Material Safety Data Sheet

Transcription

1 1. PRODUCT AND COMPANY IDENTIFICATION Product name Product Use Description Manufacturer/Importer/Distribu tor Telephone Emergency telephone number (24h) : : Surfactant : Air Products and Chemicals, Inc 7201 Hamilton Blvd. Allentown, PA GST No RT0001 QST No TQ0001 : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv : USA International 2. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS Number Concentration (Weight) 2-Propyn-1-ol % Ethanolamine % Quaternary ammonium compounds, coco % alkylbis(hydroxyethyl)methyl, ethoxylated, chlorides Propanol, % Water % CHEMICAL FAMILY: Quaternary Ammonium Compound 3. HAZARDS IDENTIFICATION Emergency Overview Corrosive Keep away from heat and sources of ignition. Components of the product may affect the nervous system. Flammable. Severe eye irritant. Severe respiratory irritant. Severe skin irritant. Harmful if swallowed. Harmful by inhalation. Highly toxic by absorption. 1/9

2 Potential Health Effects Inhalation Eye contact Skin contact Ingestion Chronic Health Hazard Exposure Guidelines Target Organs Symptoms : Harmful if inhaled and may cause delayed lung injury. Can cause severe eye, skin and respiratory tract burns. Risk of serious damage to the lungs (by inhalation). May cause nose, throat, and lung irritation. Inhalation of aerosol may cause irritation to the upper respiratory tract. May cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Severe cases of overexposure can result in respiratory failure. Inhalation of vapors and/or aerosols in high concentration may cause irritation of respiratory system. Harmful if inhaled. : Causes eye burns. May cause blindness. Severe eye irritation. : Causes skin burns. If absorbed through the skin, may cause central nervous system effects, such as headache, nausea, dizziness, confusion, breathing difficulties. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Highly toxic by absorption. : If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the stomach. Harmful if swallowed. : This product contains no listed carcinogens according to IARC, ACGIH, NTP and/or OSHA in concentrations of 0.1 percent or greater. Prolonged contact may result in chemical burns and permanent damage. : Skin. Eyes. Respiratory system. Central nervous system. : Repeated and/or prolonged exposure to low concentrations of vapors and/or aerosols may cause: Sore throat. Aggravated Medical Condition Eye disease Skin disorders and Allergies. Asthma. Neurological disorders 4. FIRST AID MEASURES General advice Eye contact Skin contact : Seek medical advice. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. : Hold eyelids apart, initiate and maintain gentle and continuous irrigation until the patient receives medical care. If medical care is not promptly available, continue to irrigate for one hour. : Immediately remove contaminated clothing, and any extraneous chemical, if possible to do so without delay. Initiate and maintain gentle and continuous irrigation until the patient receives medical care. If medical care is not promptly 2/9

3 available, continue to irrigate for one hour. Cover wound with sterile dressing. Ingestion Inhalation : Do not induce vomiting without medical advice. If a person vomits when lying on his back, place him in the recovery position. Never give anything by mouth to an unconscious person. Prevent aspiration of vomit. Turn victim's head to the side. : If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Move to fresh air. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Specific hazards Special protective equipment for fire-fighters Further information : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Dry sand. Limestone powder. : Incomplete combustion may form carbon monoxide. May generate ammonia gas. May generate toxic nitrogen oxide gases. Burning produces noxious and toxic fumes. In the event of fire, cool tanks with water spray. Downwind personnel must be evacuated. Fire or intense heat may cause violent rupture of packages. May form explosive mixtures in air. : Avoid contact with the skin. A face shield should be worn. Use personal protective equipment. Wear self contained breathing apparatus for fire fighting if necessary. : Do not allow run-off from fire fighting to enter drains or water courses., Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Additional advice : Wear suitable protective clothing, gloves and eye/face protection. Use self-contained breathing apparatus and chemically protective clothing. Remove all sources of ignition. Evacuate personnel to safe areas. : Construct a dike to prevent spreading. Shut off or remove all ignition sources. Construct a dike to prevent spreading. : Contact Air Products' Emergency Response Center for advice. Approach suspected leak areas with caution. Absorb with inert absorbent materials such as: Dry sand. Vermiculite. Activated charcoal. Place in appropriate chemical waste container. : Open enclosed spaces to outside atmosphere. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. If possible, stop flow of product. 7. HANDLING AND STORAGE 3/9

4 Handling Use only in well-ventilated areas. Avoid breathing vapors and/or aerosols. Avoid contact with skin and eyes. Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Avoid contact with eyes. See "Flammable and Combustible Liquid Code" NFPA No. 30, National Fire Protection Association, Boston, MA. Use personal protective equipment. When using, do not eat, drink or smoke. Storage Keep containers tightly closed in a dry, cool and well-ventilated place. To avoid ignition of vapors by static electricity discharge, all metal parts of the equipment must be grounded. Keep away from heat and sources of ignition. Keep away from Oxidizers. Technical measures/precautions Keep away from open flames, hot surfaces and sources of ignition. Storage Temperature : F ( C) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Use explosion-proof equipment. Maintain process conditions to ensure temperature is below product flashpoint. Provide readily accessible eye wash stations and safety showers. Provide natural or explosion-proof ventilation adequate to ensure concentrations are kept below exposure limits. Personal protective equipment Respiratory protection : Wear appropriate respirator when ventilation is inadequate. Hand protection Eye protection : Butyl-rubber Nitrile rubber. Neoprene gloves. Impervious gloves. The breakthrough time of the selected glove(s) must be greater than the intended use period. : Full face shield with goggles underneath. Chemical resistant goggles must be worn. Skin and body protection : Impervious clothing. Full rubber suit (rain gear). Rubber or plastic boots. Long sleeve shirts and trousers without cuffs. Slicker Suit. Environmental exposure controls : Construct a dike to prevent spreading. Shut off or remove all ignition sources. 4/9

5 Special instructions for protection and hygiene : Discard contaminated leather articles. Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Provide readily accessible eye wash stations and safety showers. Wash at the end of each workshift and before eating, smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. Exposure limit(s) 2-Propyn-1-ol Time Weighted Average (TWA): ACGIH 1 ppm - 2-Propyn-1-ol Recommended exposure limit (REL): NIOSH 1 ppm 2 mg/m3 Ethanolamine Time Weighted Average (TWA): ACGIH 3 ppm - Ethanolamine Short Term Exposure Limit (STEL): ACGIH 6 ppm - Ethanolamine Recommended exposure limit (REL): NIOSH 3 ppm 8 mg/m3 Ethanolamine Short Term Exposure Limit (STEL): NIOSH 6 ppm 15 mg/m3 Ethanolamine PEL: OSHA Z1 3 ppm 6 mg/m3 Propanol, 2- Recommended exposure limit (REL): NIOSH 400 ppm 980 mg/m3 Propanol, 2- Short Term Exposure Limit (STEL): NIOSH 500 ppm 1,225 mg/m3 Propanol, 2- PEL: OSHA Z1 400 ppm 980 mg/m3 Propanol, 2- Time Weighted Average (TWA): OSHA Z1A 400 ppm 980 mg/m3 Propanol, 2- Short Term Exposure Limit (STEL): OSHA Z1A 500 ppm 1,225 mg/m3 Propanol, 2- Time Weighted Average (TWA) Permissible 400 ppm 980 mg/m3 Exposure Limit (PEL): US CA OEL Propanol, 2- Short Term Exposure Limit (STEL): US CA OEL 500 ppm 1,225 mg/m3 Propanol, 2- Time Weighted Average (TWA): ACGIH 200 ppm - Propanol, 2- Short Term Exposure Limit (STEL): ACGIH 400 ppm - 9. PHYSICAL AND CHEMICAL PROPERTIES Form Color Odor : Liquid. : Amber. : Irritating. Relative density : 1.02 Vapor pressure : mmhg at 75 F (23.9 C) Boiling point/range Melting point/range : 180 F (82.2 C) : 0 F (-17.8 C) Flash point : C Water solubility : Completely soluble. 10. STABILITY AND REACTIVITY 5/9

6 Stability Conditions to avoid Materials to avoid Hazardous decomposition products : Stable under normal conditions. : Heat, flames and sparks. : Reactive metals (e.g. sodium, calcium, zinc etc.). Materials reactive with hydroxyl compounds. Sodium hypochlorite. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. Oxidizing agents. Metals. Alkalies. Alkali and alkaline earth metals - powdered aluminum, zinc, etc. Reacts with water to form corrosive acids. : Nitric acid. Ammonia Nitrogen oxides (NOx). Nitrogen oxide can react with water vapors to form corrosive nitric acid. Carbon monoxide. Carbon dioxide (CO2). Aldehydes Flammable hydrocarbon fragments. Gives off hydrogen by reaction with metals. 11. TOXICOLOGICAL INFORMATION Acute Health Hazard Ingestion Ingestion - Components 2-Propyn-1-ol LD50 : 56 mg/kg Species : Rat. Ethanolamine LD50 : 1,720 mg/kg Species : Rat. Propanol, 2- LD50 : 4,710 mg/kg Species : Rat. Inhalation Inhalation - Components 2-Propyn-1-ol LC50 (4 h) : 0.75 mg/l Species : Rat. Propanol, 2- LC50 (8 h) : ppm Species : Rat. Dermal Dermal- Components 2-Propyn-1-ol LD50 : 88 mg/kg Species : Rabbit. Ethanolamine LD50 : 1,020 mg/kg Species : Rabbit. Propanol, 2- LD50 : 12,870 mg/kg Species : Rabbit. 12. ECOLOGICAL INFORMATION 6/9

7 Ecotoxicity effects Aquatic toxicity Toxicity to fish - Components Ethanolamine LC50 (96 h) : mg/l Species : Rainbow trout (Oncorhynchus mykiss). Ethanolamine LC50 (96 h) : mg/l Species : Bluegill sunfish (Lepomis macrochirus). Propanol, 2- EC50 (48 h) : 10,000 mg/l Species : Fathead minnow (Pimephales promelas). Propanol, 2- LC50 (96 h) : > 1,400 mg/l Species : Bluegill sunfish (Lepomis macrochirus). Propanol, 2- LC50 (96 h) : 6,550 mg/l Species : Fathead minnow (Pimephales promelas). Toxicity to other organisms : No data available. Persistence and degradability Biodegradability : Inherently biodegradable. Mobility Bioaccumulation : No data available. Bioaccumulation - Components Ethanolamine Negligible bioaccumulation potential. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Contaminated packaging : Contact supplier if guidance is required. : Dispose of container and unused contents in accordance with federal, state, and local requirements. 14. TRANSPORT INFORMATION DOT UN/ID No. : UN2924 Proper shipping name : Flammable liquids, corrosive, n.o.s., (2-Propanol, Ethanolamine) Class or Division : 3 Packing group : III Label(s) : 3 (8) 7/9

8 RQ Substance(s) : 2-Propyn-1-ol IATA NOTE: This Product will meet the definition of a U.S. DOT Hazardous Substance when the noted RQ substance is shipped in the amount as specified in 49CFR Appendix A. UN/ID No. : UN2924 Proper shipping name : Flammable liquid, corrosive, n.o.s., (2-Propanol, Ethanolamine) Class or Division : 3 Packing group : III Label(s) : 3 (8) IMDG TDG UN/ID No. : UN2924 Proper shipping name : FLAMMABLE LIQUID, CORROSIVE, N.O.S., (2-Propanol, Ethanolamine) Class or Division : 3 Packing group : III Label(s) : 3 (8) UN/ID No. : UN2924 Proper shipping name : FLAMMABLE LIQUID, CORROSIVE, N.O.S., (2-Propanol, Ethanolamine) Class or Division : 3 Packing group : III Label(s) : 3 (8) Further Information The transportation information is not intended to convey all specific regulatory data relating to this material. For complete transportation information, contact an Air Products customer service representative. 15. REGULATORY INFORMATION Toxic Substance Control Act (TSCA) 12(b) Component(s): None. OSHA Hazard Communication Standard (29 CFR ) Hazard Class(es) Corrosive. Flammable. Highly Toxic. Country Regulatory list Notification USA TSCA Included on Inventory. EU EINECS Included on EINECS inventory or polymer substance, monomers included on EINECS inventory or no longer polymer. Canada DSL Included on Inventory. Australia AICS Included on Inventory. Japan ENCS Not on Inventory. South Korea ECL Included on Inventory. China SEPA Included on Inventory. 8/9

9 Philippines PICCS Included on Inventory. EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification Fire Hazard. Acute Health Hazard EPA SARA Title III Section 313 (40 CFR 372) Component(s) above 'de minimus' level Propanol, 2-2-Propyn-1-ol US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65) WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Chloromethane WHMIS Hazard Classification Flammable Liquid, Very Toxic Material Causing Immediate and Serious Toxic Effects, Toxic Material Causing Other Toxic Effects, Corrosive Material 16. OTHER INFORMATION HMIS Rating Health : 3 Flammability : 3 Physical hazard : 0 Prepared by Telephone : Air Products and Chemicals, Inc. Global EH&S Product Safety Department : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv Preparation Date : 12/27/2009 For additional information, please visit our Product Stewardship web site at 9/9