Trimethylolpropane Diallyl Ether 90

Transcription

1 Safety data sheet Issue Date 19-Jul-2016 Version 1 Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Trimethylolpropane Diallyl Ether 90 Chemical Name CAS No 2,2-bis(allyloxymethyl)butan-1-ol Other means of identification Safety data sheet number P-0177 Pure substance/mixture Substance Recommended use of the chemical and restrictions on use Application Manufacture of substances. Distribution and storage. Formulation [mixing] of preparations and/or re-packaging Manufacture: of oligomers and of polymers. Laboratory chemicals. Uses advised against Formation of acrolein (very toxic) can occur in oxidative drying systems catalyzed by metal salts, for example alkyd paints. Details of the supplier of the safety data sheet Manufacturer Supplier Perstorp Specialty Chemicals AB SE Perstorp, Sweden Tel Perstorp (Shanghai) Chemical Trading Co Ltd Room , Shanghai Central Plaza, 381 Middle Huai Hai Road Shanghai, China Tel address productinfo@perstorp.com Emergency telephone number China (+) (contract no: ) Asia Pacific (+) (contract no: ) Section 2: HAZARDS IDENTIFICATION Hazards description The product may cause slight irritation on repeated or prolonged skin contact. In contact with air/oxygen the product will slowly form peroxides. Classification of the substance or mixture Acute toxicity - Oral Category 5 - (H303) Label elements Symbols/Pictograms Signal word Warning Hazard statements H303 - May be harmful if swallowed Precautionary statements Page 1 / 7

2 P312 - Call a POISON CENTER or doctor if you feel unwell Other hazards Section 3: COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% 2,2-bis(allyloxymethyl)butan-1-ol Section 4: FIRST AID MEASURES Description of first aid measures Inhalation Skin contact Eye contact Ingestion First aid measures not required, but get fresh air for personal comfort. First aid measures not required, but wash exposed skin with soap and water for hygienic reasons. Rinse thoroughly with plenty of water, also under the eyelids. Use lukewarm water if possible. Rinse mouth then drink plenty of water. If a large quantity have been ingested or if you feel unwell, get medical advice/attention. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed None known. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Section 5: FIRE FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media High volume water jet. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating and toxic gases and vapours. Hazardous combustion products Carbon monoxide (CO). Carbon dioxide (CO2). May emit small amounts of toxic fumes under fire conditions: Allyl alcohol and acrolein. Protective equipment and precautions for firefighters Wear self-contained breathing apparatus and protective suit. Additional information Cool containers with flooding quantities of water until well after fire is out Section 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Wear safety glasses, gloves, protective clothing and rubber boots for hygienic reasons. Page 2 / 7

3 Environmental precautions Prevent further leakage or spillage if safe to do so. Avoid release to the environment. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Small spill Large spill Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Take up mechanically, placing in appropriate containers for disposal. Pump up the product into a spare container suitably labelled. Methods for cleaning up Clean contaminated surface thoroughly. Use: Water (with cleaning agent). Section 7: HANDLING AND STORAGE Precautions for safe handling Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Keep tightly closed in a dry and cool place. Keep away from heat. Protect from direct sunlight. In contact with air/oxygen the product will slowly form peroxides. Can form peroxides when stored in opened, unsealed containers. For additional information regarding peroxide formation, see Perstorp Technical information, Leaflets TI 1120 and TI Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Users are advised to consider national Occupational Exposure Limits or other equivalent values, (if existing). Appropriate engineering controls No specific measures identified. Individual protection measures, such as personal protective equipment Eye/face protection If handled where risk of splashes may occur, use safety goggles. Hand Protection Recommendation(s): Wear protective gloves. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. Skin and body protection Normal work clothes for the chemical industry (long legs and sleeves). Respiratory protection None under normal use conditions. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance liquid colourless Odour Mild Odour threshold No data available Property Value Remarks Method ph Melting point / freezing point < -80 C / -112 F Boiling point / boiling range 260 C / 500 F ASTM E Flash point 127 C / 261 F ASTM D Evaporation rate Flammability (solid, gas) Explosive limits Upper explosive limits Page 3 / 7

4 Lower explosive limits Vapour pressure C, SPARC Vapour density Relative density Water solubility C OECD Test No. 105: Water Solubility Solubility(ies) soluble in : methanol, n-butanol, acetone. Partition coefficient 3 log Pow (@25 C) OECD Test No. 117: Partition Coefficient (n-octanol/water), HPLC Method Autoignition temperature 230 C / 446 F ASTM E Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Not explosive. May form explosive peroxides. Oxidising properties Not oxidising. Density 20 C, ISO Bulk density Other Information Section 10: STABILITY AND REACTIVITY Reactivity There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter. Chemical stability In contact with air/oxygen the product will slowly form peroxides. Possibility of Hazardous Reactions In contact with air/oxygen the product will slowly form peroxides. Formation of acrolein (very toxic) can occur in oxidative drying systems catalyzed by metal salts, for example alkyd paints. Conditions to avoid None under normal use conditions. Incompatible materials Oxidizing substances including air (oxygen). Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapours: Allyl alcohol and acrolein, Carbon monoxide (CO), Carbon dioxide (CO2). Section 11: TOXICOLOGICAL INFORMATION Information on likely routes of exposure Dermal. Inhalation. Symptoms related to the physical, chemical and toxicological characteristics None known. Numerical measures of toxicity Acute toxicity May be harmful if swallowed. Method Species Exposure route Effective dose Remarks Not defined Rat Oral mg/kg LD50 (lethal dose) OECD Test No. 401: Acute Oral Toxicity Rat Oral >2000 mg/kg LD50 (lethal dose) Page 4 / 7

5 OECD Test No. 402: Acute Dermal Toxicity Rabbit Dermal >3000 mg/kg LD50 (lethal dose) Skin corrosion/irritation Causes mild skin irritation. No classification according to GHS criteria. Method Species Exposure route Results: OECD Test No. 404: Acute Dermal Irritation/Corrosion Rabbit Dermal Causes mild skin irritation No classification according to GHS criteria. Serious eye damage/eye irritation No eye irritation. Method Species Exposure route Results: OECD Test No. 405: Acute Eye Irritation/Corrosion Rabbit Eye Non-irritant Respiratory or skin sensitisation No sensitising effects known. Method Species Exposure route Results: OECD Test No. 406: Skin Sensitisation Guinea pig Skin Not a skin sensitiser Germ cell mutagenicity Not mutagenic. Method Species Results: OECD Test No. 471: Bacterial Reverse in vitro Negative Mutation Test OECD Test No. 476: In vitro Mammalian Cell in vitro Positive Gene Mutation Test OECD Test No. 474: Mammalian Erythrocyte Micronucleus Test in vivo Negative Carcinogenicity Not suspected as a human carcinogen. Reproductive toxicity Is not considered hazardous to the reproduction. Method Species Exposure route Effective dose Remarks OECD Test No. 414: Pre-natal Development Toxicity Study Rat Oral 800 mg/kg bw/d No evidence of an effect on the reproductive organs was seen in a 30-day study at dose levels of up to and including 800 mg/kg bw/d. STOT - single exposure STOT - repeated exposure Method Species Exposure route Effective dose Remarks Page 5 / 7

6 OECD Test No. 407: Repeated Dose 28-day Oral Toxicity Study in Rodents OECD Test No. 408: Repeated Dose 90-Day Oral Toxicity Study in Rodents Rat Oral 200 mg/kg bw/d NOAEL Rat Oral 200 mg/kg bw/d NOAEL Aspiration hazard. Section 12: ECOLOGICAL INFORMATION Toxicity Low toxicity to aquatic organisms. Method Species Exposure route Effective dose Exposure time Remarks OECD Test No. 203: Fish, Acute Toxicity Test Brachydanio rerio Freshwater h mg/l LC50 (lethal OECD Test No. 202: Daphnia sp. Acute Immobilization Test Daphnia magna Freshwater h mg/l EC50 (effective OECD Test No. 201: Freshwater Algae and Cyanobacteria, Growth Inhibition Test OECD Test No. 209: Activated Sludge, Respiration Inhibition Test (Carbon and Ammonium Oxidation) Pseudokirchneriell a subcapitata Persistence and degradability Not readily biodegradable. Inherently biodegradable. Freshwater >100 72h mg/l EC50 (effective Bacteria toxicity Freshwater >1000 3h mg/l EC50 (effective Method Value Exposure time Results: OECD Test No. 302B: Inherent Biodegradability: Zahn-Wellens/ EVPA Test 72% 28d Not readily biodegradable Inherently biodegradable. Bioaccumulative potential Not likely to bioaccumulate. Mobility in soil The substance is not expected to adsorb to a high degree to suspended solids and sediment based upon the log Pow. Other adverse effects. Section 13: DISPOSAL CONSIDERATIONS Disposal methods The product is not classified as hazardous waste. Incinerate at a licensed installation. Contaminated packaging Thoroughly emptied and clean packaging may be recycled. Contaminated packaging materials must be disposed of in the same manner as the product. Section 14: TRANSPORT INFORMATION China Road transport Not regulated Page 6 / 7

7 IMDG Sea transport Not regulated Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code IATA Air transport Not regulated Section 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture International Regulations National Regulations China Taiwan Section 16: OTHER INFORMATION Key or legend to abbreviations and acronyms used in the safety data sheet Issue Date Revision Date Revision Note 19-Jul Jul Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 7 / 7