94408 ORASOL Orange 272

Transcription

1 Revised edition: Version: 4.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: ORASOL Orange 272 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent for dye and varnish industry Coloring agent for industrial purposes Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H302 Cat.: 4 Classification according to Directive No. 67/548/EC or No. 1999/45/EC Harmful (Xn) R22 Acute toxicity (oral), hazard category 4 Harmful if swallowed. Harmful if swallowed. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: GHS07-1 Signal word: Warning Hazard designation: 2

2 H302 Harmful if swallowed. Page 2 Safety designation: P264 P270 P301+P330 P312 P501 Wash thoroughly after handling. Do not eat, drink or smoke when using this product. If swallowed: Rinse mouth. Call a poison center or physician if you feel unwell. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture This product is capable of dust explosion under certain circumstances. Chemical Characterization: Dye, woodstain. Metal complex dye, Solvent Orange 99 Information on Components / Hazardous Ingredients: Amines, C10-14-branched and linear Alkyl-, bis [2,4-dihydro-4[(2-hydroxy-5-nitrophenyl)azo]-5- methyl-2-phenyl-3h-pyrazol-3-onato(2-)]chromate (1-) (1:1) (Xn; R22; H302) 100 % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air. In case of complaints consult a physician. Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Symptoms: No further information available. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 3

3 Page Treatment: Treat symptomatically Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Unsuitable extinguishing media: Extingishing powder, foam. Carbon dioxide (CO2) Special Hazards arising from the Substance or Mixture Special hazards: In case of fire: hazardous vapors may be released. Development of fumes/aerosol Advice for Firefighters Protective equipment: Further information: Wear self-contained respiratory protective device. Avoid formation of dust: risk of dust explosion. Dispose of fire debris and contaminated extinguishing water in accordance with local regulations Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Avoid formation of dust, wear protective clothing Environmental Precautions Environmental precautions: Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and Material for Containment and Cleaning Up Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Clean up mechanically. Avoid dust formation. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Instructions on safe handling: Respiratory protection when handling without exhaust system. Avoid contact with eyes, skin and clothing. 4

4 Avoid formation of dust. Do not inhale dust. Page Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and cool room. No special measures necessary. Avoid dust formation. Protect against electrostatic charging. Do not store together with ignitable sources, heat and fire. 11; Combustible solids Further Information: Specific End Use(s) Further information: See Section 1.2.; no other uses provided Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled: No exposure limits for this product. Amines, C10-14-branched and linear Alkyl-, bis[2,4-dihydro-4[(2- hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3h-pyrazol-3-onato (2-)] chromate(1-) (1:1) (CAS ): TWA (CH): 0.5 mg/m3, inhalable dust (measured as chromium (Cr)) Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: The usual precautionary measures are to be adhered to when handling chemicals. Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Respiratory protection: 5

5 Page 5 Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). Hand protection: Protective glove material: Eye protection: Chemical protective gloves (EN 374 (Europe), F739 (US)). The manufacturer s directions for use should be observed because of the great diversity of types. Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Body protection: Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Avoid contamination of sewage system, open water ways and ground water. Form: Color: Odor: Odor threshold: ph-value: powder orange odorless No information available. ca. 6.8 (0.05 g/l, 20 C) Melting temperature: C Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): not easily flammable Upper explosion limit: Lower explosion limit: Vapor pressure: 6

6 Vapor density: This product is a non-volatile solid. Page Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: ca g/cm3 (20 C) insoluble Product is not auto-ignitable. 220 C, 0.91 kj/g (DSC (DIN 51007)) Product does not present an explosion hazard. not oxidizing kg/m3 ethanol, approx. 150 g/l Self-heating ability: This product is not a self-heating substance according to the UN class 4.2 (UN Test N.4) Minimum ignition energy: > 10 - < 30 mj (1013 hpa, 20 C) No decomposition if used according to specifications. Stable if used according to specifications. Risk of dust explosion. Avoid formation of dust. Avoid electrostatic discharge. 7

7 Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity Page 7 Strong acids, strong bases and strong oxidizing agents. None if stored and handled according to specifications. LD50, oral: LD50, dermal: LC50, inhalation: 1400 mg/kg (rat) Primary effects Irritant effect on skin: Non irritating (rabbit) Irritant effect on eyes: Non-irritating to eyes (rabbit) Inhalation: No information available. Ingestion: No information available Sensitization: No relevant data found. Mutagenicity: No relevant data found. Reproductive toxicity: No relevant data found. Carcinogenicity: No relevant data found. Teratogenicity: No information available. Specific target organ toxicity (STOT): Single exposure: no information available. Repeated exposure: no information available. Additional toxicological information: Aspiration hazard: 12. Ecological Information 8

8 Aquatic Toxicity Page Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): EC50: > 100 mg/l (48h, Daphnia magna) EC20: > 1000 mg/l (0.5h, active sludge; OECD 209) Inorganic product is not very soluble in water and can thus be removed from water mechanically in suitable effluent treatment plants. Can be eliminated from water by chemical adsorption. No information available. No information available. According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. 1, slightly hazardous No impairment of the biodegradability of active sludge expected when small amounts are discharged in biological sewage plants. The product contains about 6 % Cr bound as a complex. In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. Uncleaned packaging: Uncontaminated packaging may be recycled. Packaging may be disposed of in the same manner as the product. 9

9 Page 9 Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation, Assessment by list) Local regulations on chemical accidents: 10

10 Employment restrictions: Page Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Not applicable. A Chemical Safety Assessment has not yet been carried out for this product. Regulation (EC) 2037/ Substances that Deplete the Ozone Layer: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.