MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET MSDS No: G3179 Revision: LN9 Effective Date: 05/13/2005 (month/day/year) 16 NA ENG 1 IDENTIFICATION of the SUBSTANCE and COMPANY Trade Name : Chemical Name :Cured Rubber Fabric Composite Synonyms :NA CAS Number : - Article Company Identification Emergency Phone numbers :The Goodyear Tire & Rubber Company Akron, Ohio USA Goodyear Canada, Inc Etobicoke, Ontario M8Z 5E1 Canada :Goodyear / 24 hour Assistance Chemical Transportation Emergency Assistance Chemtrec (USA) Canutec (Canada) MSDS Information :Technical Assistance ISSUED BY - Global Chemical Material Management - Akron, Ohio COMPOSITION / INFORMATION on the COMPONENTS Hazardous Components Percentage by wt CAS No ACGIH* (TLV-TWA) OSHA* (PEL-TWA) Non - hazardous Goodyear NAm 08/19/2005 1

2 * C=Ceiling D=Dust F=Fumes M=Mist m=max N=NIOSH R=Respirable Dust S=Skin ST/STEL=Short Term Exposure Limit T= Total Dust t=typical TS=Trade Secret V=Vapor 3 HAZARDS IDENTIFICATION Emergency Overview If ignited by excessive heat or open flame, this product will burn APPEARANCE : Solid ODOR : Rubber Potential Health Effects --- PRIMARY ROUTES OF ENTRY SHORT-TERM EXPOSURE --- expected --- LONG-TERM EXPOSURE --- expected 4 FIRST AID MEASURES --- SKIN CONTACT --- SKIN: Wash thoroughly with soap and water 5 FIRE-FIGHTING MEASURES --- FLASH POINT and METHOD FLAMMABLE LIMITS --- LEL UEL --- EXTINGUISHING MEDIA --- Water, all purpose (ABC) dry chemical, CO2, foam --- SPECIAL FIRE-FIGHTING PROCEDURES --- Although this material will not normally burn, if it is in the fire area an approved, self-contained breathing apparatus should be worn to prevent exposure to thermal decomposition products and/or residual monomers --- UNUSUAL FIRE AND EXPLOSION HAZARD --- When ignited, an intense fire develops with high heat generation Health Fire Reactivity Specific NFPA Rating Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme 6 ACCIDENTAL RELEASE MEASURES Goodyear NAm 08/19/2005 2

3 ---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up) 7 HANDLING and STORAGE --- PRECAUTIONS --- No Special Procedure needed for this product 8 EXPOSURE CONTROLS / PERSONAL PROTECTION --- VENTILATION PROTECTION --- If heated, chopped, cut, buffed, drilled, ground or abrasively cut, provide enough fresh air flowing past the user to remove smoke and/or fume from the work area Observe the Occupational Exposure Limit of 3 mg/m3 (Threshold Limit Value- 8 hour time-weighted average) for insoluble respirable particulates, not otherwise classified (fumes) --- RESPIRATION PROTECTION --- Under normal conditions of use, respiratory protection should not be required --- EYE PROTECTION --- If cut, sawed, buffed or ground, wear Safety glasses or goggles --- PROTECTIVE GLOVES OTHER PROTECTION --- Practice good personal hygiene Wash hands and arms after handling and before eating 9 PHYSICAL and CHEMICAL PROPERTIES APPEARANCE : Solid ODOR : Rubber DENSITY : SOLUBILITY IN WATER : Insoluble MELT POINT : --- FLASH POINT and METHOD --- SPECIFIC GRAVITY : Not established INITIAL BOILING POINT : VAPOR PRESSURE : Not volatile 10 STABILITY and REACTIVITY --- MATERIALS TO AVOID --- Acids Strong oxidizers --- CONDITIONS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS --- Carbon monoxide Goodyear NAm 08/19/2005 3

4 Carbon dioxide Oxides of nitrogen Oxides of sulfur Zinc Oxide Aldehydes Trace aromatic and aliphatic hydrocarbons, benzene, toluene xylene, carbon, ash: (ZnO, TiO2, SiO2, CaO, Mg) oxides of sulfur Organic Acids Methane Trace amounts of: Hydrogen cyanide Products containing polychloroprene: Products containing neoprene Hydrogen chloride From oil decomposition: Polynuclear aromatic hydrocarbons --- SPECIAL SENSITIVITY TOXICOLOGY INFORMATION ORAL LD50 DERMAL LD50 INHALATION LC50 : : : 12 ECOLOGICAL INFORMATION --- OTHER --- This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known 13 DISPOSAL CONSIDERATIONS --- DISPOSAL --- Incinerate or landfill in accordance with applicable environmental control regulations Recycle if possible --- REGULATIONS AFFECTING DISPOSAL --- Based upon most recent process knowledge this product, as sold, would not be hazardous waste (if disposed) per 40CFR TRANSPORTATION INFORMATION United States --- BASIC DESCRIPTION FREIGHT DESCRIPTION --- Belts, NOI, in packages, NMFC PRIMARY HAZARD CLASS Goodyear NAm 08/19/2005 4

5 SUBSIDIARY HAZARD CLASS LABELS REQUIRED --- REPORTABLE QUANTITY --- STCC Number: AA : UN No: NA Packing Group: 15 REGULATORY INFORMATION This material is considered an "article" under the OSHA Hazard Communication Standard 29CFR, Part and the WHMIS Canadian legislation and is therefore, non-hazardous --- WHMIS CLASSIFICATION SARA 311/312 CLASSIFICATION INTERNATIONAL --- One or more of the components of this mixture is exempt from US EPA Toxic Substances Control Act (TSCA) "Chemical Substances Inventory" and the Canadian "Domestic Substances List" The components of this preparation are included in, or are exempt from, the European Inventory of Existing Commercial Chemical Substances 16 OTHER INFORMATION / ADDITIONAL COMMENTS Goodyear provides the information herein in compliance with national and local regulations, where applicable, to give warning of actual and assumed hazards, and to inform of generally applicable precautions and control measures which are known to Goodyear Hazard information is based on available scientific evidence, but is not always obtained from sources under the direction or control of Goodyear Goodyear makes no warranty or representation that the information is accurate, reliable, complete or representative and Buyer may rely thereon only at Buyer's own risk Goodyear warrants only that it has made no effort to censor other than trade secret information or to conceal hazards of its products The data shown on these pages in no way modifies, amends or enlarges any specification or warranties --- END of DOCUMENT --- Goodyear NAm 08/19/2005 5