Safety Data Sheet. Triton X-45. In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week)

Transcription

1 Safety Data Sheet Triton X PRODUCT AND COMPANY IDENTIFICATION Product Name: Triton X-45 Synonyms/Generic Names: Polyethylene glycol 4-tert-octylphenyl ether; 4-(1,1,3,3- Tetramethylbutyl)phenyl-polyethylene glycol; Alcohol C13-C15 Poly (1-6) Ethoxylate Product Number: 5946 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information Call: (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION OSHA Hazards: Harmful by ingestion, Irritant Target Organs: None Signal Word: Danger Pictograms: GHS Classification: Acute toxicity, Oral Category 4 irritation Category 3 Serious eye damage Category 1 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 2 GHS Label Elements, including precautionary statements: Hazard Statements: H302 Harmful if swallowed. H316 Causes mild skin irritation. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects. Revised on 01/28/2013 Page 1 of 6

2 Precautionary Statements: P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Potential Health Effects Causes eye irritation. Inhalation May be harmful if inhaled. Causes respiratory tract irritation. May be harmful if absorbed through skin. Causes skin irritation. Ingestion Harmful if swallowed. NFPA Ratings Health 3 Flammability 1 Reactivity 0 Specific hazard HMIS Ratings Health 3 Fire 1 Reactivity 0 Personal J 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % CAS # Polyethylene glycol 4- tert-octylphenyl ether EINECS# / ELINCS# Formula Molecular Weight N/A (C 2 H 4 O) n C 14 H 22 O N/A 4. FIRST-AID MEASURES Inhalation Ingestion In case of eye contact, immediately rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention immediately. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention immediately. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Specific hazards arising from the chemical Product is flammable. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use appropriate media for adjacent fire. Cool containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Emits toxic fumes (carbon oxides) under fire conditions. (See also Stability and Reactivity section). 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions See section 8 for recommendations on the use of personal protective equipment. Prevent spillage from entering drains. Any release to the environment Revised on 01/28/2013 Page 2 of 6

3 Methods and materials for containment and cleaning up may be subject to federal/national or local reporting requirements. Absorb spill with noncombustible absorbent material, then place in a suitable container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of aerosols. Conditions for safe storage, including any incompatibilities Store in cool, dry well ventilated area. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Contains no substances with occupational exposure limit values. Personal Protection Wear chemical safety glasses or goggles with face shield. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear nitrile or rubber gloves, and complete body suit. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limit Vapor pressure Vapor density Density Solubility (ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Transparent yellow liquid. Mild. > 200 C (> 392 F) 251 C (484 F) Flammable Not Explosive Revised on 01/28/2013 Page 3 of 6

4 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable Will not occur. Excessive heat, flames, sparks. Strong bases, strong acids, strong oxidizing agents. Carbon oxides. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA LD50 Dermal - rabbit - 8,000 mg/kg LD50 Oral - rat - 1,800 mg/kg as probable, possible or confirmed human carcinogen by IARC. as a carcinogen or potential carcinogen by ACGIH. as a known or anticipated carcinogen by NTP. as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Irritation, redness. Irritation, redness, watering eyes. Respiratory Irritation, coughing. Ingestion Irritation, nausea, vomiting, diarrhea. Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization 12. ECOLOGICAL INFORMATION Ecotoxicity Aquatic Vertebrate Aquatic Invertebrate Terrestrial EC50 - Daphnia - 26 mg/l - 48 h Persistence and Degradability Bioaccumulative Potential Mobility in Soil Biotic/Aerobic Biochemical oxygen demand Result: 36 % - Not readily biodegradable. Method: Closed Bottle test Revised on 01/28/2013 Page 4 of 6

5 PBT and vpvb Assessment Other Adverse Effects Chemical Oxygen Demand (COD): 2.19 mg/g Toxic to aquatic life with long lasting effects. 13. DISPOSAL CONSIDERATIONS Waste Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residues. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION US DOT UN3082, Environmentally hazardous substances liquid, n.o.s., (Alcohol C13- C15 poly (1-6) ethoxylate), 9, pg III TDG UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES LIQUID, N.O.S., (ALCOHOL C13-C15 POLY (1-6) ETHOXYLATE), 9, PG III IMDG UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES LIQUID, N.O.S., (ALCOHOL C13-C15 POLY (1-6) ETHOXYLATE), 9, PG III Marine Pollutant Yes IATA/ICAO UN3082, Environmentally hazardous substances liquid, n.o.s., (Alcohol C13- C15 poly (1-6) ethoxylate), 9, pg III 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 WHMIS Canada All ingredients are listed on the TSCA inventory. All ingredients are listed on the DSCL inventory. Alcohol C13-C15 Poly (1-6) Ethoxylate Alcohol C13-C15 Poly (1-6) Ethoxylate CLASS D-2B: Material causing other toxic effects (TOXIC). Revised on 01/28/2013 Page 5 of 6

6 16. OTHER INFORMATION Revision Date Revision 1 01/28/2013 Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 01/28/2013 Page 6 of 6