Polyurethane Dispersion No. 61 PC

Transcription

1 Revised edition: Version: 3.5 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Polyurethane Dispersion No. 61 PC Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Binding agent Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H315 Cat.: 2 H319 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 Skin irritation, hazard category 2 Eye irritation, category 2 Causes skin irritation. Causes serious eye irritation. The material is not subject to classification according to EC lists Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: See Section 12. GHS07-1 2

2 Signal word: Warning Page 2 Hazard designation: Safety designation: H315 H319 P280 P337+P313 Causes skin irritation. Causes serious eye irritation. Wear protective gloves/ clothing/ eye/ face protection. If eye irritation persists: Get medical advice/ attention Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture EUH208: contains 1,2-Benzisolthiazol-3(2H)-one. Can cause allergic reactions. Chemical Characterization: Aqueous polyurethane dispersion. Hazardous Ingredients: 2-Dimethylaminoethanol (C,Xn; R10-20/21/22-34; H ); REACH Reg. No xxxx 1,2-Benzisothiazol-3(2H)-one (Xn,N; R ; H ) % < 0.01 % CAS-Nr: EINECS-Nr: EC-Nr: CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Show this safety data sheet to the doctor in attendance. Supply fresh air. Consult physician if symptoms persist. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed If symptoms persist consult physician. Symptoms: Irritates eyes and skin. 3

3 Skin contact: causes irritation and sensitization. Page Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Symptomatic treatment (decontamination, vital functions), no specific antidote known. CO2, extinguishing powder, water jet. Fight larger fire with water jet or alcohol resistant foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: Advice for Firefighters Protective equipment: Formation of hazardous decomposition products at high temperatures. In case of fire: formation of hazard fumes possible, e.g. carbon monoxide (CO), hydrogen cyanide (HCN), toxic gases/vapors. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Avoid contact with skin, eyes and clothing. Do not ingest or inhale. Wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Contain with absorbent material (sand, diatomaceous earth, universal absorbent, Oil Dri) and dispose accordingly. For information for safe handling see Section 7. Protective clothing, see Section 8. See Section 13 for information on disposal. Instructions on safe handling: 4

4 Avoid contact with eyes, skin and clothing. Provide adequate ventilation. Page Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Take off contaminated clothing immediately and reuse only after thoroughly cleaning these. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Protect from frost. Keep container tightly closed No special measures necessary. No special measures necessary. 12; Non-combustible liquids Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Does not contain any components with workplace limit values. Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 2-Dimethyaminoethanol (CAS ): 7.4 mg/m3 (worker, inahalation, long-term exposition - systemic effects) 1.04 mg/kg (worker, skin contact, long-term exposition - systemic effects) 2-Dimethyaminoethanol (CAS ): Fresh water: mg/l Sea water: mg/l Periodic release: mg/l Fresh water sediment: mg/kg Soil: mg/kg Sewage treatment system (STP): 10 mg/l Additional Information: Exposure Controls 5

5 Technical protective measures: No further measures, see Section 7. Page 5 Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory equipment required in case of insufficient ventilation, filter type A. Provide adequate ventilation. Protective gloves. The glove material has to be impermeable and resistant to the product / substance / preparation. Nitrile rubber (480 min, 0.4 mm) Fluoro carbon rubber - FKM (480 min, 0.7 mm). Tightly fitting safety goggles (EN 166). Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: Odor: Odor threshold: ph-value: liquid yellowish characteristic (20 C) Melting temperature: ca. 0 C Boiling temperature: 100 C Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: not determined 6

6 Lower explosion limit: not determined Page Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: 23 hpa (20 C) This product is a non-volatile solid g/cm3 (20 C) miscible not determined not determined mpa.s (20 C) Product does not present an explosion hazard. not determined Solid content: % Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Stable if used according to specifications. 2-Dimethylaminoethanol is released during the application and drying processes. Conditions to avoid: 7

7 Thermal decomposition: No data available Imcompatible Materials Hazardous Decomposition Products Further Information 11. Toxicological Information Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: 2-Dimethylaminoethanol: 1183 mg/kg (rat; OECD 401) 1,2-Benzisothiazol-3(2H)-one: 1193 mg/kg (rat) 2-Dimethylaminoethanol: 1219 mg/kg (rabbit; OECD 402) 1,2-Benzisothiazol-3(2H)-one: 580 mg/kg (rat) 2-Dimethylaminoethanol: 6.1 mg/kg (rat; OECD 403) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Irritating to skin. Irritating (OECD 405) Irritates the respiratory tract. No information available May cause sensitization by skin contact. No data available. No data available. Under certain circumstances 2-dimethylaminoethanol can form nitrosamines with nitrosing agents (e.g. nitrates, nitrogen oxides). Nitroseamines have shown cancerogenic effects in animal studies. Specific target organ toxicity (STOT): No data available. 8

8 Additional toxicological information: Irritating to eyes and skin. 12. Ecological Information Aquatic Toxicity Page Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods 2-Dimethylaminoethanol: LC50: mg/l (96h, Leuciscus idus) 1,2-Benzisothiazol-3(2H)-one: LC50: 2.18 mg/ml (96h, Oncorhynchus mykiss) 2-Dimethylaminoethanol: EC50: 98.4 mg/l (48h, Daphnia magna) 1,2-Benzisothiazol-3(2H)-one: EC50: 2.94 mg/ml (48h, Daphnia magna) 2-Dimethylaminoethanol: EC20: > 1000 mg/l (30 min; active sludge) 2-Dimethylaminoethanol: EC50: 66.1 mg/l (72h, Scenedesmus subspicatus) 1,2-Benzisothiazol-3(2H)-one: ErC50: 011 mg/l (72h, Pseudokirchneriella subcapitata) No data available for the mixture. 2-Diemethylaminoethanol is readily biodegradable. According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. 1, slightly hazardous Do not let product contaminate ground water, waterways or sewage system. No data available. Product: 9

9 European Waste Code (EWC): Page 9 Must not be disposed together with household garbage. Do not let product enter water systems. Dispose of according to official national and local regulations. Uncleaned packaging: Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code 10

10 Further Information 15. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Page 10 Water hazard class: 1, slightly hazardous for water (self-assessment) Local regulations on chemical accidents: Employment restrictions: The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.