: Best Greens King Micro with Nutralene

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : Best Greens King Micro with Nutralene : M Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet JR Simplot Company Boise, ID T Emergency telephone number Emergency number : CHEMTREC SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 Eye Irrit. 2B H320 STOT SE 3 H335 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H315 - Causes skin irritation H320 - Causes eye irritation H335 - May cause respiratory irritation : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P264 - Wash... thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P302 + P352 - If on skin: Wash with plenty of water/ P304 + P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a poison center/doctor/ if you feel unwell P321 - Specific treatment (see... on this label) P332 + P313 - If skin irritation occurs: Get medical advice/attention P337 + P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to... in accordance with local/regional/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available 01/16/2015 EN (English) Page 1

2 SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification ammonium sulfate (CAS No) Eye Irrit. 2B, H320 STOT SE 3, H335 potassium nitrate (CAS No) Eye Irrit. 2B, H320 formaldehyde/urea,resins (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 STOT SE 3, H335 potassium sulfate (CAS No) Not classified Monoammonium Phosphate (CAS No) Eye Irrit. 2B, H320 STOT SE 3, H335 Potassium Magnesium Sulfate (CAS No) Not classified urea (CAS No) Skin Irrit. 2, H315 Eye Irrit. 2B, H320 STOT SE 3, H335 *ingredients without WT% are considered proprietary based on trade secrets Eye Irrit. 2B, H320 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see... on this label). : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. 01/16/2015 EN (English) 2/8

3 Emergency procedures : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a wellventilated area. : Wash... thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Multicolored granules. Colour : Multi-colored Odour on odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C 01/16/2015 EN (English) 3/8

4 Relative density Density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : lbs/ft3 : Water: 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions Conditions to avoid Extremely high temperatures. Direct sunlight. Extremely high or low temperatures Incompatible materials Oxidizing agent. Prolonged contact may cause oxidation of unprotected metals. Strong acids. Strong bases Hazardous decomposition products Extremely high temperatures. The product may reach melting point and decompose to release NH3, SOx, POx, or CN. fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ammonium sulfate ( ) formaldehyde/urea,resins ( ) potassium sulfate ( ) Monoammonium Phosphate ( ) LD50 dermal rabbit 2840 mg/kg (Rat) > 2000 mg/kg mg/kg bodyweight 8394 mg/kg (Rat) > 2100 mg/kg (Rat) mg/kg bodyweight 6600 mg/kg (Rat) mg/kg bodyweight 5750 mg/kg (Rat) > mg/kg > 7940 mg/kg (Rabbit) mg/kg bodyweight 8471 mg/kg (Rat) > 3200 mg/kg (Rat) LD50 dermal rabbit > mg/kg (Rabbit) 01/16/2015 EN (English) 4/8

5 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) mg/kg bodyweight 3750 mg/kg (Rat) > 5000 mg/kg mg/kg bodyweight : Causes skin irritation. : Causes eye irritation. Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : May cause respiratory irritation. Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. : May cause respiratory irritation. : Causes skin irritation. : Causes eye irritation. SECTION 12: Ecological information Toxicity ammonium sulfate ( ) EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 formaldehyde/urea,resins ( ) EC50 Daphnia mg/l (96 h; Poecilia reticulata) 202 mg/l (96 h; Daphnia magna) mg/l (96 h; Brachydanio rerio) 433 mg/l (50 h; Daphnia magna) 1290 ppm (96 h; Gambusia affinis) > 500 mg/l (96 h; Leuciscus idus; Estimated value) mg/l (Daphnia magna; QSAR) potassium sulfate ( ) mg/l (96 h; Alburnus alburnus) LC50 other aquatic organisms 1 > 1000 mg/l (96 h) EC50 Daphnia mg/l (48 h; Daphnia magna; Static system) LC50 fish 2 EC50 Daphnia mg/l (96 h; Lepomis macrochirus) 1180 mg/l (96 h; Crustacea) TLM fish ppm (96 h; Lepomis sp.) Threshold limit other aquatic organisms 1 > 1000 mg/l (96 h) Threshold limit algae mg/l (72 h; Scenedesmus subspicatus) Monoammonium Phosphate ( ) EC50 Daphnia 1 LC50 fish ppm (96 h; Pimephales promelas) > 6810 mg/l (96 h; Leuciscus idus) > mg/l (48 h; Daphnia magna) mg/l (96 h; Poecilia reticulata) 01/16/2015 EN (English) 5/8

6 EC50 Daphnia 2 TLM fish 1 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 Threshold limit algae 2 LC50 other aquatic organisms 1 EC50 other aquatic organisms 1 LC50 fish 2 LC50 other aquatic organisms 2 TLM fish 1 TLM fish 2 Threshold limit other aquatic organisms 1 Threshold limit other aquatic organisms 2 > mg/l (24 h; Daphnia magna) ppm (96 h; Poecilia reticulata) mg/l (16 h; Bacteria; Toxicity test) > mg/l (Pseudomonas putida) > mg/l (168 h; Scenedesmus quadricauda) 162 mg/l (96 h; Pisces; Lethal) 39 mg/l (96 h; Daphnia magna) mg/l (Plankton; Nocivity test) 1378 mg/l (Poecilia reticulata) 490 mg/l (48 h; Daphnia magna) 3000 mg/l (96 h; Lepomis macrochirus) 162 mg/l (96 h; Gambusia affinis) 39 mg/l (96 h; Daphnia magna) 490 mg/l (48 h; Daphnia magna) Best Greens King Micro with Nutralene ammonium sulfate ( ) formaldehyde/urea,resins ( ) potassium sulfate ( ) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Monoammonium Phosphate ( ) ThOD Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Potassium Magnesium Sulfate ( ) Biodegradability in water: no data available. Not readily biodegradable in water. Biodegradability: not applicable. Biodegradability in water: no data available. Inherently biodegradable. Hydrolysis in water g O₂ /g substance Biodegradability: not applicable Best Greens King Micro with Nutralene ammonium sulfate ( ) Log Pow -5.1 Bioaccumulation: not applicable. 01/16/2015 EN (English) 6/8

7 formaldehyde/urea,resins ( ) potassium sulfate ( ) Monoammonium Phosphate ( ) No bioaccumulation data available. Not bioaccumulative. Not bioaccumulative. BCF fish 1 BCF other aquatic organisms 1 1 (72 h; Brachydanio rerio; Fresh water) (Chlorella sp.) Log Pow Bioaccumulation: not applicable. Potassium Magnesium Sulfate ( ) No bioaccumulation data available Mobility in soil Other adverse effects Effect on ozone layer Effect on the global warming Other information : : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Potassium Magnesium Sulfate CAS No CAS No 01/16/2015 EN (English) 7/8

8 This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Potassium Magnesium Sulfate ( ) Not listed on the United States TSCA (Toxic Substances Control Act) inventory Not listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Other information : : None. Full text of H-phrases: see section 16: Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Skin Irrit. 2 Skin corrosion/irritation, Category STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H320 Causes eye irritation H335 May cause respiratory irritation SDS US (GHS HazCom 2012) - Custom Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. 01/16/2015 EN (English) 8/8