Version: 2.3. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 2.3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Primal AC 35 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Binding agent Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists Safety Phrases: Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Hazard designation: Signal word: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Hazard designation: EUH208 May produce an allergic reaction. Safety designation: 2

2 Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Page 2 Contains 2-Methly-2H-isothiazol-3-one: can cause allergic reactions. This produkt is a mixture. Chemical Characterization: Acrylic latex Information on Components / Hazardous Ingredients: Does not contain any hazardous components according to EC Guidelines 1272/2008 and 67/548/EEC Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Take affected person to fresh air. Wash off with plenty of water and soap. Consult a physician if irritation persists. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Use extinguishing media for surrounding fire. Unsuitable extinguishing media: 3

3 5. 2. Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Material can splatter above 100 C/212 F. Dried product can burn. Wear self-contained respiratory protective device and protective clothing Further information: Thermal decomposition may yield acrylic monomers. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Floor may be slippery; use care to avoid falling Environmental precautions: Methods and Material for Containment and Cleaning Up Caution: Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent, inert material (sand, earth) and dispose accordingly. See Section 13 for information on disposal. Avoid contact with eyes, skin and clothing. Wash hands with soap and water. Do not swallow or inhale Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry room. Stir well before use. Keep from freezing; material may coagulate. Store between 1-49 C ( F). Keep container tightly closed. Information on fire and explosion 4

4 protection: Storage class (VCI): Page 4 Monomer vapors may be evolved when material is heated during processing operations Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled The technical guidelines for the application of this product/mixture should be followed. Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Adequate ventilation. Facilities storing or utilizing this material should be equipped with an eyewash facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Avoid contact with skin and avoid inhalation of vapour. Do not eat, drink or smoke while working. Respiratory equipment required in case of insufficient ventilation, filter type A-P2 (organic gases and vapors). Chemical protective gloves (EN 374 (Europe), F739 (US)). Neoprene Safety glasses with protective shields (EN 166). Protective suit with long sleeves. Environmental precautions: 9. Physical and Chemical Properties 5

5 9. 1. Information on Basic Physical and Chemical Properties Page 5 Form: Color: Odor: Odor threshold: liquid milky white ammoniacal ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: 0 C (H20) 100 C (H2O) not combustible < 1 H2O non-combustible not determined not determined 2266,4808 Pa (20 C) g/cm3 dilutable not determined not determined < 2500 mpa.s no information available Bulk density: Further Information Solubility in solvents: 6

6 Viscosity, kinematic Page Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Percent volatility: % water The product is stable. Stable if used according to specifications. Unknown. Avoid heat. Thermal decomposition may yield acrylic monomers. None known. Product does not polymerize. > 5000 mg/kg (rat) > 5000 mg/kg (rabbit) Slight irritant effect. Non-irritating to eyes No information available 7

7 Sensitization: Page Mutagenicity: Reproductive toxicity: Carcinogenicity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: By analogy with a product of similar composition. No data available. no information available This substance is not classified as PBT (persistent, bioaccumulative, toxic), nor as vpvb (very persistent, very bioaccumulative). Do not let product contaminate ground water, waterways or sewage system. No ecological data available. AOX Value: 8

8 Page Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Coagulate the emulsion by the stepwise addition of ferric chloride and lime. Remove the clear supernatant and flush to a chemical sewer. Incinerate liquid and contaminated solids in accordance with local, state and federal regulations. The waste code must be determined together with the regional disposal service. Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IATA: Environmental Hazards None 9

9 Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water (German Regulation) Seveso III Directive: under Directive 2012/18/EC Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment is not necessary for this product. Polymer: exempted from the mandatory REACH Registration. EC: This product is in accordance with the requirements of the European Inventory of Existing Chemical Substances (EINECS). This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.