: Mixed white zinc / titanium

Transcription

1 Date of issue: Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Mixed white zinc / titanium Product code : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : Oilpaint Uses advised against 1.3. Details of the supplier of the safety data sheet Old Holland Classic Colours Since 1664 Nijendal KC Driebergen Rijsenburg - Nederland T F info@oldholland.com Emergency telephone number Country Organisation/Company Address Emergency number NETHERLANDS SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Nationaal Vergiftigingen Informatie Centrum National Institute for Public Health and the Environment, NB this service is only available to health professionals Classification according to Regulation (EC) No. 1272/2008 [CLP] Huispostnummer B , PO Box GA Utrecht Aquatic Acute 1 H400 Aquatic Chronic 1 H410 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC or 1999/45/EC N; R50/53 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS09 : Warning : De-aromatised Kerosene : H410 - Very toxic to aquatic life with long lasting effects : P273 - Avoid release to the environment P391 - Collect spillage P501 - Dispose of contents/container to to an authorized waste treatment plant 2.3. Other hazards EN (English) 1/6

2 SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Comments : The product is a mixture of the ingredients mentioned below and non-dangerous additives Name Product identifier % Classification according to Directive 67/548/EEC zinc oxide (CAS No) (EC no) (EC index no) N; R50/53 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] zinc oxide (CAS No) (EC no) (EC index no) Full text of R- and H-phrases: see section Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store aways from other materials EN (English) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Heat sources. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Insufficient ventilation: wear respiratory protection. Gloves. Safety glasses. Hand protection Eye protection Respiratory protection Other information : Wear protective gloves. Since the product consists of several substances, it is possible to estimate the durability of the glove material beforehand and it therefore needs to be tested before use. Gloves must be replaced aftereach use and whenever signs of wear of perforation appear. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : White. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits EN (English) 3/6

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms SECTION 12: Ecological information Toxicity Ecology - water :. : Very toxic to aquatic life with long lasting effects Persistence and degradability Mixed white zinc / titanium Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential Mixed white zinc / titanium Bioaccumulative potential Not established Mobility in soil Results of PBT and vpvb assessment EN (English) 4/6

5 12.6. Other adverse effects : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to to an authorized waste treatment plant. : Avoid release to the environment UN number No dangerous good in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Dangerous for the environment Marine pollutant : : Yes Yes Other information : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Inland waterway transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance Seveso Information : National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information EN (English) 5/6

6 Data sources Abbreviations and acronyms Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road). ATE: Acute Toxicity Estimated. CAS: Chemical Abstracts Service (division of the American Chemical Society). CLP: Classification, Labeling and Packaging. CMR: Carcinogeen, Mutageen, Reprotoxisch. CSA: Chemical Safety Assessment. CSR: Chemical Safety Report. DNEL: Derived No Effect Level (for human). EC50: Median Effective Concentration (required to induce a 50% effect). EINECS: European Inventory of Existing Commercial Chemical Substances. GHS: Globally Harmonized System of Classification and Labelling of Chemicals. IATA: International Air Transport Association. IMDG: International Maritime Code for Dangerous Goods. LC50: Lethal concentration, 50 percent. LD50: Lethal dose, 50 percent. PBT: Persistent, Bio accumulating and Toxic. PNEC: Predicted No Effect Concentration (for environment). REACH: Registration, Evaluation and Authorisation of Chemical substances. RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail). SVHC: Substances of Very High Concern. vpvb: very Persistent, very Bio accumulating. : REACH Disclaimer: This information is based on current knowledge. Consistency of data in the SDS with CSR is considered, as far as the information is available at the time of compilation (cfr Revision date and Version number). DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Full text of R-, H- and EUH-phrases:: Aquatic Acute 1 Hazardous to the aquatic environment AcuteHazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 H400 H410 Very toxic to aquatic life Very toxic to aquatic life with long lasting effects R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment N Dangerous for the environment SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 6/6