Material Safety Data Sheet

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1 Material Safety Data Sheet Issuing Date: 13-Jun-2012 Version 1 1. PRODUCT AND COMPANY IDENTIFICATION Product ID: Product Name Uses advised against Synyms Address Emergency telephone Emergency Overview WHMIS Principle Routes of Exposure Pantene Pro-V Expert Collection Advanced + Keratin All other uses pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION Not subject to WHMIS classification Eye contact. Skin contact. 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS-No Weight % 1-Docosanaminium, N,N,N-trimethyl-, chloride (1:1) Hexadecal Isopropal Benzyl acetate < 0.1 Page 1 / 8

2 4. FIRST AID MEASURES Eye contact Skin contact Ingestion Inhalation Protection of First-aiders Most important symptoms/effects, acute and delayed Notes to physician Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If symptoms persist, call a physician.. Clean mouth with water and afterwards drink plenty of water. Not an expected route of exposure. Use personal protective equipment.. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Flash Point Suitable Extinguishing Media Unsuitable Extinguishing Media Special Hazard Special protective equipment for fire-fighters Not applicable Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.. None in particular As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up None under rmal use conditions. Use personal protective equipment. No special environmental precautions required HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Handle in accordance with good industrial hygiene and safety practice. Keep containers tightly closed in a dry, cool and well-ventilated place. Page 2 / 8

3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product does t contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Isopropal Benzyl acetate Isopropal ACGIH TLV STEL: 400 ppm TWA: 200 ppm British Columbia TWA: 200 ppm STEL: 400 ppm OSHA PEL Alberta Quebec Ontario TWAEV TWA: 200 ppm TWA: 492 STEL: 400 ppm STEL: 984 NIOSH IDLH TWA: 400 ppm TWA: 985 STEL: 500 ppm STEL: 1230 Benzyl acetate TWA: 10 ppm TWA: 10 ppm TWA: 61 - Mexico OEL Mexico: TWA 400 ppm Mexico: TWA 980 Mexico: STEL 500 ppm Mexico: STEL 1225 TWA: 400 ppm TWA: 980 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 (vacated) TWA: 400 ppm (vacated) TWA: 980 STEL: 500 ppm STEL: 1225 (vacated) STEL: 500 ppm (vacated) STEL: 1225 TWA: 10 ppm - - TWA: 200 ppm STEL: 400 ppm TWA: 10 ppm Engineering Measures Not applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Hygiene measures No special protective equipment required. No special protective equipment required. No special protective equipment required. No special protective equipment required Not applicable. Handle in accordance with good industrial hygiene and safety practice. Environmental Exposure Controls See Section 6. Page 3 / 8

4 9. PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor Cream/ Lotion White to pale yellow. cream. Characteristic Property Values Note ph VALUE Melting/freezing point Boiling point/boiling range Flash Point Not applicable Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density 0.96 Water solubility Solubility in other solvents Partition coefficient: n-octal/water Autoignition temperature. Decomposition temperature. Viscosity of Product Bulk Density log Pow 1-Hexadecal 6.65 Isopropal 0.05 Benzyl acetate STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid None under rmal use conditions. Stable under rmal conditions. Hazardous polymerization does t occur. None under rmal processing. None under rmal processing. None in particular. Hazardous Decomposition Products None under rmal use. Page 4 / 8

5 Product Information 11. TOXICOLOGICAL INFORMATION Acute Toxicity Principle Routes of Exposure Inhalation Skin contact Ingestion Eye contact Product does t present an acute toxicity hazard based on kwn or supplied information. Eye contact. Skin contact. No kwn effect based on information supplied. No kwn effect based on information supplied. No kwn effect based on information supplied. No kwn effect based on information supplied. LD50 Oral LD50 Dermal LC50 Inhalation 1-Hexadecal 5 g/kg ( Rat ) 2600 mg/kg ( Rabbit ) - Isopropal 4396 mg/kg ( Rat ) mg/kg ( Rat ) mg/l ( Rat ) 4 h mg/kg ( Rabbit ) Benzyl acetate 2490 mg/kg ( Rat ) 5 g/kg ( Rabbit ) - Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive Toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcigenicity No kwn effect. No kwn effect. No kwn effect. The product contains substances kwn to be hazardous to health in concentrations which need to be taken into account. There are kwn mutagenic chemicals in this product. No kwn effect. No kwn effect. Contains ingredients above reportable quantities listed as a carcigen. Page 5 / 8

6 Ecotoxicity Acute Toxicity 12. ECOLOGICAL INFORMATION Toxicity to algae Isopropal EC50 96 h > 1000 mg/l Desmodesmus subspicatus EC50 72 h > 1000 mg/l Desmodesmus subspicatus Toxicity to fish LC50 96 h = 9640 mg/l Pimephales promelas flow-through LC50 96 h = mg/l Pimephales promelas static LC50 96 h > µg/l Lepomis macrochirus Toxicity to microorganisms Toxicity to daphnia and other aquatic invertebrates - EC50 48 h = mg/l Daphnia magna > 1000 mg/l EC50 Toxicity to other organisms - Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Dispose of in accordance with local regulations. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT TDG MEX IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION Page 6 / 8

7 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does t contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard CERCLA This material, as supplied, does t contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does t contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Volatile Organic Compounds CAA (Clean Air Act) Hazardous Air Pollutants 1-Hexadecal Present - Isopropal Present - Benzyl alcohol Present - Clean Water Act This product does t contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). U.S. State Regulations California Proposition 65 This product is t subject to warning labeling under California Proposition 65 Isopropal Pennsylvania X International Regulations Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. International Inventories TSCA Complies DSL Complies NDSL Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List Page 7 / 8

8 16. OTHER INFORMATION Issuing Date: Revision Date: 13-Jun Jun-2012 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our kwledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is t to be considered a warranty or quality specification. The information relates only to the specific material designated and may t be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 8 / 8