SAFETY DATA SHEET. Blῡgloo Light Cure Adhesive. : Blῡgloo Light Cure Adhesive. : Dental product: Adhesive./Curing

Transcription

1 Section 1. Identification SAFETY DATA SHEET Blῡgloo Light Cure Adhesive Product identifier Product code Other means of identification Product type Blῡgloo Light Cure Adhesive Paste. Relevant identified uses of the substance or mixture and uses advised against Product use Dental product Adhesive./Curing Area of application Professional applications. Manufacturer Ormco Corporation 1332 S. Lone Hill Avenue Glendora, CA Telephone no address of person responsible for this SDS Emergency telephone number (with hours of operation) Section 2. Hazard identification CHEMTREC (24 hours) U.S International Classification of the substance or mixture Not classified. GHS label elements Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Supplemental label elements No signal word. No known significant effects or critical hazards. Not applicable. Not applicable. Not applicable. Not applicable. Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity 17% Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity 18. 3% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity 97.2% Health effects are based on the uncured material. Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 1/10

2 Section 3. Composition/information on ingredients Substance/mixture Other means of identification Mixture Ingredient name % (w/w) CAS number 2,3epoxypropyl Propylidynetrimethanol, ethoxylated, esters with acrylic acid trimethoxysilylpropyl There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. Firstaid measures Description of necessary first aid measures Eye contact Inhalation Skin contact Ingestion No special measures are required. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. No special measures required. If inhaled, remove to fresh air. Get medical attention if symptoms occur. No special measures required. In case of contact, immediately flush skin with plenty of water. Get medical attention if symptoms occur. Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Get medical attention if adverse health effects persist or are severe. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact No known significant effects or critical hazards. Inhalation No known significant effects or critical hazards. Skin contact No known significant effects or critical hazards. Ingestion No known significant effects or critical hazards. Overexposure signs/symptoms Eye contact Inhalation Skin contact Ingestion Indication of immediate medical attention and special treatment needed, if necessary Notes to physician Specific treatments Protection of firstaiders In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. No specific treatment. In case of major fire and large quantities No action shall be taken involving any personal risk or without suitable training. See toxicological information (Section 11) Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 2/10

3 Section 5. Firefighting measures Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. Do not use water jet. Specific hazards arising from the chemical Hazardous thermal decomposition products In a fire or if heated, a pressure increase will occur and the container may burst. Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Formaldehyde. Special protective actions for firefighters Special protective equipment for firefighters Section 6. Accidental release measures In case of major fire and large quantities Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Firefighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. Personal precautions, protective equipment and emergency procedures For nonemergency personnel For emergency responders Low release. For professional use only. Handling of product in very small amounts or in situations where release is highly unlikely Low release. See also the information in "For nonemergency personnel". Environmental precautions Low release. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Methods and materials for containment and cleaning up Small spill Large spill Section 7. Handling and storage Precautions for safe handling Protective measures Advice on general occupational hygiene Small Quantity. For professional use only. Absorb with an inert material and place in an appropriate waste disposal container. Small Quantity. For professional use only. Absorb with an inert material and place in an appropriate waste disposal container. No special measures are required for small quantities under normal and intended conditions of product use. For professional use only. Put on appropriate personal protective equipment (see Section 8). Handle with care and dispose in a safe manner. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 3/10

4 Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Ingredient name Exposure limits 2,3epoxypropyl AIHA WEEL (United States, 10/2011). Absorbed through skin. Skin sensitizer. TWA 0.5 ppm 8 hours. Appropriate engineering controls Environmental exposure controls No special measures are required for small quantities under normal and intended conditions of product use. No special measures are required for small quantities under normal and intended conditions of product use. Individual protection measures Hygiene measures Eye/face protection Skin protection Hand protection Body protection Other skin protection Respiratory protection No special measures are required for small quantities under normal and intended conditions of product use. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection safety glasses with sideshields. Chemicalresistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. No special measures are required for small quantities under normal and intended conditions of product use. Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. No special measures are required for small quantities under normal and intended conditions of product use. Section 9. Physical and chemical properties Appearance Physical state Color Odor Odor threshold ph Melting point Boiling point Liquid. [Paste.] Various Fruity esterlike Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 4/10

5 Section 9. Physical and chemical properties Flash point Evaporation rate Vapor pressure Vapor density Relative density Solubility Partition coefficient n octanol/water Autoignition temperature Flammability (solid, gas) Not applicable. Lower and upper explosive (flammable) limits Decomposition temperature Viscosity Flow time (ISO 2431) 1.16 Insoluble in the following materials cold water and hot water. Section 10. Stability and reactivity Reactivity No specific test data related to reactivity available for this product or its ingredients. Chemical stability The product is stable. Possibility of hazardous reactions Hazardous reactions or instability may occur under certain conditions of storage or use. Hazardous polymerization may occur under certain conditions of storage or use. Conditions to avoid Keep away from heat and direct sunlight. Heat can cause polymerization with rapid release of energy. Incompatible materials Reactive or incompatible with the following materials oxidizing materials and reducing materials. Peroxide. Amine. Hazardous decomposition products Section 11. Toxicological information Information on toxicological effects Acute toxicity 2,3epoxypropyl Propylidynetrimethanol, ethoxylated, esters with acrylic acid 3trimethoxysilylpropyl Under normal conditions of storage and use, hazardous decomposition products should not be produced. Product/ingredient name Result Species Dose Exposure LD50 Dermal Rabbit 450 mg/kg LD50 Dermal Rat 483 mg/kg LD50 Oral Rat 500 mg/kg LD50 Dermal Rabbit >13 g/kg LD50 Oral Rat mg/kg Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 5/10

6 Section 11. Toxicological information Irritation/Corrosion 2,3epoxypropyl Propylidynetrimethanol, ethoxylated, esters with acrylic acid Mutagenicity Carcinogenicity Reproductive toxicity Teratogenicity Product/ingredient name Result Species Score Exposure Observation 3trimethoxysilylpropyl Skin Eyes Respiratory Sensitization Skin Respiratory Eyes Moderate irritant Rabbit 100 microliters Skin Severe irritant Rabbit 24 hours 500 microliters Eyes Moderate irritant Rabbit 100 milligrams Skin Moderate irritant Rabbit 500 milligrams Eyes Mild irritant Rabbit 24 hours 500 milligrams Skin Mild irritant Rabbit 24 hours 500 milligrams Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Information on the likely routes of exposure Potential acute health effects Eye contact Inhalation Skin contact Ingestion Routes of entry anticipated Oral, Dermal, Inhalation. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 6/10

7 Section 11. Toxicological information Symptoms related to the physical, chemical and toxicological characteristics Eye contact Inhalation Skin contact Ingestion Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects Potential delayed effects Long term exposure Potential immediate effects Potential delayed effects Potential chronic health effects General Carcinogenicity Mutagenicity Teratogenicity Developmental effects Fertility effects No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Route Oral Dermal ATE value mg/kg mg/kg Section 12. Ecological information Toxicity Product/ingredient name 3trimethoxysilylpropyl Result Species Exposure Acute LC50 >100 mg/l Fish Danio rerio 96 hours Persistence and degradability Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 7/10

8 Section 12. Ecological information Product/ingredient name Test Result Dose 3trimethoxysilylpropyl Product/ingredient name Aquatic halflife Photolysis Biodegradability 3trimethoxysilylpropyl OECD 301F Ready Biodegradability Manometric Respirometry Test 69 % Readily 28 days Inoculum Readily Bioaccumulative potential Product/ingredient name LogPow BCF Potential 2,3epoxypropyl 0.96 low Propylidynetrimethanol, 2.89 low ethoxylated, esters with acrylic acid 3trimethoxysilylpropyl 2.1 low Mobility in soil Soil/water partition coefficient (KOC) Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods Section 14. Transport information The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. TDG Classification DOT Classification ADR/RID IMDG IATA UN number Not regulated. Not regulated. Not regulated. Not regulated. Not regulated. UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. No. No. No. No. Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 8/10

9 Section 14. Transport information Special precautions for user Transport within user s premises always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according to Annex II of MARPOL and the IBC Code Section 15. Regulatory information Canadian lists Canadian NPRI CEPA Toxic substances inventory International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. Section 16. Other information History Date of issue/date of revision Date of previous issue Version Key to abbreviations None of the components are listed. None of the components are listed. At least one component is not listed in DSL but all such components are listed in NDSL. 08/09/2017 No previous validation Procedure used to derive the classification 1 ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of ("Marpol" = marine pollution) UN = United Nations HPR = Hazardous Products Regulations Not classified. Classification Justification Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 9/10

10 Section 16. Other information References Indicates information that has changed from previously issued version. Notice to reader HPR = Hazardous Products Regulations To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue/date of revision 08/09/2017 Date of previous issue No previous validation Version 1 10/10