SAFETY DATA SHEET. Oatey Silver Lead Free and Safe-Flo Solder. Hazardous to the aquatic environment, acute hazard Not classified.

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1 1. Identification Product identifier Other means of identification SAFETY DATA SHEET SDS number 1601E Synonyms Part Numbers: 22027, 23000, 23001, 23002, 29030, 29024, 29025, 53061, 53180, 53062, 53188, 53064, 53195, 50683, 50684, 50691, 50962, 53013, Recommended use Joining Copper Pipes. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Oatey Co. Address 4700 West 160th St. Cleveland, OH Telephone Transport Emergency Chemtrec (Outside the US ) Emergency First Aid Contact person MSDS Coordinator 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Hazardous to the aquatic environment, acute hazard Category 1 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Warning Very toxic to aquatic life. Avoid release to the environment. Collect spillage. Store away from incompatible materials. Dispose of contents/container in accordance with local/regional/national/international regulations. Heating above the melting point releases metallic oxides which may cause metal fume fever by inhalation. The symptoms are shivering, fever, malaise and muscular pain. 3. Composition/information on ingredients Mixtures Chemical name CAS number % Tin Bismuth Copper Silver *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6

2 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Wash off with soap and water. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. Get medical attention if symptoms occur. Direct contact with eyes may cause temporary irritation. Provide general supportive measures and treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Water fog. Foam. Dry chemical powder. Dry sand. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to cool unopened containers. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or emergency procedures spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Stop the flow of material, if this is without risk. Collect spillage. Prevent entry into waterways, containment and cleaning up sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions 7. Handling and storage Precautions for safe handling Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Avoid prolonged exposure. Avoid breathing dust/fume/gas/mist/vapors/spray. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (see Section 10 including any incompatibilities of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Components Type Value Form PEL 1 mg/m3 Dust and mist. 0.1 mg/m3 Fume. PEL 0.01 mg/m3 Tin (CAS ) PEL 2 mg/m3 US. ACGIH Threshold Limit Values Components Type Value Form Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6

3 TWA 0.1 mg/m3 Dust and fume. Tin (CAS ) TWA 2 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form TWA 1 mg/m3 Dust and mist. TWA 0.01 mg/m3 Dust. Tin (CAS ) TWA 2 mg/m3 Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Physical state Odor Form Color Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Wear protective gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Solid wire. Solid. Solid. Silver F ( C) Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (noctanol/water) Auto-ignition temperature Decomposition temperature Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6

4 Viscosity 10. Stability and reactivity Reactivity Chemical stability The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Contact with incompatible materials. Acids. Chlorine. No hazardous decomposition products are known. Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Ingestion Direct contact with eyes may cause temporary irritation. Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity This product is not expected to cause skin sensitization. No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects No data available. 13. Disposal considerations Disposal instructions This product is not expected to cause reproductive or developmental effects. Prolonged inhalation may be harmful. Very toxic to aquatic life. No data is available on the degradability of this product. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6

5 Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT IATA Not regulated as dangerous goods. Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR ) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) No LISTED LISTED Chemical name CAS number % by wt. Copper Silver Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK - Substance List Tin (CAS ) Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6

6 US. New Jersey Worker and Community Right-to-Know Act Tin (CAS ) US. Pennsylvania Worker and Community Right-to-Know Law Tin (CAS ) US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # July December-2014 HMIS ratings Health: 0 Flammability: 0 Physical hazard: 0 Disclaimer Oatey Co. cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available Version #: 02 Revision date: 10-December-2014 Issue date: 30-July / 6