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Triple rinse containers. Fully drained containers which are drop- and scrape-free can be treated as industrial waste, and can possibly be recycled. Can be offered for recycling, re-conditioning or puncture. IATA UN number UN proper shipping name FORBIDDEN BY AIR Transport hazard class(es) Class Subsidiary risk - Packing group Not applicable. Environmental hazards No. Special precautions for user Read safety instructions, SDS and emergency procedures before handling. Other information Passenger and cargo Forbidden. aircraft Cargo aircraft only Forbidden. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) US EPCRA Section 304 Extremely Haz. Subs. & CERCLA Haz. Subs.: Section 304 EHS reportable quantity Hydrogen peroxide (CAS ) 1000 LBS US. OSHA Specifically Regulated Substances (29 CFR ) CERCLA (Superfund) reportable quantity Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance No 5 / 6

6 SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. 16. Other information, including date of preparation or last revision HMIS ratings Health: 3* Flammability: 0 Physical hazard: 1 Personal protection: B NFPA ratings Health: 3 Flammability: 0 Instability: 1 SDS sections updated Revision Information Issue date Version # 01 Disclaimer Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Proper Shipping Name/Packing Group Regulatory Information: United States Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Proper Shipping Name/Packing Group Regulatory Information: United States The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release. 6 / 6