MATERIAL SAFETY DATA SHEET

Transcription

1 Health : 2 Flammability : 1 Reactivity : ************************************************************************************ MATERIAL DATE ISSUED DOT HAZARD CLASSIFICATION 09/25/2006 New 9, PG III DOT SHIPPING NAME Environmentally Hazardous Substance, CAS NO Liquid, N.O.S. DOT LABEL Class 9 FORMULA C 11 H 18 N 2 IMO Classification Environmentally Hazardous substance, Liquid, N.O.S Marine Pollutant CHEMICAL NAME Diethyltoluenediamine, mixed isomers ********************************* I - INGREDIENTS *********************************** APPROXIMATE WEIGHT % TWA/TLV Diethyltoluenediamine (CAS No ) >99 None established *********************** II - PHYSICAL AND CHEMICAL PROPERTIES *********************** APPEARANCE Clear, amber to red liquid VISCOSITY o C BOILING POINT 132 o 4mmHg VAPOR DENSITY (Air=1) Not known PERCENT VOLATILE (by weight) Not known EVAPORATION RATE (Butyl Acetate=1) Not known ph 1 gm/l in water ODOR Amine-like MELTING POINT -15 o C (pour point) VAPOR PRESSURE (mm Hg) o C SOLUBILITY IN WATER o C SPECIFIC GRAVITY (WATER = 1) 20 o C *********************** III - FIRE AND EXPLOSION INFORMATION ************************ FLASH POINT > 284 o F (>140 o C) (PMCC) AUTO IGNITION TEMPERATURE 420 o C LOWER EXPLOSION LIMIT (%) Not applicable UPPER EXPLOSION LIMIT (%) Not applicable EXTINGUISHING MEDIA FOAM X ALCOHOL FOAM CO 2 X DRY CHEMICAL X WATER X OTHER SPECIAL FIRE FIGHTING PROCEDURES: Must wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. UNUSUAL FIRE AND EXPLOSION HAZARDS: Products of combustion are toxic.

2 2 7 ************************ IV - HEALTH EFFECTS INFORMATION **************************** PRIMARY ROUTES OF ENTRY - SKIN CONTACT X INHALATION EYE CONTACT X INGESTION EFFECTS OF OVEREXPOSURE Based upon animal toxicity information available for this material, it is anticipated that ingestion and prolonged skin contact with the product will be harmful. Direct eye contact can produce irritation. Long term overexposure to this material may produce serious harmful effects. No information found for human overexposure. OVEREXPOSURE MAY AGGRAVATE EXISTING CONDITIONS: No effects indicated. EMERGENCY AND FIRST AID PROCEDURES: Eyes: Immediately flush eyes with running water for at least 15 minutes. Hold eyelids apart to ensure rinsing of the entire surface of the eyes and lids with water. Get immediate medical attention. Skin: Wash affected areas with plenty of water, and soap if available, for several minutes. Remove and clean contaminated clothing and shoes. Seek medical attention if irritation develops. Ingestion: If swallowed, give 3-4 glasses of water but DO NOT induce vomiting. If vomiting does occur, give fluids again. Get medical attention to determine whether vomiting or evacuation of stomach is necessary. Do not give anything by mouth to an unconscious or convulsing person. Inhalation: Remove from area to fresh air. Seek medical attention if respiratory irritation develops or if breathing becomes difficult. CHEMICALS LISTED AS CARCINOGEN BY: NATIONAL TOXICOLOGY PROGRAM - No I.A.R.C. MONOGRAPHS - No OSHA - No ************************** V - REACTIVITY INFORMATION ****************************** STABILITY: STABLE X CONDITIONS TO AVOID UNSTABLE Light, heat(product darkens with time when exposed to light and heat. No exotherm observed at 280 C)

3 3 7 ******************* V - REACTIVITY INFORMATION (continued)************************* HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition may produce toxic organic vapors/fumes and oxides of carbon and nitrogen. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID MAY WILL NOT X OCCUR OCCUR INCOMPATIBILITY (MATERIALS TO AVOID) WATER OTHER X Oxidizing agents ********************** VI - SPILL AND DISPOSAL INFORMATION ************************* STEPS TO BE TAKEN IN CASE OF MATERIAL SPILL OR RELEASE CAUTION! If spilled, wet floors may become slippery. Wear appropriate protective gear and respiratory protection where dusts or airborne particulates of unknown concentrations may be generated (self-contained breathing apparatus preferred for large spills). Dike and contain spill with inert material (sand, earth, etc.) and transfer the liquid and solid separately to containers for recovery or disposal. Keep spill out of sewers and open bodies of water. WASTE DISPOSAL METHODS Dispose of in compliance with all Federal, state and local laws and regulations. Incineration is the preferred method. ********************** VII - PERSONAL PROTECTION INFORMATION *********************** ENGINEERING CONTROLS In processes where mists or vapors may be generated, proper ventilation must be provided in accordance with good ventilation practices. RESPIRATORY PROTECTION In processes where mists or vapors may be generated, a NIOSH approved respirator is advised in the absence of proper environmental controls. PROTECTIVE GLOVES Rubber or neoprene, when needed, to prevent skin contact.

4 4 7 **************** VII - PERSONAL PROTECTION INFORMATION (continued)****************** EYE PROTECTION Wear chemical goggles where there is a potential for eye contact. Use safety glasses with side shields under normal use conditions. OTHER PROTECTIVE EQUIPMENT Eye wash; safety shower; protective clothing (long sleeves, coveralls or other, as appropriate), when needed, to prevent skin contact. *************************** VIII - STORAGE AND HANDLING **************************** PRECAUTIONS FOR STORAGE AND HANDLING: Keep containers closed until used. To maintain product quality, do not store in heat or in light. Product has a minimum of one year stability if stored in the dark at or below room temperature. ******************* IX - TOXICOLOGY & ECOTOXICITY INFORMATION ********************** TOXICITY ACUTE - oral LD 50 (rat): mg/kg - dermal LD 50 (rat, 24-hour): >2000 mg/kg - dermal LD 50 (rabbit): >2000 mg/kg - eye irritation (rabbit): Irritant. - skin irritation (rabbit - 24 hour exposure): Not an irritant. - skin sensitization(guinea pig): Not sensitizing. ****************** IX - TOXICOLOGY & ECOTOXICITY INFORMATION (continued)************ GENOTOXIC/MUTAGENIC - Ames test (salmonella sp.): Mutagen with or without metabolic activation. - unscheduled DNA synthesis (in vitro rat hepatocytes): Not mutagenic. - gene mutation (in vitro mammalian cell): Mutagenic. - micronucleus test (in vivo mouse): Not clastogenic. ECOTOXICITY AQUATIC - LC 50 (golden orfe 48 hour): 194 mg/l - EC 50 (Daphnia Magna 48 hours): <1 mg/l - EC 10 (Pseudomonas sp 16 hour): 170 mg/l

5 5 7 ****************** X - MISCELLANEOUS AND REGULATORY INFORMATION ******************** INTERNATIONAL LEVEL REGULATIONS CANADIAN WORKPLACE HAZARDOUS MATERIAL INFORMATION SYSTEM (WHMIS) CLASSIFICATION This product is not regulated by WHMIS DOMESTIC SUBSTANCE LIST (DSL) STATUS This product is currently listed on the Canadian DSL. TRANSPORT OF DANGEROUS GOODS (TDG) Environmentally Hazardous Substance, Liquid N.O.S.) Class 9 UN 3082 PG III (Marine Pollutant) FEDERAL LEVEL REGULATIONS: TOXIC SUBSTANCES CONTROL ACT (TSCA INVENTORY) STATUS: This product is currently listed on the U.S. EPA TSCA 8(b) inventory list. CERCLA (Comprehensive Environmental Response, Compensation and Liability Act of 1980 requires notification of the National Response Center (Telephone ) in the event of a release of quantities of the following hazardous materials contained in this product, if the release is equal to or greater than the Reportable Quantities (RQs) listed in 40 CFR 302.4: SARA Title III, Sections 302/304 (Superfund Amendments and Reauthorization act of 1986) - This act requires emergency planning, including agency notification, for possible release of the following components of this material, based upon the Threshhold Planning Quantities (TPQs) and release Reportable Quantities (RQs) listed for the Components in 40 CFR 355:

6 6 7 ****************** X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ******** FEDERAL LEVEL REGULATIONS (continued): SARA Title III Sections 311/312 - This act requires reporting under the Community Right-to-Know provisions due to the inclusion of the following components of this material in one or more of the five hazard categories listed in 40 CFR 370: Hazard *) Chemical Name CAS Number Categories Diethyltoluenediamine, mixed isomers A,C *) The five hazard categories are as follows: F=FIRE HAZARD; S= SUDDEN RELEASE OF PRESSURE; R=REACTIVE; A=IMMEDIATE (ACUTE) HEALTH HAZARD; C=DELAYED (CHRONIC) HEALTH HAZARD SARA Title III Section This act requires submission of annual reports of the releases of the following components of this material if the threshold reporting quantities, as listed in 40 CFR 372, are met or exceeded: STATE RIGHT-TO-KNOW REGULATIONS: CALIFORNIA PROPOSITION 65 - Components present in this material which the State of California has found to cause cancer, birth defects or other reproductive harm are as follows: AS A CANCER HAZARD 2,4-Toluenediamine ppm MASSACHUSETTS Right-to-Know - The following components of this material are included in the Massachusetts Substance List and are present at or above reportable levels: 2,4-Toluenediamine ppm MICHIGAN Critical Materials - The following components of this material are included in the Michigan Critical Materials List: Chemical Name CAS Number

7 7 7 ****************** X - MISCELLANEOUS AND REGULATORY INFORMATION (continued) ******** NEW JERSEY Right-to-Know - The following components of this material are included in the New Jersey Hazardous Substance List and are present at or above reportable levels: PENNSYLVANIA Right-to-Know - The following components of this material are included in the Pennsylvania Hazardous Substance List and are present at or above reportable levels: 2,4-Toluenediamine ppm