SAFETY DATA SHEET Provalue Concentrated Multipurpose Cleaner

Transcription

1 Revision Date 05/06/2013 Revision 3 Supersedes date 05/06/2013 SAFETY DATA SHEET Provalue Concentrated Multipurpose Cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue Concentrated Multipurpose Cleaner PV10005 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Multi-Purpose Cleaner 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC P14 Contains Perfume. May produce an allergic reaction. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 2-(2-Butoxyethoxy)Ethanol 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xi;R36. 1 / 7

2 Provalue Concentrated Multipurpose Cleaner Dodecylbenzene sulphonic acid 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xn;R22. C;R34. SODIUM HYDROXIDE < 1 CAS-No.: EC No.: Classification (EC 1272/2008) Skin Corr. 1A - H314 Classification (67/548/EEC) C;R35 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Do not induce vomiting. Get medical attention if any discomfort continues. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion May cause stomach pain or vomiting. Skin contact Prolonged skin contact may cause redness and irritation. Eye contact Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. 2 / 7

3 Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES Provalue Concentrated Multipurpose Cleaner 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb with inert, damp, non-combustible material, then flush area with water. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes 2-(2-Butoxyethoxy)Ethanol WEL 10 ppm 67.5 mg/m3 15 ppm mg/m3 SODIUM HYDROXIDE WEL 2 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Gloves are recommended for prolonged use. Eye protection No specific eye protection noted, but may be required anyway. Other Protection Wear suitable protective clothing as protection against splashing or contamination. 3 / 7

4 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Provalue Concentrated Multipurpose Cleaner 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Initial boiling point and boiling range ( C) Melting point ( C) Mobile Liquid Blue. Characteristic. Soluble in water. Relative density Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G H2O@20 C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability 4 / 7

5 Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Provalue Concentrated Multipurpose Cleaner Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: Viscosity 5 / 7

6 Provalue Concentrated Multipurpose Cleaner Inhalation No specific health warnings noted. Ingestion May cause stomach pain or vomiting. Skin contact May cause defatting of the skin, but is not an irritant. Eye contact May cause severe irritation to eyes. Target Organs No specific target organs noted SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name 6 / 7

7 Provalue Concentrated Multipurpose Cleaner Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Not known Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Revision Date 05/06/2013 Revision 3 Supersedes date 05/06/2013 SDS No. 2 Date 5/6/2013 Risk Phrases In Full R34 R35 R22 R36 NC Hazard Statements In Full H314 Causes burns. Health & Safety Officer Causes severe burns. Harmful if swallowed. Irritating to eyes. Causes severe skin burns and eye damage. 7 / 7

8 Revision Date 07/06/2013 Revision 3 Supersedes date 06/06/2013 SAFETY DATA SHEET Provalue RTU Citrus Disinfectant SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue RTU Citrus Disinfectant PV10011 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Washroom Cleaner 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC S2 Keep out of the reach of children. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures ETHANOL < 1 CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 2 - H225 Classification (67/548/EEC) F;R11 1 / 7

9 Provalue RTU Citrus Disinfectant The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Do not induce vomiting. Get medical attention if any discomfort continues. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion Nausea, vomiting. Skin contact Prolonged skin contact may cause redness and irritation. Eye contact May cause temporary eye irritation Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb with inert, damp, non-combustible material, then flush area with water. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 2 / 7

10 Provalue RTU Citrus Disinfectant 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes ETHANOL WEL 1000 ppm 1920 mg/m3 WEL = Workplace Exposure Limit Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Gloves are recommended for prolonged use. Eye protection No specific eye protection noted, but may be required anyway. Other Protection No specific protective equipment noted, but may be required anyway. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Mobile Liquid Colour Light (or pale). Red. Odour Fruity. Solubility Soluble in water. Initial boiling point and boiling range ( C) Melting point ( C) Relative density Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor 3 / 7

11 ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties Provalue RTU Citrus Disinfectant 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) 4 / 7

12 Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Provalue RTU Citrus Disinfectant Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: Viscosity Inhalation No specific health warnings noted. Ingestion May cause stomach pain or vomiting. Skin contact May cause defatting of the skin, but is not an irritant. Eye contact Irritating and may cause redness and pain. Target Organs No specific target organs noted SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Acute Fish Toxicity Not considered toxic to fish. 5 / 7

13 Provalue RTU Citrus Disinfectant Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture 6 / 7

14 Uk Regulatory References Provalue RTU Citrus Disinfectant The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU Legislation REGULATION (EU) No 528/2012 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 22 May 2012 concerning the making available on the market and use of biocidal products Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Revision Date 07/06/2013 Revision 3 Supersedes date 06/06/2013 SDS No. 2 Date 6/6/2013 Risk Phrases In Full R11 NC Hazard Statements In Full H225 Health & Safety Officer Highly flammable Highly flammable liquid and vapour. 7 / 7

15 Revision Date 07/06/2013 Revision 3 Supersedes date 07/06/2013 SAFETY DATA SHEET Provalue RTU Washroom Cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue RTU Washroom Cleaner PV10017 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Washroom Cleaner 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC S2 P14 Keep out of the reach of children. Contains. May produce an allergic reaction. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Get medical attention if any discomfort continues. 1 / 7

16 Ingestion Provalue RTU Washroom Cleaner Immediately rinse mouth and drink plenty of water ( ml). Do not induce vomiting. Get medical attention if any discomfort continues. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion May cause stomach pain or vomiting. Skin contact No specific symptoms noted. Eye contact No specific symptoms noted Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb with inert, damp, non-combustible material, then flush area with water. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container Reference to other sections For personal protection, see section 8. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. 2 / 7

17 Storage Class Chemical storage. Provalue RTU Washroom Cleaner 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Gloves are recommended for prolonged use. Eye protection No specific eye protection noted, but may be required anyway. Other Protection No specific protective equipment noted, but may be required anyway. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Mobile Liquid Colour Colourless. Odour Characteristic. Solubility Soluble in water. Initial boiling point and boiling range ( C) Melting point ( C) Relative density Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G H2O@20 C) Decomposition temperature ( C) 3 / 7

18 Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties Provalue RTU Washroom Cleaner 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Respiratory or skin sensitisation: Respiratory sensitisation 4 / 7

19 Skin sensitisation Provalue RTU Washroom Cleaner Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: Viscosity Inhalation No specific health warnings noted. Ingestion May cause stomach pain or vomiting. Skin contact May cause defatting of the skin, but is not an irritant. Eye contact Irritating and may cause redness and pain. Target Organs No specific target organs noted SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. 5 / 7

20 Partition coefficient Provalue RTU Washroom Cleaner Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment 6 / 7

21 No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Health & Safety Officer Revision Date 07/06/2013 Revision 3 Supersedes date 07/06/2013 SDS No. 2 7/6/2013 Risk Phrases In Full NC Hazard Statements In Full Provalue RTU Washroom Cleaner 7 / 7

22 Revision Date 07/06/2013 Revision 3 Supersedes date 07/06/2013 SAFETY DATA SHEET Provalue Toilet Cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue Toilet Cleaner PV10013 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Toilet Cleaner/Descaler 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC S2 P14 Keep out of the reach of children. Contains Perfume. May produce an allergic reaction. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 7

23 Provalue Toilet Cleaner CITRIC ACID 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xi;R36. NONIONIC SURFACTANT C9-C11 alcohol + 8 EO 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xn;R22. Xi;R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Do not induce vomiting. Get medical attention if any discomfort continues. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion May cause stomach pain or vomiting. Skin contact Skin irritation. Eye contact Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. 2 / 7

24 Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES Provalue Toilet Cleaner 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Absorb with inert, damp, non-combustible material, then flush area with water. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container Reference to other sections For personal protection, see section 8. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Gloves are recommended for prolonged use. Eye protection No specific eye protection noted, but may be required anyway. Other Protection No specific protective equipment noted, but may be required anyway. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Light viscous liquid. Light (or pale). Blue. Characteristic. 3 / 7

25 Solubility Initial boiling point and boiling range ( C) Melting point ( C) Soluble in water. Relative density Bulk Density Vapour density (air=1) Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G H2O@20 C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties Provalue Toilet Cleaner 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known Conditions to avoid 4 / 7

26 Avoid excessive heat for prolonged periods of time. Provalue Toilet Cleaner Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: Viscosity Inhalation No specific health warnings noted. Ingestion May cause stomach pain or vomiting. 5 / 7

27 Provalue Toilet Cleaner Skin contact May cause defatting of the skin, but is not an irritant. Eye contact Irritating and may cause redness and pain. Target Organs No specific target organs noted SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity There are no data on the ecotoxicity of this product Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) Packing group 6 / 7

28 Provalue Toilet Cleaner Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Revision Date 07/06/2013 Revision 3 Supersedes date 07/06/2013 SDS No. 2 Date 7/6/2013 Risk Phrases In Full R22 R36 NC R41 Hazard Statements In Full Health & Safety Officer Harmful if swallowed. Irritating to eyes. Risk of serious damage to eyes. 7 / 7

29 Revision Date 10/06/2013 Revision 6 Supersedes date 07/06/2013 SAFETY DATA SHEET Provalue Washing Up Liquid SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue Washing Up Liquid PV10001 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Washing Up Liquid 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC P14 Contains Perfume. May produce an allergic reaction. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures ALKYL ARYL SODIUM SALT 5-10% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xi;R36/38. 1 / 7

30 Provalue Washing Up Liquid Sodium lauryl ether sulphate 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xi;R38,R41. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and drink plenty of water ( ml). Do not induce vomiting. Get medical attention if any discomfort continues. Skin contact Remove contaminated clothes and rinse skin thoroughly with water. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms occur after washing Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion Nausea, vomiting. Skin contact Skin irritation. Eye contact Irritating and may cause redness and pain Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Hazardous combustion products None under normal conditions. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Protective equipment for fire-fighters Use protective equipment appropriate for surrounding materials. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions 2 / 7

31 Do not discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Provalue Washing Up Liquid Absorb with inert, damp, non-combustible material, then flush area with water. Ensure that waste and contaminated materials are collected and removed from the work area as soon as possible in a suitably labelled container Reference to other sections For personal protection, see section 8. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Read and follow manufacturer's recommendations Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective equipment Respiratory equipment None noted. Hand protection Gloves are recommended for prolonged use. Eye protection No specific eye protection noted, but may be required anyway. Other Protection No specific protective equipment noted, but may be required anyway. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Light viscous liquid. Colour Green. Odour Characteristic. Solubility Soluble in water. Initial boiling point and boiling range ( C) Melting point ( C) Relative density Bulk Density Vapour density (air=1) 3 / 7

32 Vapour pressure Evaporation rate Evaporation Factor ph-value, Conc. Solution ph-value, Diluted Solution Viscosity Solubility Value (G/100G C) Decomposition temperature ( C) Odour Threshold, Lower Odour Threshold, Upper Flash point ( C) Auto Ignition Temperature ( C) Flammability Limit - Lower(%) Flammability Limit - Upper(%) Partition Coefficient (N-Octanol/Water) Explosive properties Other Flammability Oxidising properties Provalue Washing Up Liquid 9.2. Other information Not known. SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Not known Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No incompatible groups noted Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION 4 / 7

33 Provalue Washing Up Liquid Information on toxicological effects Acute toxicity: Acute Toxicity (Oral LD50) Acute Toxicity (Dermal LD50) Acute Toxicity (Inhalation LC50) Respiratory or skin sensitisation: Respiratory sensitisation Skin sensitisation Germ cell mutagenicity: Genotoxicity - In Vitro Genotoxicity - In Vivo Carcinogenicity: Carcinogenicity Reproductive Toxicity: Reproductive Toxicity - Fertility Reproductive Toxicity - Development Specific target organ toxicity - single exposure: STOT - Single exposure Specific target organ toxicity - repeated exposure: STOT - Repeated exposure Aspiration hazard: Viscosity Inhalation No specific health warnings noted. Ingestion May cause stomach pain or vomiting. Skin contact Irritating to skin. Eye contact Irritating and may cause redness and pain. Target Organs No specific target organs noted SECTION 12: ECOLOGICAL INFORMATION 5 / 7

34 Ecotoxicity There are no data on the ecotoxicity of this product. Provalue Washing Up Liquid Toxicity Acute Fish Toxicity Not considered toxic to fish Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 6 / 7

35 Provalue Washing Up Liquid SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. EU Legislation Detergents Regulations (EC) No 648/ Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Issued By Health & Safety Officer Revision Date 10/06/2013 Revision 6 Supersedes date 07/06/2013 SDS No. 2 Date 6/6/2013 Risk Phrases In Full R36/38 Irritating to eyes and skin. R38 Irritating to skin. NC R41 Risk of serious damage to eyes. Hazard Statements In Full 7 / 7

36 Revision Date 07/06/2013 Revision 2 Supersedes date 04/06/2013 SAFETY DATA SHEET Provalue ready to use window & glass cleaner SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. Provalue ready to use window & glass cleaner PV10003 / PV Relevant identified uses of the substance or mixture and uses advised against Identified uses Office Cleaner 1.3. Details of the supplier of the safety data sheet Supplier Provalue Oakley Gardens Bouncers Lane Cheltenham Glos GL52 5JD laboratory@premiereproducts.co.uk 1.4. Emergency telephone number +44 (0) GMT 9am-5pm Monday-Friday SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human health See section 11 for additional information on health hazards. Environment The product is not expected to be hazardous to the environment Label elements Risk Phrases Safety Phrases 2.3. Other hazards NC S2 S26 P13 Keep out of the reach of children. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Safety data sheet available for professional user on request. This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1 / 8

37 Provalue ready to use window & glass cleaner PROPAN-2-OL 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Liq. 2 - H225 Eye Irrit. 2 - H319 STOT SE 3 - H336 Classification (67/548/EEC) F;R11 Xi;R36 R67 Propylene Glycol n-butyl Ether 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Classification (67/548/EEC) Xi;R36/38. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion Remove victim immediately from source of exposure. Rinse mouth thoroughly. Drink plenty of water. Get medical attention. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation No specific symptoms noted. Ingestion May cause stomach pain or vomiting. Skin contact Prolonged skin contact may cause redness and irritation. Eye contact May cause temporary eye irritation Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. 2 / 8

38 SECTION 6: ACCIDENTAL RELEASE MEASURES Provalue ready to use window & glass cleaner 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not discharge into drains, water courses or onto the ground. Contain spillages with sand, earth or any suitable adsorbent material Methods and material for containment and cleaning up Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. Containers with collected spillage must be properly labelled with correct contents and hazard symbol Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry and cool place. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes PROPAN-2-OL WEL 400 ppm 999 mg/m3 500 ppm 1250 mg/m3 WEL = Workplace Exposure Limit. Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Respiratory equipment None noted. Hand protection For prolonged or repeated skin contact use suitable protective gloves. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Wear suitable protective clothing as protection against splashing or contamination. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Clear liquid. Colour Colourless. Odour Slight odour. of solvents or Slight odour of alcohol. Solubility Soluble in water. Initial boiling point and boiling range ( C) 3 / 8