Safety data sheet PERCARBONATO SBIANCANTE DISINFETTANTE IN POLVERE. European

Transcription

1 Page n / 08 SECTION Hazards Exposure Ecological Transport Or inmation identification controls/personal inmation... /... >> / >> // >> protection... / >> Safety data sheet contaminated - PBT: Persistence Transport P305+P351+P338 required, Persistent in water unless bulk bioaccumulative used degradability according indicated IF extinction IN orwise EYES: to Annex toxic Rinse as II REACH cautiously remains Marpol chemical Regulation with risk assessment. water fire IBC according Code several to applicable minutes. Remove regulations. contact lenses, if present easy to do. SPECIAL VIRONMTAL - PEC: Predicted PROTECTIVE environmental EXPOSURE EQUIPMT Continue Concentration CONTROLS rinsing. FOR FIRE-FIGHTERS Normal The emissions fire fighting generated clothing by i.e. manufacturing fire kit (BS processes, 469), gloves including (BS those 659) generated boots by (HO ventilation specification equipment, A29 should A30) be in combination checked to ensure with SECTION - PEL: P337+P313 Predicted 11. available relevant exposure Toxicological level If eye irritation inmation persists: Get medical advice / attention SECTION self-contained compliance - PNEC: P370+P378 Predicted 1. with open Identification environmental no toxicological circuit effect positive In concentration case stards. effects pressure fire: use compressed substance/mixture... to extinguish. air breathing apparatus (BS 137). company/undertaking - REACH: EC Regulation 1907/ SECTION SECTION Metabolism, - RID: Product Bioaccumulative Regulation identifier 15. Regulatory toxicokinetics, concerning potential inmation Accidental Physical mechanism international release chemical action transport measures properties or dangerous inmation goods by train - TLV: Contains: Threshold Limit ValuePERCARBONATO DI SODIO Code: TLV Personal Safety, CEILING: health precautions, available available Concentration environmental protective that should equipment regulations/legislation be exceeded R0002 emergency during specific procedures any time occupational substance exposure. or mixture 9.1. Nr. - Product TWA EC: STEL: nameshort-term on basic physical exposure limit RICARICANDO SMACCHIATORE TRIPLO IMPIEGO - IN GRANELLI chemical properties If Seveso - EC TWA: number re Time-weighted are Category no on contraindications, likely - Directive routes average 2012/18/EC: exposure exposure spray powder limit with water to prevent P8 mation dust Wear Appearance - CAS VOC: Mobility number suitable Volatile in protective soil organic Compounds equipment (including personal powder protective equipment referred to under Section 8 safety data sheet) to prevent 2.3. any Colour Restrictions - vpvb: Or contamination Very s relating Persistent available to skin, eyes product very Bioaccumulative or personal contained clothing. substances as white These REACH pursuant indications Regulation to Annex apply XVII both to EC processing Regulation staff 1907/2006 those involved in emergency 1.2. procedures. Odour - WGK: Relevant Water identified available classes uses (German). substance or mixture uses advised against no odour On Odour Delayed threshold basis immediate available effects data, as well product as chronic does effects contain from any short PBT or vpvb long-term in percentage exposure greater than 0,1%. Intended use PERCARBONATO SBIANCANTE DISINFETTANTE IN POLVERE 6.2. SECTION ph Substances Environmental 3. in Cidate Composition/inmation precautions List (Art. 59 REACH) Not on available ingredients Melting On GERAL Results basis point BIBLIOGRAPHY / PBT freezing available point vpvb data, assessment product does contain any SVHC in percentage greater than 0,1% The Initial 1. Details Regulation product boiling must point supplier 1907/2006 penetrate (REACH) safety data into sewer sheet European system Not or available come into contact with surface water or ground water Boiling Interactive On Substances 2. Regulation basis range effects subject (EC) available 1272/2008 to authorisarion data, (CLP) product (Annex does European XIV REACH) contain Not available any PBT or vpvb in percentage greater than 0,1% Flash 3. Name Methods Regulation point material 790/2009 (I containment Atp. CLP) European NIVEL cleaning SRL up Contains: Evaporation 4. Full Regulation Or address adverse rate available effects 2015/830 European VIA ROMANA 615 Collect Flammability Substances 5. District Regulation Country leaked subject (solid, product 286/2011 gas) to exportation (II place Atp. reporting CLP) it containers pursuant European Not to recovery (EC) available LUCCA (LU) Reg. or 649/2012: disposal. If product is flammable, use explosion-pro equipment. If Identification re Lower ACUTE 6. Regulation are inflammability TOXICITY no contraindications, available 618/2012 limit Conc. (III use Atp. % jets CLP) water Classification to European eliminate ITALIA product 1272/2008 residues. (CLP) Make Upper 7. Regulation sure inflammability leakage 487/2013 limit site is (IV well Atp. aired. CLP) Evaluate European Tel. Not compatibility available container to be used, by checking section 10. Contaminated material SECTION PERCARBONATO should Lower Does Substances 8. Regulation explosive be meet disposed DI in SODIO compliance with provisions set th in point subject limit 944/2013 Disposal to Rotterdam (V Atp. criteria CLP) considerations Convention: this European Fax Not class available CAS Upper 9. Regulation address explosive limit 605/2014 competent 100 (VI Atp. person CLP) Ox. European Sol. Not 2 H272, available Acute Tox. 4 H EC Vapour SKIN Reuse, 10. responsible Reference Regulation CORROSION when pressure to possible. Safety or / 2015/1221 Data IRRITATION sections Product (VII Sheet residues Atp. CLP) should be considered European ufficioqualita@nivel.it special ous waste. The level waste containing this product INDEX Vapour should Substances 11. Regulation be density evaluated subject 2016/918 to according Stockholm (VIII applicable Atp. Convention: CLP) regulations. European 1.4. Emergency telephone number Any Relative Does Disposal inmation density must meet be on permed personal protection through criteria an authorised this disposal waste is 1,05 class given management in sections 8 firm, in 13. compliance with national local regulations. The Solubility CONTAMINATED - The full Merck wording Index. PACKAGING - 10th Edition (H) phrases is given in section 16 sheet. Partition SERIOUS Contaminated Healthcare - For Hling urgent coefficient: EYE Chemical inquiries refer controls packaging DAMAGE n-octanol/water Safety to must / IRRITATION be recovered or disposed in compliance with national waste management regulations. SECTION Auto-ignition Workers - INRS - Fiche exposed 7. temperature Toxicologique Hling to this chemical (toxicological agent storage must sheet) undergo health checks, provided that available risk-assessment data prove that risks Decomposition Causes related - Patty Mixtures Precautions Waste - to serious Industrial treatment workers' temperature eye Hygiene safe irritation methods health hling Toxicology SECTION 2. Hazards identification safety are modest Not that available 98/24/EC directive is respected. Viscosity - N.I. Sax - Dangerous properties Industrial Materials-7, 1989 Edition 2.1. Bee Explosive RESPIRATORY Reuse, German - IFA Classification GESTIS hling when regulation properties possible. website OR on product, SKIN Product substance SSITISATION consult residues or mixture all should substances or be sections considered Not ous available this special material to water ous safety (VwVwS data waste. 2005) sheet. The Avoid leakage level waste product containing into this product environment. Oxidising should Self - ECHA assessment be website properties evaluated Do relevant based according eat, on drink Annex or to smoke applicable 3 during regulations. use. Does Disposal - The Database product must meet is SDS be classified permed models ous through chemicals criteria an pursuant authorised - Ministry this to waste Health class provisions management ISS set (Istituto th firm, in in EC Superiore compliance Regulation di Sanità) with 1272/2008 national - Italy (CLP) local ( regulations. subsequent amendments CONTAMINATED SECTION Conditions Or Chemical supplements). inmation safety 4. First safe PACKAGING The assessment product thus requires a safety datasheet that complies with provisions EC Regulation 1907/2006 storage, aid measures including any incompatibilities GERM Contaminated subsequent CELL amendments. MUTAGICITY packaging must be recovered or disposed in compliance with national waste management regulations Keep No Note Any Description chemical additional users: product safety inmation first assessment concerning clearly aid measures labelled has containers. been risks processed health Keep containers /or mixture environment away from any substances are given incompatible it contains. sections this sheet. materials, see section 10 details. Does The inmation meet available contained in criteria present sheet this are based class our own knowledge on date last version. Users must verify SECTION suitability Hazard 14. thoroughness Transport indication: provided inmation according to each specific use product SECTION Not Specific specifically end necessary. use(s) Observance good industrial hygiene is recommended. CARCINOGICITY This Oxidising document 16. solid, must Or category be inmation regarded 2 as a guarantee on any specific product H272property. May intensify fire; oxidiser. SECTION The product 10. Stability dangerous under reactivity current provisions Code International Carriage Dangerous Goods by Road (ADR) by Rail Acute use toxicity, this product category is 4 subject to our direct control; ree, users H302 must, under ir Harmful own if responsibility, swallowed. comply with current health 4.2. (RID), Text Most important International available symptoms Maritime effects, Dangerous both Goods acute Code (IMDG), delayed International Air Transport Association (IATA) regulations Does (H) indications mentioned in section 2-3 sheet: Eye safety Reactivity irritation, meet laws category regulations. 2 criteria The producer this is relieved class from any liability H319 arising from improper Causes serious uses. eye irritation. Provide appointed staff with adequate training on how to use chemical products Specific UN Ox. number Sol. inmation 2 on symptoms Oxidising effects solid, caused category by 2 product are unknown SECTION There REPRODUCTIVE Label elements Acute are Tox. no 8. particular 4Exposure TOXICITY risks controls/personal reaction Acute toxicity, with or category substances 4protection in normal conditions use Not Indication Eye applicable Irrit. 2 any immediate medical Eye irritation, attention category 2special treatment needed Does Hazard Control Chemical H272 labelling meet parameters stability pursuant to EC May criteria Regulation intensify this 1272/2008 fire; oxidiser. class (CLP) subsequent amendments supplements UN H302 proper shipping availablename Harmful if swallowed. The STOT Hazard H319 product - SINGLE pictograms: is stable EXPOSURE available in normal conditions Causes serious use eye irritation. storage. SECTION 5. Firefighting measures Does Exposure Possibility meet controls ous reactions criteria this class LEGD: Extinguishing Transport media class(es) As No STOT - ADR: ous - REPEATED use European adequate reactions Agreement EXPOSURE technical are eseeable concerning equipment in normal carriage must always conditions Dangerous take priority use goods over storage. by personal Road protective equipment, make sure that workplace is SUITABLE well Not - CAS applicable aired NUMBER: through EXTINGUISHING Chemical effective local Abstract EQUIPMT aspiration. Service Number Does Changes When - CE50: Conditions meet to previous extinguishing choosing Effective to personal concentration avoid review: criteria this class The following sections equipment were protective modified: should (required equipment, be to induce conventional ask a your 50% chemical effect) kind: carbon substance dioxide, supplier foam, powder advice. water spray UNSUITABLE Personal - CE Packing NUMBER: protective group EXTINGUISHING Identifier equipment in ESIS must EQUIPMT (European be CE marked, archive showing existing that substances) it complies with applicable stards. HAND ASPIRATION 01 / 02 / 03 / 04 - CLP: in in EC PROTECTION particular. particular. Regulation HAZARD / 06 / 09 / 11 / 13 / 14 / 15 / 16. However 1272/2008 usual precautions used chemical products should be respected. Signal words: Danger In Not - DNEL: applicable case Derived prolonged No Effect contact Level with product, protect hs with penetration-resistant work gloves (see stard 374) Does Work - EmS: Special Incompatible meet glove Emergency s material materials Schedule criteria this class Hazard statements: arising must be from chosen substance according to or mixture use process products that may m. Latex gloves may cause sensitivity reactions. - GHS: Environmental Globally Harmonized s System labeling chemicals H272 May intensify fire; oxidiser. SECTION HAZARDS SKIN - IATA PROTECTION DGR: CAUSED 12. International available Ecological BY EXPOSURE Air Transport inmation IN Association THE EVT Dangerous OF FIRE Goods Regulation H302 Harmful if swallowed. Do Wear Not - IC50: applicable category brea Immobilization I combustion pressional Concentration products. long-sleeved 50% H319 Causes serious overalls eye irritation. safety footwear (see Directive 89/686/EEC stard ISO 20344). Wash body with - IMDG: Hazardous soap International water decomposition after Maritime removing Code products protective dangerous clothing. goods EYE - IMO: Advice Toxicity Special PROTECTION International precautions firefighters Maritime user Organization Precautionary statements: Wear - INDEX airtight NUMBER: protective available Identifier goggles in Annex (see stard VI CLP P101 If medical advice is needed, 166). have product container or label at h. GERAL In Not - LC50: applicable presence Lethal INFORMATION Concentration available risks exposure 50% P102 Keep out to splashes reach children. or squirts during work, adequate mouth, nose eye protection should be used to prevent Use accidental - LD50: jets Lethal absorption. water dose to cool 50% P264 Wash containers... thoroughly to prevent after product hling. decomposition development substances potentially ous health. RESPIRATORY - OEL: Occupational Always wear PROTECTION full Exposure fire prevention Level P280 Wear protective gear. gloves Collect / eye extinguishing protection water / face to protection. prevent it from draining into sewer system. Dispose

2 Page n. 2 / 8 SECTION 2. Hazards identification... / >> P305+P351+P338 IF IN EYES: Rinse cautiously with water several minutes. Remove contact lenses, if present easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice / attention. P370+P378 In case fire: use... to extinguish. Contains: PERCARBONATO DI SODIO Nr. EC: Or s On basis available data, product does contain any PBT or vpvb in percentage greater than 0,1%. SECTION 3. Composition/inmation on ingredients 3.1. Substances Contains: Identification Conc. % Classification 1272/2008 (CLP) PERCARBONATO DI SODIO CAS Ox. Sol. 2 H272, Acute Tox. 4 H302 EC INDEX The full wording (H) phrases is given in section 16 sheet Mixtures relevant SECTION 4. First aid measures 4.1. Description first aid measures Not specifically necessary. Observance good industrial hygiene is recommended Most important symptoms effects, both acute delayed Specific inmation on symptoms effects caused by product are unknown Indication any immediate medical attention special treatment needed SECTION 5. Firefighting measures 5.1. Extinguishing media SUITABLE EXTINGUISHING EQUIPMT The extinguishing equipment should be conventional kind: carbon dioxide, foam, powder water spray. UNSUITABLE EXTINGUISHING EQUIPMT in particular Special s arising from substance or mixture HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do brea combustion products Advice firefighters GERAL INFORMATION Use jets water to cool containers to prevent product decomposition development substances potentially ous health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into sewer system. Dispose

3 Page n. 3 / 8 contaminated water used extinction remains fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) boots (HO specification A29 A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137). SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment emergency procedures If re are no contraindications, spray powder with water to prevent mation dust. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 safety data sheet) to prevent any contamination skin, eyes personal clothing. These indications apply both processing staff those involved in emergency procedures Environmental precautions The product must penetrate into sewer system or come into contact with surface water or ground water Methods material containment cleaning up Collect leaked product place it in containers recovery or disposal. If product is flammable, use explosion-pro equipment. If re are no contraindications, use jets water to eliminate product residues. Make sure leakage site is well aired. Evaluate compatibility container to be used, by checking section 10. Contaminated material should be disposed in compliance with provisions set th in point Reference to or sections Any inmation on personal protection disposal is given in sections SECTION 7. Hling storage 7.1. Precautions safe hling Bee hling product, consult all or sections this material safety data sheet. Avoid leakage product into environment. Do eat, drink or smoke during use Conditions safe storage, including any incompatibilities Keep product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 details Specific end use(s) SECTION 8. Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls As use adequate technical equipment must always take priority over personal protective equipment, make sure that workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier advice. Personal protective equipment must be CE marked, showing that it complies with applicable stards. HAND PROTECTION In case prolonged contact with product, protect hs with penetration-resistant work gloves (see stard 374). Work glove material must be chosen according to use process products that may m. Latex gloves may cause sensitivity reactions. SKIN PROTECTION Wear category I pressional long-sleeved overalls safety footwear (see Directive 89/686/EEC stard ISO 20344). Wash body with soap water after removing protective clothing. EYE PROTECTION Wear airtight protective goggles (see stard 166). In presence risks exposure to splashes or squirts during work, adequate mouth, nose eye protection should be used to prevent accidental absorption. RESPIRATORY PROTECTION

4 Page n. 4 / 8 SECTION 8. Exposure controls/personal protection... / >> required, unless indicated orwise in chemical risk assessment. VIRONMTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental stards. SECTION 9. Physical chemical properties 9.1. on basic physical chemical properties Appearance powder Colour white Odour no odour Odour threshold ph Melting point / freezing point Initial boiling point Boiling range Flash point Evaporation rate Flammability (solid, gas) Lower inflammability limit Upper inflammability limit Lower explosive limit Upper explosive limit Vapour pressure Vapour density Relative density 1,05 Solubility Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2. Or inmation SECTION 10. Stability reactivity Reactivity There are no particular risks reaction with or substances in normal conditions use Chemical stability The product is stable in normal conditions use storage Possibility ous reactions No ous reactions are eseeable in normal conditions use storage Conditions to avoid in particular. However usual precautions used chemical products should be respected Incompatible materials Hazardous decomposition products

5 Page n. 5 / 8 SECTION 11. Toxicological inmation on toxicological effects Metabolism, toxicokinetics, mechanism action or inmation on likely routes exposure Delayed immediate effects as well as chronic effects from short long-term exposure Interactive effects ACUTE TOXICITY Does meet criteria this class SKIN CORROSION / IRRITATION Does meet criteria this class SERIOUS EYE DAMAGE / IRRITATION Causes serious eye irritation RESPIRATORY OR SKIN SSITISATION Does meet criteria this class GERM CELL MUTAGICITY Does meet criteria this class CARCINOGICITY Does meet criteria this class REPRODUCTIVE TOXICITY Does meet criteria this class STOT - SINGLE EXPOSURE Does meet criteria this class STOT - REPEATED EXPOSURE Does meet criteria this class ASPIRATION HAZARD Does meet criteria this class SECTION 12. Ecological inmation Toxicity

6 SECTION 12. Ecological inmation... / >> Persistence degradability Page n. 6 / Bioaccumulative potential Mobility in soil Results PBT vpvb assessment On basis available data, product does contain any PBT or vpvb in percentage greater than 0,1% Or adverse effects SECTION 13. Disposal considerations Reuse, when possible. Product residues should be considered special ous waste. The level waste containing this product should be evaluated according to applicable regulations. Disposal must be permed through an authorised waste management firm, in compliance with national local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed in compliance with national waste management regulations Waste treatment methods Reuse, when possible. Product residues should be considered special ous waste. The level waste containing this product should be evaluated according to applicable regulations. Disposal must be permed through an authorised waste management firm, in compliance with national local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed in compliance with national waste management regulations. SECTION 14. Transport inmation The product is dangerous under current provisions Code International Carriage Dangerous Goods by Road (ADR) by Rail (RID), International Maritime Dangerous Goods Code (IMDG), International Air Transport Association (IATA) regulations UN number UN proper shipping name Transport class(es) Packing group Environmental s Special precautions user

7 SECTION 14. Transport inmation... / >> Transport in bulk according to Annex II Marpol IBC Code relevant Page n. 7 / 8 SECTION 15. Regulatory inmation Safety, health environmental regulations/legislation specific substance or mixture Seveso Category - Directive 2012/18/EC: P8 Restrictions relating to product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Substances in Cidate List (Art. 59 REACH) On basis available data, product does contain any SVHC in percentage greater than 0,1%. Substances subject to authorisarion (Annex XIV REACH) Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Substances subject to Rotterdam Convention: Substances subject to Stockholm Convention: Healthcare controls Workers exposed to this chemical agent must undergo health checks, provided that available risk-assessment data prove that risks related to workers' health safety are modest that 98/24/EC directive is respected. German regulation on substances ous to water (VwVwS 2005) Self assessment based on Annex Chemical safety assessment No chemical safety assessment has been processed mixture substances it contains. SECTION 16. Or inmation Text (H) indications mentioned in section 2-3 sheet: Ox. Sol. 2 Oxidising solid, category 2 Acute Tox. 4 Acute toxicity, category 4 Eye Irrit. 2 Eye irritation, category 2 H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H319 Causes serious eye irritation. LEGD: - ADR: European Agreement concerning carriage Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive existing substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System labeling chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level

8 SECTION 16. Or inmation... / >> - PBT: Persistent bioaccumulative toxic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerning international transport dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should be exceeded during any time occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent very Bioaccumulative as REACH Regulation - WGK: Water classes (German). Page n. 8 / 8 GERAL BIBLIOGRAPHY 1. Regulation 1907/2006 (REACH) European 2. Regulation (EC) 1272/2008 (CLP) European 3. Regulation 790/2009 (I Atp. CLP) European 4. Regulation 2015/830 European 5. Regulation 286/2011 (II Atp. CLP) European 6. Regulation 618/2012 (III Atp. CLP) European 7. Regulation 487/2013 (IV Atp. CLP) European 8. Regulation 944/2013 (V Atp. CLP) European 9. Regulation 605/2014 (VI Atp. CLP) European 10. Regulation 2015/1221 (VII Atp. CLP) European 11. Regulation 2016/918 (VIII Atp. CLP) European - The Merck Index. - 10th Edition - Hling Chemical Safety - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene Toxicology - N.I. Sax - Dangerous properties Industrial Materials-7, 1989 Edition - IFA GESTIS website - ECHA website - Database SDS models chemicals - Ministry Health ISS (Istituto Superiore di Sanità) - Italy Note users: The inmation contained in present sheet are based on our own knowledge on date last version. Users must verify suitability thoroughness provided inmation according to each specific use product. This document must be regarded as a guarantee on any specific product property. The use this product is subject to our direct control; ree, users must, under ir own responsibility, comply with current health safety laws regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. Changes to previous review: The following sections were modified: 01 / 02 / 03 / 04 / 06 / 09 / 11 / 13 / 14 / 15 / 16.