SAFETY DATA SHEET. ZRC Zero-VOC Water-Based Galvanizing Compound - Liquid Component

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code Recommended use Recommended restrictions Corrosion protection of iron and steel. ne known. Manufacturer / Importer / Supplier / Distributor information Supplier/Manufacturer ZRC Worldwide Address 145 Enterprise Drive, Marshfield, MA Telephone Emergency telephone CCN15781 (CHEMTREC) 2. Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Skin corrosion/irritation Serious eye damage/eye irritation Category 2 Category 2A Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Warning Causes serious eye irritation. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. Supplemental information ne. 3. Composition/information on ingredients Mixtures Chemical name Silicic acid, lithium salt Lithium Hydroxide CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Skin contact If symptomatic, move to fresh air. Get medical attention if symptoms persist. Wash skin with soap and water. Get medical attention promptly if symptoms occur after washing. Eye contact Remove contact lenses, if present and easy to do. Flush eyes thoroughly with water for at least 15 minutes. Get medical attention Version #: 01 Revision date: - Issue date: 14-December / 6

2 Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Seek medical advice. Irritant effects. Treat symptomatically. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 5. Fire-fighting measures Suitable extinguishing media Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up restrictions known. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Cool containers exposed to flames with water until well after the fire is out. Wear appropriate personal protective equipment (See Section 8). Stop leak if you can do so safely. Absorb spill with appropriate sand, clay or other inert sorbent material, then place in appropriate waste container. Environmental precautions Large Spills: Flush area with water. Treat runoff per applicable environmental regulations pertaining to drains, water courses and ground water, diking if required. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Observe good industrial hygiene practices. Avoid inhalation of vapors and contact with skin and eyes. Keep out of reach of children. Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits Keep container closed. Store away from incompatible materials. Ideal storage temperature is 0 to 43 C (32 to 109 F). US. Workplace Environmental Exposure Level (WEEL) Guides Components Lithium Hydroxide (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls Type Ceiling Value biological exposure limits noted for the ingredient(s). Follow standard monitoring procedures. 1 mg/m3 Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Wear approved safety glasses or goggles. Wear face shield if there is risk of splashes. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Suitable gloves can be recommended by the glove supplier. Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. Use suitable protective equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants Version #: 01 Revision date: - Issue date: 14-December / 6

3 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Milky liquid. Liquid. Liquid. White. Odorless. 212 F (100 C) > 1 (Butyl acetate=1) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density 1.19 Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Bulk density VOC (Weight %) 17.5 mm Hg (25 C / 77 F) 0.67 (25 C / 77 F) Completely soluble in water. 200 mpa s (25 C / 77 F) 9.9 lb/gal 0 g/l 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non reactive under normal conditions of storage and transport. Material is stable under normal conditions. Hazardous polymerization does not occur. Contact with incompatible materials. Freezing. Elevated temperatures. Strong oxidizers, strong acids, and strong bases. hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion harmful effects expected in amounts likely to be ingested by accident. Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Causes skin irritation. Causes serious eye irritation. Irritant effects Version #: 01 Revision date: - Issue date: 14-December / 6

4 Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity May cause discomfort if swallowed. Causes skin irritation. Causes serious eye irritation. t a skin sensitizer. Persistence and degradability data available. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. The product is not expected to bioaccumulate. DOT t regulated as a hazardous material by DOT. IATA t regulated as a dangerous good. IMDG t regulated as a dangerous good. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Dispose in accordance with all applicable regulations. Do not allow runoff to sewer, waterway or ground. Waste codes should be assigned by the user based on the application for which the product was used. Dispose of in accordance with local regulations. Since emptied containers may retain product residue, follow label warnings even after container is emptied. This substance/mixture is not intended to be transported in bulk. US federal regulations This product is hazardous according to OSHA 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) US. OSHA Specifically Regulated Substances (29 CFR ) t listed. CERCLA Hazardous Substance List (40 CFR 302.4) t listed Version #: 01 Revision date: - Issue date: 14-December / 6

5 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) US state regulations US. Massachusetts RTK - Substance List This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance t listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date - Version # 01 Further information 14-December-2013 I - Safety Glasses, Gloves, Dust, Vapor Respirator Version #: 01 Revision date: - Issue date: 14-December / 6

6 NFPA Ratings References Disclaimer ACGIH EPA: Acquire database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices ESIS (European chemical Substances Information System) HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment Version #: 01 Revision date: - Issue date: 14-December / 6