MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name FeelFresh Hand Sanitizing Spray - CAS # Product use Manufacturer information Supplier Emergency overview Potential short term health effects Routes of exposure Eyes Skin Ingestion Target organs Chronic effects Signs and symptoms OSHA regulatory status Mixture Topical antiseptic hand cleaner NWL Netherlands Services BV Newell Rubbermaid Amperestraat HB Hillegom, Netherlands Phone + 31 (0) Kruger Products L.P Minnesota Court Mississauga, Ontario L5N 5R5 Canada Emergency Phone: Fax: Phone: Hazards Identification FLAMMABLE LIQUID AND VAPOR. MAY IRRITATE EYES. Eye, Skin contact,, Ingestion. May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. Eyes. Potential environmental effects See section 12. Prolonged or repeated exposure can cause drying, defatting and dermatitis. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR Composition/Information on Ingredients CAS # Percent ETHANOL Composition comments Active ingredients are listed above. 4. First Aid Measures First aid procedures Eye contact Skin contact Ingestion Notes to physician General advice Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Flush with water. In case of skin irritation, discontinue use of product. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Symptoms may be delayed. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep out of reach of children. #20529 Page: 1 of 7

2 Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Occupational exposure limits US. ACGIH Threshold Limit Values Ethanol (CAS ) 5. Fire Fighting Measures Flammable by WHMIS/OSHA criteria. Dry chemical. Carbon dioxide. Vapors may form explosive mixtures with air. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. Remove sources of ignition. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills to original containers for re-use. 7. Handling and Storage Use according to package label instructions. For external use only. DO NOT get in eyes. Do not ingest. Use good industrial hygiene practices in handling this material. Keep out of reach of children. Store in a cool, dry, well-ventilated place away from incompatible materials. Store away from heat, flames, sparks, and all other sources of ignition. 8. Exposure Controls/Personal Protection Type STEL Value 1000 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Type Ethanol (CAS ) PEL Value 1900 mg/m ppm Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection Not applicable General ventilation normally adequate. Not normally required when used as directed. Not applicable. In case of skin irritation, discontinue use of product. #20529 Page: 2 of 7

3 Skin and body protection Respiratory protection General hygiene considerations Appearance Color Form Odor Odor threshold Physical state As required by employer code. Not normally required. Handle in accordance with good industrial hygiene and safety practice. Clear Colorless 9. Physical and Chemical Properties aqueous solution Mild ph 6.5 Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Liquid. 32 F (0 C) > F (> 78 C) F (24.00 C) > 698 F (> 370 C) < 19 (ethanol) > 3.3 (ethanol) Specific gravity 0.91 (Water = 1) Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Appreciable Slightly Viscous 10. Stability and Reactivity This product may react with oxidizing agents. This product may react with acids. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Avoid heat, flames, sparks, and all other sources of ignition. Caustics. Acids. Oxidizers. May include and are not limited to: Oxides of carbon. 11. Toxicological Information Toxicological data Acute LC50 Species Mouse Rat Test Results 39 mg/l, 4 Hours ppm, 4 Hours #20529 Page: 3 of 7

4 Oral LD50 Species Dog Guinea pig Mouse Rat Test Results 5.5 g/kg 5.6 g/kg 3450 mg/kg 7060 mg/kg 6.2 g/kg Effects of acute exposure Eye contact Skin contact Ingestion Sensitization Chronic effects Carcinogenicity ACGIH Carcinogens May cause respiratory tract irritation. May cause stomach distress, nausea or vomiting. IARC Monographs. Overall Evaluation of Carcinogenicity A3 Confirmed animal carcinogen with unknown relevance to humans. Volume 44, Volume 96, Volume 100E 1 Carcinogenic to humans. Volume 96, Volume 100E 1 Carcinogenic to humans. US - California Proposition 65 - CRT: Listed date/carcinogenic substance US NTP Report on Carcinogens: Known carcinogen Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Carcinogenic. Known To Be Human Carcinogen. 12. Ecological Information Ecotoxicity Ecotoxicological data Aquatic Crustacea Fish Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity See below EC50 LC50 Species Daphnia Water flea (Daphnia magna) Fathead minnow (Pimephales promelas) Partition coefficient ETHANOL Chemical fate information Test Results mg/l, 48 Hours mg/l, 48 hours > 100 mg/l, 96 hours #20529 Page: 4 of 7

5 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Dispose in accordance with all applicable regulations. 14. Transport Information U.S. Department of Transportation (DOT) Basic shipping requirements: UN number UN1170 Proper shipping name Ethanol, solution Hazard class 3 Packing group III Special provisions 24, B1, IB3, T2, TP1 Packaging exceptions 150 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: UN number UN1170 Proper shipping name ETHANOL SOLUTION Hazard class 3 Packing group III DOT TDG Canadian federal regulations 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada NPRI VOCs with Additional Reporting Requirements: Mass reporting threshold/identification Number Canada WHMIS Ingredient Disclosure: Threshold limits 1 tonnes 0.1 % WHMIS classification Exempt - Registered product - (NHP ) Occupational Safety and Health Administration (OSHA) 29 CFR hazardous chemical US federal regulations Yes This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR CERCLA/SARA Hazardous Substances - Not applicable. #20529 Page: 5 of 7

6 TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) US CAA Section 111 Volatile Organic Compounds: Listed substance Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No See below US - California Hazardous Substances (Director's): Listed substance US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance US - Illinois Chemical Safety Act: Listed substance US - Louisiana Spill Reporting: Listed substance US - Minnesota Haz Subs: Listed substance US - New Jersey RTK - Substances: Listed substance US - Texas Effects Screening Levels: Listed substance US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information No Yes Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / X #20529 Page: 6 of 7

7 Disclaimer Issue date Effective date Expiry date Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 29-August August August-2016 Prepared by Dell Tech Laboratories, Ltd. Phone: (519) Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. #20529 Page: 7 of 7