: Bromophenol blue, solution 0.04% IND

Transcription

1 Date of issue: 11/04/2016 Revision date: 15/12/2016 Supersedes: 11/04/2016 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixtures : Bromophenol blue, solution 0.04% IND Product code : BRPH-BSD 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Laboratory use Uses advised against 1.3. Details of the supplier of the safety data sheet labbox labware s.l. Joan Peiró i Belis, Vilassar de Dalt - ES T F info@labkem.com Emergency telephone number Emergency number : ( Office Hours) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] BROMPHENOL BLUE (CAS No) (EC No) SODIUM HYDROXIDE (CAS No) (EC No) (EC Index No) (REACH-no) Specific concentration limits: <= 0,04 Not classified <= 0,005 Skin Corr. 1A, H314 Name Product identifier Specific concentration limits SODIUM HYDROXIDE (CAS No) (EC No) (EC Index No) (REACH-no) ( 0,5 =<C < 2) Eye Irrit. 2, H319 ( 0,5 =<C < 2) Skin Irrit. 2, H315 ( 2 =<C < 5) Skin Corr. 1B, H314 (C >= 5) Skin Corr. 1A, H314 23/02/2017 EN (English) 1/6

2 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. : Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice. Assure fresh air breathing. : Wash contaminated clothing before reuse. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Consult an eye specialist. : Drink plenty of water. Obtain emergency medical attention. Induce vomiting if victim completely conscious/alert Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Carbon dioxide. Foam. Dry powder Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting Other information : Do not enter fire area without proper protective equipment, including respiratory protection. : Combustible. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling : Collect spillage Conditions for safe storage, including any incompatibilities Storage area 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters SODIUM HYDROXIDE ( ) : Take up liquid spill into absorbent material. Small quantities of liquid spill: take up in noncombustible absorbent material and shovel into container for disposal. This material and its container must be disposed of in a safe way, and as per local legislation. : Store in a well-ventilated place. Store away from heat. France Local name Hydroxyde de sodium France VME (mg/m³) 2 mg/m³ France Note (FR) Valeurs recommandées/admises 23/02/2017 EN (English) 2/6

3 SODIUM HYDROXIDE ( ) Portugal Local name Hidróxido de sódio Portugal OEL - Ceilings (mg/m³) 2 mg/m³ Spain Local name Hidróxido de sodio Spain VLA-EC (mg/m³) 2 mg/m³ United Kingdom Local name Sodium hydroxide United Kingdom WEL STEL (mg/m³) 2 mg/m³ 8.2. Exposure controls Hand protection: protective gloves Eye protection: Safety glasses SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : Blue. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 0,976 g/ml Solubility : Miscible. Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions 23/02/2017 EN (English) 3/6

4 10.4. Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) : Disposal must be done according to official regulations. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 23/02/2017 EN (English) 4/6

5 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Water hazard class (WGK) nwg, Non-hazardous to water (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) 23/02/2017 EN (English) 5/6

6 Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Skin Corr. 1A H314 Skin corrosion/irritation, Category 1A Causes severe skin burns and eye damage SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 23/02/2017 EN (English) 6/6