SAFETY DATA SHEET Water, oil, grease & dirt repellent for leather

Transcription

1 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Product name Product use Telephone No. Fax Country A completly invisble protection that doen not alter the feel of the surface Company/undertaking identification Manufacturer HG International b.v. Telephone No. +31 (0) Address Damsluisweg 70 Fax +31 (0) EJ Almere Internet Country Netherlands Importer HG UK Address Unit 11 Grange Way Business Park Whitehall Road Industrial Estate Uk Colchester Essex CO2 8HF United Kingdom (UK) Composition/information on ingredients Substance/preparation United Kingdom (UK) Preparation See section 16 for the full text of the R Phrases declared above * Occupational Exposure Limit(s), if available, are listed in Section 8 CAS number EC Number % Naphtha (petroleum), hydrotreated light F; R11 Xn; R65 Xi; R38 R67 N; R51/53 n-butyl acetate R10 R66, Hazards identification The substance is classified as dangerous according to Directive 67/548/EEC and its amendments. Classification Physical/chemical hazards Human health hazards Environmental hazards F+; R12 Xi; R38 R66, R67 N; R51/53 Extremely flammable. Classification Irritating to skin. Repeated exposure may cause skin dryness or cracking.vapours may cause drowsiness and dizziness. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Page 1/7

2 Additional Hazards Pressurised container protect from sunlight and do not expose to temperature exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. See section 11 for more detailed information on health effects and symptoms. 4. First aid measures Inhalation Ingestion Skin Contact Eye contact First aid measures Notes to physician Specific treatments If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if symptoms appear. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. In case of contact, immediately flush skin copiously with water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain medical attention immediately. In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Get medical attention if irritation occurs. See section 11 for more detailed information on health effects and symptoms. 5. Fire-fighting measures Extinguishing media Special exposure hazards Hazardous thermal decomposition products In case of fire, use water spray (fog), foam, dry chemical or CO2 extinguisher or spray. Extremely flammable liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas, travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. This material is toxic to aquatic organisms. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. These products are carbon oxides (CO, CO2). Special protective equipment for fire-fighters Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal Precautions Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Do not touch or walk through spilled material. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) and use a nonsparking or explosion proof means to transfer material to a sealed, appropriate container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Note see section 8 for personal protective equipment and section 13 for waste disposal. Page 2/7

3 7. Handling and storage Handling Storage Packaging materials Recommended Specific uses Avoid contact with skin and clothing. Keep container closed. Use only with adequate ventilation. Keep away from heat, sparks and flame. To avoid fire or explosion, dissipate static electricity during transfer by earthing and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Avoid contact of spilled material and runoff with soil and surface waterways. Wash thoroughly after handling. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Use original container. 8. Exposure controls/personal protection United Kingdom (UK) Respiratory protection Hand protection Eye protection Occupational exposure limits n-butyl acetate EH40-WEL (United Kingdom (UK), 1/2005). STEL 966 mg/m 3 15 minute(s). Form All forms STEL 200 ppm 15 minute(s). Form All forms TWA 724 mg/m 3 8 hour(s). Form All forms TWA 150 ppm 8 hour(s). Form All forms 9. Exposure controls Occupational exposure controls Skin protection Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are close to the workstation location. A respirator is not needed under normal and intended conditions of product use. Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hour(s) (breakthrough time) polyvinyl alcohol (PVA) safety glasses with side shields Work uniform or laboratory coat. Physical and chemical properties General information Appearance Physical state Colour Odour ph Flash point Flammability (solid, gas) Liquid. (Aerosol.) Clear. Colourless. Characteristic. Important health, safety and environmental information Melting point Boiling point Not applicable. May start to solidify at -78 C ( F) based on data for n-butyl acetate. The lowest known value is 126 C (258.8 F) (n-butyl acetate). Closed cup Between -18 C (0 F) and 23 C (73 F). (Pensky-Martens.) Yes, applicable. Page 3/7

4 Explosive properties Explosion Limits Oxidising properties Relative density Solubility Evaporation rate (butyl acetate = 1) Other information 10. Auto-ignition temperature Stability and reactivity Stability Conditions to Avoid Materials to avoid Hazardous Decomposition Products 11. This safety data sheet is prepared in accordance with EU Lower 0.8% Upper 10% Not applicable 0.66 g/ml (20 C / 68 F) Easily soluble in methanol, diethyl ether, n-octanol. Very slightly soluble in cold water, hot water. 1 (n-butyl acetate) compared to Butyl acetate. The lowest known value is 392 C (737.6 F) (Naphtha (petroleum), hydrotreated light). The product is stable. Toxicological information Keep away from heat, sparks and flame. Stable under recommended storage and handling conditions (see section 7). Reactive with oxidising agents, acids. These products are carbon oxides (CO, CO2). Potential acute health effects Inhalation Ingestion Skin Contact Eye contact Acute toxicity n-butyl acetate Practically non-toxic by inhalation. Irritating to skin. May cause eye irritation. Test Result Route Species mg/kg 3200 mg/kg 4300 mg/kg >17600 mg/kg >17600 mg/kg Oral Oral Oral Dermal Dermal Rat Rabbit Mammal Rabbit Rabbit Carcinogenicity Mutagenicity Reproductive toxicity Over-exposure signs/symptoms Inhalation Ingestion Skin Target organs Contains material which causes damage to the following organs upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. Other adverse effects Page 4/7

5 12. Ecological information Ecotoxicity data n-butyl acetate Other adverse effects 13. This safety data sheet is prepared in accordance with EU Disposal considerations Methods of disposal Waste classification Hazardous waste 14. International transport regulations Regulatory information ADR/RID Class Species Period Result Pimephales promelas (EC50) Pimephales promelas (LC50) Lepomis macrochirus (LC50) 48 hour(s) 96 hour(s) 96 hour(s) 19 mg/l 18 mg/l 100 mg/l Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Not applicable. Transport information The classification of the product may meet the criteria for a hazardous waste UN number Proper shipping name Class Packing group Label Additional Information UN, "dangerous goods in limited quantities of class 2", III, Aerosol, ADR (Naphtha (petroleum), hydrotreated light) 2.1 III 2 Hazard identification number None Reportable quantity 30 Remarks Dangerous goods in limited quantities ADN Class UN "dangerous goods in limited quantities of class 2", III, Aerosol, ADNR (Naphtha (petroleum), hydrotreated light) 2.1 III 3 RQ (Reportable quantity) ADN 30 Remarks Dangerous goods in limited quantities IMDG Class "dangerous goods in limited quantities of class 2" UN, Aerosol (Naphtha (petroleum), hydrotreated light). Marine pollutant 2.1 III 2 Emergency schedules (EmS) F-D, S-U Marine pollutant Marine pollutant (P) Page 5/7

6 Reportable quantity 30 Remarks Dangerous goods in limited quantities IATA-DGR Class "dangerous goods in limited quantities of class 2" UN, Aerosol (Naphtha (petroleum), hydrotreated light) 2.2 III Regulatory information EU Regulations Hazard symbol(s) Risk Phrases Safety Phrases Other EU regulations Product use Other EU regulations Additional warning phrases Tactile warning of danger EC Statistical classification (Tariff Code) Ingredients identification information R12- Extremely flammable. R38- Irritating to skin. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S2- Keep out of the reach of children. S16- Keep away from sources of ignition - No smoking. S23- Do not breathe aerosol. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label. S51- Use only in well-ventilated areas. Pressurised container protect from sunlight and do not expose to temperature exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition. - Do not smoke. Yes, applicable. Extremely flammable, Irritant, Dangerous for the environment. Classification and labelling have been performed according to EU directives 67/548/EEC, 1999/45/EC, including amendments and the intended use. - Consumer applications % and more aliphatic hydrocarbons. Page 6/7

7 16. Other information Full text of R phrases referred to in sections 2 and 3 - United Kingdom (UK) Full text of classifications referred to in sections 2 and 3 - United Kingdom (UK) History Date of printing Version Verified by T. Rutgers. R12- Extremely flammable. R11- Highly flammable. R10- Flammable. R65- Harmful may cause lung damage if swallowed. R38- Irritating to skin. R66- Repeated exposure may cause skin dryness or cracking. R67- Vapours may cause drowsiness and dizziness. R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. F+ - Extremely flammable F - Highly flammable Xn - Harmful Xi - Irritant N - Dangerous for the environment Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version 5.05 Page 7/7