Version: 1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

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1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Benzoin Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Oil essence, odorous substance Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2

2 Substance Mixture Page 2 Chemical Characterization: Benzoin is a natural resin. Gum Benzoin Sumatra (CAS No ; EINECS ) Free benzoic acid, free cinnamic acid, vanillin, cinnamic acid phenylpropylester, cinnamic acid cinnamic ester styracine. stryrene, benzaldehyde, resin cinnamic acid and benzoic acid ester of the delta resinol acid and of the benzoic resinol. Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. No special measures required. Wash off with warm water. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. If symptoms persist consult physician. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, carbon dioxide (CO2), extinguishing powder, water spray Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. Special hazards: 3

3 5. 3. Advice for Firefighters Page 3 Protective equipment: Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Cool exposed containers with water spray. Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions No special measures required Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Protective clothing, see Section 8. Provide adequate ventilation. Avoid formation of dust Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in a cool and dry place. Do not store together with food stuff and animal feed. No special measures necessary. No special measures necessary Further Information: Specific End Use(s) Further information: 4

4 8. Exposure Controls/Personal Protection Parameters to be Controlled Page 4 Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. In case of formation of dust. Protective gloves (EN 374) Please note the manufacturers detailed statements, especially about the minimum thickness and the minimum breakthrough time. Safety glasses with protective shields (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: Odor: Odor threshold: ph-value: almond shaped pieces reddish brown resin-like 5

5 Melting temperature: not determined Page 5 Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: not determined no information available no information available not determined insoluble not determined no information available Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: 6

6 Solid content: Page Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: No further information. Stable if used according to specifications. Stable if used according to specifications. Unknown. Avoid direct sunlight and heat. No further information available. None if stored and handled according to specifications. > 5000 mg/kg (rat) Non irritating Non-irritating to eyes No information available Not known. Mutagenicity: 7

7 Page Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): No health impairments known or expected when used according to specifications. No toxicity expected. Readily biodegradable. No special effects or hazards known. If product cannot be reused or recycled, it has to be disposed of according to current local regulations. 8

8 Page 8 Uncleaned packaging: Uncontaminated packaging may be recycled. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User Not classified as environmentally hazardous. Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Not classified as a dangerous good under transport regulations Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 9

9 0, not hazardous (self-assessment) Page Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.