FORM-1 FOR PROPOSED EXPANSION OF ORGANIC INTERMEDIATES MANUFACTURING IN EXISTING UNIT

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1 FORM-1 FOR PROPOSED EXPANSION OF ORGANIC INTERMEDIATES MANUFACTURING IN EXISTING UNIT OF M/S. SHREEJI CHEMICALS INDUSTRIES (UNIT-1) PLOT NO. 506, GIDC ESTATE, PANOLI , TAL: ANKLESHWAR, DIST: BHARUCH, GUJARAT Prepared By: NABL Accredited Testing Laboratory ISO 9001:2008 Certified Company Aqua-Air Environmental Engineers P. Ltd. 403, Centre Point, Nr. Kadiwala School, Ring Road, Surat Page 1 of 48

2 APPENDIX I (See paragraph - 6) FORM 1 (I) Basic Information Sr. Item Details No. 1. Name of the project/s M/s. Shreeji Chemical Industries (Unit-1) 2. S. No. in the schedule 5(f) 3. Proposed Proposed Capacity = 150 MT/Month capacity/area/length/tonnage to be Total Plot Area = 1,575 m 2 handled/command area/lease For detail Please refer Annexure-I area/number of wells to be drilled 4. New/Expansion/Modernization Expansion 5. Existing Capacity/Area etc. Existing Capacity = 9 MT/Month Total Plot Area = 1,575 m 2 For detail Please refer Annexure-I 6. Category of Project i.e. A or B A 7. Does it attract the general condition? Yes. Located within 5 km of critically polluted If yes, please specify. area (Ankleshwar). 8. Does it attract the specific condition? No If yes, please specify. 9. Location Plot No. 506, GIDC Estate, Panoli , Tal: Ankleshwar, Dist. Bharuch, Gujarat Plot/Survey/Khasra No. Plot No. 506 Village GIDC Estate, Panoli Tehsil Ankleshwar District Bharuch State Gujarat 10. Nearest railway station/airport along Nearest Railway Station: Ankleshwar (4.5 with distance in kms. km) 11. Nearest Town, city, District Headquarters along with distance in kms. 12. Village Panchayats, Zilla Parishad, Municipal Corporation, local body (complete postal address with Nearest Airport: Surat (60 km) Ankleshwar (4.0 km) Notified Area Authority, Panoli telephone nos. to be given) 13. Name of the applicant M/s. Shreeji Chemical Industries (Unit-1) 14. Registered Address M/s. Shreeji Chemical Industries (Unit-1) Plot No. 506, GIDC Estate, Panoli , Tal: Ankleshwar, Dist. Bharuch, Gujarat 15. Address for correspondence: Name Mr. Bharat M. Patel Page 2 of 48

3 Designation (Owner/Partner/CEO) Partner Address M/s. Shreeji Chemical Industries (Unit-1) Plot No. 506, GIDC Estate, Panoli , Tal: Ankleshwar, Dist. Bharuch, Gujarat Pin Code Telephone No. +91(2646)272271, M. No Fax No. +91(2646) Details of Alternative Sites examined, NA if any. Location of these sites should be shown on a topo sheet. 17. Interlinked Projects No 18. Whether separate application of No interlinked project has been submitted? 19. If yes, date of submission No 20. If no, reason No 21. Whether the proposal involves No approval/clearance under: if yes, details of the same and their status to be given. (a) The Forest (Conservation) Act, 1980? (b) The Wildlife (Protection) Act, 1972? (c) The C.R.Z. Notification, 1991? 22. Whether there is any Government No Order/Policy relevant/relating to the site? 23. Forest land involved (hectares) No 24. Whether there is any litigation No pending against the project and/or land in which the project is propose to be set up? (a) Name of the Court (b) Case No. (c) Orders/directions of the Court, if any and its relevance with the proposed project. Capacity corresponding to sectoral activity (such as production capacity for manufacturing, mining lease area and production capacity for mineral production, area for mineral exploration, length for linear transport infrastructure, generation capacity for power generation etc.,) Page 3 of 48

4 (II) Activity 1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.) Sr. No. Information/Checklist confirmation Yes/ No 1.1 Permanent or temporary change in land use, land cover or topography including increase intensity of land use (with respect to local land use plan) 1.2 Clearance of existing land, vegetation and Buildings? 1.3 Creation of new land uses? No Pre-construction investigations e.g. bore Houses, soil testing? Details thereof with approximate quantities frates, wherever possible) with source of information data No Proposed Expansion will be carried out within the existing premises. Yes Minor site clearance activities shall be carried out. No Construction works? Yes For detail Please refer Annexure-II 1.6 Demolition works? No Temporary sites used for No -- construction works or housing of construction workers? 1.8 Above ground buildings, structures Yes For detail Please refer Annexure-II or earthworks including linear structures, cut and fill or excavations 1.9 Underground works mining or No -- tunneling? 1.10 Reclamation works? No Dredging? No Off shore structures? No Production and manufacturing Yes For detail Please refer Annexure-III processes? 1.14 Facilities for storage of goods or materials? Yes Areas for storage of raw materials and finished products will be available Facilities for treatment or disposal of solid waste or liquid effluents? Yes Details of the Liquid Effluent are given as Annexure-V and details of solid waste are given as Annexure-VI Facilities for long term housing of No -- operational workers? 1.17 New road, rail or sea traffic during No -- Construction or Operation? 1.18 New road, rail, air waterborne or No -- other transport infrastructure Page 4 of 48

5 including new or altered routes and stations, ports, airports etc? 1.19 Closure or diversion of existing No -- transport routes or infrastructure leading to changes in traffic movements? 1.20 New or diverted transmission lines No -- or Pipelines? 1.21 Impoundment, damming, culverting, No -- realignment or other changes to the hydrology of watercourses or aquifers? 1.22 Stream crossings? No Abstraction or transfers of water Yes Water Source: GIDC Water Supply form ground or surface waters? 1.24 Changes in water bodies or the land No -- surface Affecting drainage or runoff? 1.25 Transport of personnel or materials for construction, operation or decommissioning? 1.26 Long-term dismantling or decommissioning or restoration works? 1.27 Ongoing activity during decommissioning which could have an impact on the environment? Yes Transportation of personnel, raw material and products will be primarily by road only. No -- No Influx of people to an area either temporarily or permanently? 1.29 Introduction of alien species? No Loss of native species or genetic No -- diversity? 1.31 Any other actions? No -- No Direct/Indirect employment shall be generated after proposed expansion. 2. Use of Natural resources for construction or operation of the Project (such as land, water, materials or energy, especially any resources which are non-renewable or in short supply): Sr. No. Information/checklist confirmation Yes/No Details there of (with approximate quantities frates, wherever possible) with source of information data 2.1 Land especially undeveloped or No -- agricultural land (ha) 2.2 Water (expected source & Yes Water Source: GIDC Water Supply competing users) unit: KLD Please refer Annexure-IV. 2.3 Minerals (MT) No -- Page 5 of 48

6 2.4 Construction material - stone, aggregates, and / soil (expected source - MT) 2.5 Forests and timber (source - MT) No Energy including electricity and fuels (source, competing users) Unit: fuel (MT), energy (MW) Yes Construction materials, like steel, cement, crushed stones, sand, rubble, etc. required for the project shall be procured from the local market of the region. Yes Power requirement will be 400 KVA Existing = 300 KVA Additional = 100 KVA (100 KVA D.G. Set will be kept for emergency power back up) Source: DGVCL 2.7 Any other natural resources (use appropriate standard units) Fuel Requirement: Existing: Natural Gas = 200 SM 3 /Day Additional: Natural Gas = 300 SM 3 /Day Total = Natural Gas = 500 SM 3 /Day Diesel= 50 Lit./Day (Only for emergency). Source: Gujarat Gas Co. Ltd. No Use, storage, transport, handling or production of substances or materials, which could be harmful to human health or the environment or raise concerns about actual or perceived risks to human health Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 3.1 Use of substances or materials, which are hazardous (as per MSIHC Yes For detail please refer Annexure- VII rules) to human health or the environment (flora, fauna, and water supplies) 3.2 Changes in occurrence of disease or No -- affect disease vectors (e.g. insect or water borne diseases) 3.3 Affect the welfare of people e.g. by changing living conditions? 3.4 Vulnerable groups of people who could be affected by the project e.g. hospital patients, children, the elderly etc. No -- No -- Page 6 of 48

7 3.5 Any other causes No Production of solid wastes during construction or operation or decommissioning (MT/month) Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 4.1 Spoil, overburden or mine wastes No Municipal waste (domestic and or No -- commercial wastes) 4.3 Hazardous wastes (as per Hazardous Yes Please refer Annexure-VI Waste Management Rules) 4.4 Other industrial process wastes Yes Please refer Annexure-VI 4.5 Surplus product No Sewage sludge or other sludge from Yes Please refer Annexure-VI effluent treatment 4.7 Construction or demolition wastes Construction waste shall be utilized No for leveling, land filling in the premises. 4.8 Redundant machinery or equipment No Contaminated soils or other materials No Agricultural wastes No Other solid wastes No Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 5.1 Emissions from combustion of fossil Yes Please refer as Annexure-VIII fuels from stationary or mobile sources 5.2 Emissions from production processes Yes Please refer as Annexure-VIII 5.3 Emissions from materials handling storage or transport Yes Solid raw materials shall be charged through close pipeline into reactors and the dust collection hopper shall be connected to a bag filter and ID fan. Page 7 of 48

8 5.4 Emissions from construction activities including plant and equipment 5.5 Dust or odors from handling of materials including construction materials, sewage and waste 5.6 Emissions from incineration of waste No -- Also all hazardous chemicals storage tanks will be provided with flame arrestors & breather valves for safety. No During construction work, only dust contamination will be there & water sprinklers shall be utilized whenever necessary. No Emissions from burning of waste in open air (e.g. slash materials, construction debris) 5.8 Emissions from any other sources No -- No Generation of Noise and Vibration, and Emissions of Light and Heat: Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data with source of information data 6.1 From operation of equipment e.g. engines, ventilation plant, crushers Yes The Noise level will be within the prescribed limit. At noisy area, adequate preventive & control measures will be taken. No significant noise, vibration or emission of light & heat from the unit. D.G. Set will be installed in a closed room and provided with acoustic enclosure. 6.2 From industrial or similar processes Yes All machinery / equipment shall be well maintained, shall have proper foundation with anti vibrating pads wherever applicable to keep noise levels within permissible limits. Acoustic enclosures shall be provided for DG set. 6.3 From construction or demolition No From blasting or piling No -- Page 8 of 48

9 6.5 From construction or operational traffic No From lighting or cooling systems No From any other sources No Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea: Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 7.1 From handling, storage, use or spillage of hazardous materials Yes All raw materials shall be stored separately in designated storage area with safely measures. For detail please refer Annexure- 7.2 From discharge of sewage or other effluents to water or the land (expected mode and place of discharge) 7.3 By deposition of pollutants emitted to air into the and or into water VII Yes Sewage effluent is disposed through septic tank / soaks pit system. No From any other sources No Is there a risk of long term build up of pollutants in the environment from these sources? No Risk of accidents during construction or operation of the Project, which could affect human health or the environment Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 8.1 From explosions, spillages, fires etc. from storage, handling, use or Yes For detail please refer Annexure- VIII production of hazardous substances 8.2 From any other causes No Could the project be affected by natural disasters causing environmental damage (e.g. floods, earthquakes, landslides, cloudburst No -- Page 9 of 48

10 etc)? 9. Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality Sr. Information/Checklist confirmation Yes/No Details there of (with approximate No. quantities/rates, wherever possible) with source of information data 9.1 Lead to development of supporting. lities, ancillary development or development stimulated by the project which could have impact on the environment e.g. Supporting infrastructure (roads, power supply, waste or waste water Yes Site is having the entire required infrastructure. Existing road infrastructure & power supply are to be utilized. Local people will be employed and no housing is required. For detail please refer Annexure-IX treatment, etc.) housing development extractive industry supply industry other 9.2 Lead to after-use of the site, which No -- could have an impact on the environment 9.3 Set a precedent for later No -- developments 9.4 Have cumulative effects due to proximity to other existing or planned projects with similar effects No -- (III) Environmental Sensitivity Sr. No. Information/Checklist confirmation 1 Areas protected under international conventions, national or local legislation for their ecological, landscape, cultural or other related value Name/ Identity Aerial distance (within 5 km) Proposed project location boundary No No protected area within 5 km from the proposed expansion project site. Page 10 of 48

11 2 Areas which important for are or sensitive Ecol logical reasons - Wetlands, watercourses or other water bodies, coastal zone, biospheres, mountains, forests 3 Area used by protected, important or sensitive Species of flora or fauna for breeding, nesting, foraging, resting, over wintering, migration 4 Inland, coastal, marine or underground waters Yes River Narmada = 12 km No -- No -- 5 State, National boundaries No -- 6 Routes or facilities used by the public Yes Public transportation for access to recreation or other tourist, pilgrim areas 7 Defense installations Yes Ankleshwar 8 Densely populated or built-up area Yes Panoli village 3.0 km and Ankleshwar city around 4.0 km from the proposed expansion project site. 9 Area occupied by sensitive manmade land uses Hospitals, schools, places of worship, community facilities) 10 Areas containing important, high quality or scarce resources (ground water resources, surface resources, forestry, agriculture, fisheries, tourism, minerals) 11 Areas already subjected to pollution environmental damage. (those where existing legal environmental standards are exceeded) 12 Are as susceptible to natural hazard which could cause the project to present environmental problems (earthquakes, subsidence,landslides, flooding erosion, or extreme or adverse climatic conditions) No -- No -- Yes Ankleshwar No -- IV). Proposed Terms of Reference for EIA studies: For detail please refer Annexure-X Page 11 of 48

12 I hereby given undertaking that the data and information given in the application and enclosures are true to the best of my knowledge and belief and I am aware that if any part of the data and information submitted is found to be false or misleading at any stage, the project will be rejected and clearance given, if any to the project will be revoked at our risk and cost. Date: May 27, 2017 Place: Panoli NOTE: 1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall submit with the application a C.R.Z. map duly demarcated by one of the authorized agencies, showing the project activities, w.r.t. C.R.Z. (at the stage of TOR) and the recommendations of the State Coastal Zone Management Authority (at the stage of EC). Simultaneous action shall also be taken to obtain the requisite clearance under the provisions of the C.R.Z. Notification, 1991 for the activities to be located in the CRZ. 2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location and the recommendations or comments of the Chief Wildlife Warden thereon (at the stage of EC). 3. All correspondence with the Ministry of Environment & Forests including submission of application for TOR/Environmental Clearance, subsequent clarifications, as may be required from time to time, participation in the EAC Meeting on behalf of the project proponent shall be made by the authorized signatory only. The authorized signatory should also submit a document in support of his claim of being an authorized signatory for the specific project. Page 12 of 48

13 LIST OF ANNEXURES SR. NO. I II III IV V VI VII VIII IX X XI XII XIII XIV XV XVI NAME OF ANNEXURE List of products with their production capacity Layout Map of the Plant Brief Manufacturing Process Description with Chemical and Mass Balance Details of Water Consumption Wastewater Generation Details of Effluent Treatment Scheme Details of Hazardous / Solid Waste Generation, Handling and Disposal Details of Hazardous Chemicals Storage & Handling Details of Air pollution Control System (Stack& Vent) Socio-economic Impacts Proposed Terms of Reference for EIA studies Copy of Plot Allotment Letter GIDC Water Supply Certificate Membership Certificate of CETP (M/s. PETL) Membership Certificate of Common Solid Waste Disposal Facility (M/s. BEIL) Membership Certificate of Common Incineration Facility (M/s. BEIL) Toposheet Page 13 of 48

14 ANNEXURE-I LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY Sr. No. Name of Products CAS No. Existing Additional Total After Proposed Expansion 1 Cetyl Chloride Lauryl Chloride Stearyl Chloride Decyl Chloride Myristyl Chloride Lauroyl Chloride Phenyl Acetyl Chloride Palmitoyl Chloride MT/Month MT/Month 150 MT/Month Page 14 of 48

15 LIST OF RAW MATERIALS Sr. No. Name of Raw Materials Existing Cetyl Chloride Capacity (MT/Month) 1 Cetyl Alcohol HCL Water Caustic Soda 0.36 Lauryl Chloride 1 Lauryl Alcohol HCL Water Caustic Soda 0.36 Stearyl Chloride 1 Stearyl Alcohol HCL Water Caustic Soda 0.36 Decyl Chloride 1 Decyl Alcohol HCL Water Caustic Soda 0.36 Myristyl Chloride 1 Myristyl Alcohol HCL Water Caustic Soda 0.36 Proposed Cetyl Chloride 1 Cetyl Alcohol Thionyl Chloride Sodium Hydroxide Water Lauryl Chloride 1 Lauryl Alcohol Thionyl Chloride Sodium Hydroxide Water Page 15 of 48

16 Stearyl Chloride 1 Stearic Acid Thionyl Chloride Sodium Hydroxide Water Decyl Chloride 1 Decyl Alcohol Thionyl Chloride Sodium Hydroxide Water Myristyl Chloride 1 Myristyl Alcohol Thionyl Chloride Sodium Hydroxide Water Lauroyl Chloride 1 Lauric Acid Thionyl Chloride Sodium Hydroxide Water Phenyl Acetyl Chloride 1 Phenyl Acetic Acid Thionyl Chloride Sodium Hydroxide Water Palmitoyl Chloride 1 Palmitic Acid Thionyl Chloride Sodium Hydroxide Water Page 16 of 48

17 ANNEXURE-II LAYOUT MAP OF THE PLANT Page 17 of 48

18 ANNEXURE-III BRIEF MANUFACTURING PROCESS DESCRIPTION WITH CHEMICAL AND MASS BALANCE Existing: 1) Cetyl Chloride Manufacturing Process: Take Cetyl alcohol in to reactor. Charge slowly HCl into it at room temp. After addition heat whole mass up to 75 C to 80 C. maintain temp. for 6 to 8 hrs. Further heat whole mass up to 120 C to 125 C. Maintain temp. for 10 to 12 hrs. Saperate out lower layer of water. The upper layer of crude Cetyl chloride subjected to distillation to obtain pure Cetyl chloride. Chemical Reaction: CH3(CH2)14CH2OH + HCL = CH3(CH2)14CH2CL + H20 (CETYL ALCOHOL) (HYDROCHLORIC ACID) (CETYL CHLORIDE) (WATER) Mass Balance: CETYL CHLORIDE INPUT (KG) OUTPUT(KG) CETYL ALCOHOL 929 CETYL CHLORIDE 1000 CONC. HCL 140 EFFLUENT 436 WATER 327 CAUSTIC SODA 40 TOTAL Page 18 of 48

19 2) Lauryl Chloride Manufacturing Process: Take Lauryl alcohol in to reactor. Charge slowly HCl into it at room temp. After addition heat whole mass up to 75 C to 80 C. maintain temp. for 6 to 8 hrs. Further heat whole mass up to 115 C to 120 C. Maintain temp. for 10 to 12 hrs. Saperate out lower layer of water. The upper layer of crude Lauryl chloride subjected to distillation to obtain pure Lauryl chloride. Chemical Reaction: CH3(CH2)10CH2OH + HCL = CH3(CH2)10CH2CL + H20 (LAURYL ALCOHOL) (HYDROCHLORIC ACID) (LAURYL CHLORIDE) (WATER) Mass Balance: LAURYL CHLORIDE INPUT (KG) OUTPUT(KG) LAURYL ALCOHOL 910 LAURYL CHLORIDE 1000 CONC. HCL 179 EFFLUENT 449 WATER 320 CAUSTIC SODA 40 Total Page 19 of 48

20 3) Stearyl Chloride Manufacturing Process: Take Stearyl alcohol in to reactor. Charge slowly HCl into it at room temp. After addition heat whole mass up to 75 C to 80 C. maintain temp. for 6 to 8 hrs. Further heat whole mass up to 130 C to 135 C. Maintain temp. for 10 to 12 hrs. Saperate out lower layer of water. The upper layer of crude Stearyl chloride subjected to distillation to obtain pure Stearyl chloride. Chemical Reaction: CH3(CH2)16CH2OH + HCL = CH3(CH2)16CH2CL + H20 (STEARYL ALCOHOL) (HYDROCHLORIC ACID) (STEARYL CHLORIDE) (WATER) Mass Balance: STEARYL CHLORIDE INPUT (KG) OUTPUT(KG) STEARYL ALCOHOL 936 STEARYL CHLORIDE 1000 CONC. HCL 127 EFFLUENT 400 WATER 297 CAUSTIC SODA 40 Total Page 20 of 48

21 4) Decyl Chloride Manufacturing Process: Take Decyl alcohol in to reactor. Charge slowly HCl into it at room temp. After addition heat whole mass up to 75 C to 80 C. maintain temp. for 6 to 8 hrs. Further heat whole mass up to 110 C to 115 C. Maintain temp. for 10 to 12 hrs. Saperate out lower layer of water. The upper layer of crude Decyl chloride subjected to distillation to obtain pure Decyl chloride. Chemical Reaction: CH3(CH2)8CH2OH + HCL = CH3(CH2)8CH2CL + H20 (DECYL ALCOHOL) (HYDROCHLORIC ACID) (DECYL CHLORIDE) (WATER) Mass Balance: DECYL CHLORIDE INPUT (KG) OUTPUT(KG) DECYL ALCOHOL 895 DECYL CHLORIDE 1000 CONC. HCL 207 EFFLUENT 474 WATER 332 CAUSTIC SODA 40 Total Page 21 of 48

22 5) Myristyl Chloride Manufacturing Process: Take Myristyl alcohol in to reactor. Charge slowly HCl into it at room temp. After addition heat whole mass up to 75 C to 80 C. maintain temp. for 6 to 8 hrs. Further heat whole mass up to 125 C to 130 C. Maintain temp. for 10 to 12 hrs. Saperate out lower layer of water. The upper layer of crude Myristyl chloride subjected to distillation to obtain pure Myristyl chloride. Chemical Reaction: CH3(CH2)12CH2OH + HCL = CH3(CH2)12CH2CL + H20 (MYRISTYL ALCOHOL) (HYDROCHLORIC ACID) (MYRISTYL CHLORIDE) (WATER) Mass Balance: MYRISTYL CHLORIDE INPUT (KG) OUTPUT(KG) MYRISTYL ALCOHOL 920 MYRISTYL CHLORIDE 1000 CONC. HCL 157 EFFLUENT 449 WATER 332 CAUSTIC SODA 40 Total Page 22 of 48

23 Proposed: 6) Cetyl Chloride Manufacturing Process: Cetyl Alcohol is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the consumer. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the consumer. The crude Cetyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Cetyl Chloride. Process Flow Diagram for Cetyl Chloride: Cetyl Alcohol Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Cetyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 14 CH 2 OH + SOCL 2 CH 3 (CH 2 ) 14 CH 2 CL + SO 2 + HCL Mass Balance: INPUT (M.T) OUTPUT (M.T) Cetyl Alcohol 9.29 Cetyl Chloride 9.95 Residue 0.05 Thionyl Chloride 4.56 Bye-Product Sodium Hydroxide 3.04 Hydrochloric Acid 25% to 30% 6.00 Water Sodium Sulphite 20 to 25% Total Page 23 of 48

24 7) Lauryl Chloride Manufacturing Process: Lauryl Alcohol is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the Party. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the party. The crude Lauryl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Lauryl Chloride. Process Flow Diagram for Lauryl Chloride: Lauryl Alcohol Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Lauryl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 10 CH 2 OH + SOCL 2 CH 3 (CH 2 ) 10 CH 2 CL + SO 2 + HCL Lauryl Thionyl Lauryl Chloride Alcohol Chloride Mass Balance: INPUT (M.T) OUTPUT (M.T) Lauryl Alcohol 8.66 Lauryl Chloride 9.95 Residue 0.05 Thionyl Chloride 3.07 Bye-Product Sodium Hydroxide 2.56 Hydrochloric Acid 25% to 30% 4.20 Water 26.0 Sodium Sulphite 20 to 25% Total Page 24 of 48

25 8) Stearyl Chloride Manufacturing Process: Stearyl alcohol is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is scrubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the End user. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the end user. The crude Stearyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Stearyl Chloride. Process Flow Diagram for Stearyl Chloride: Stearyl Alcohol Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Stearyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 16 CH 2 OH + SOCL 2 CH 3 (CH 2 ) 16 CH 2 CL + SO 2 + HCL Mass Balance: INPUT (M.T) OUTPUT (M.T) Stearic Acid Stearayl Chloride 9.95 Thionyl Chloride Residue 0.05 Sodium Hydroxide Hydrochloric Acid 25% to 30% Water Sodium Sulphite 20 to 25% Total Page 25 of 48

26 9) Decyl Chloride Manufacturing Process: Decyl Alcohol is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the End user. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the end user. The crude Decyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Decyl Chloride. Process Flow Diagram for Decyl Chloride: Decyl Alcohol Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Decyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 8 CH 2 OH + SOCL 2 CH 3 (CH 2 ) 8 CH 2 CL + SO 2 + HCL Mass Balance: INPUT (M.T) OUTPUT (M.T) Decyl Alcohol Decyl Chloride 9.95 Residue Thionyl Chloride Bye-Product Sodium Hydroxide Hydrochloric Acid 25% to 30% Water Sodium Sulphite 20 to 25 % Total Page 26 of 48

27 10) Myristyl Chloride Manufacturing Process: Myristyl alcohol is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is scrubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the End user. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the end user. The crude Myristyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Myristyl Chloride. Process Flow Diagram for Myristyl Chloride: Myristyl Alcohol Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Myristyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 12 CH 2 OH + SOCL 2 CH 3 (CH 2 ) 12 CH 2 CL + SO 2 + HCL Mass Balance: INPUT(M.T) OUTPUT(M.T) Myristyl alcohol 9.1 Myristyl Chloride 9.95 Residue 0.05 Thionyl Chloride Bye-Product Sodium Hydroxide Hydrochloric Acid 25% to 30% 5.92 Water Sodium Sulphite 20% to 25% Total Page 27 of 48

28 11) Lauroyl Chloride Manufacturing Process: Lauric Acid is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the Party. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the party. The crude Lauroyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Lauroyl Chloride. Process Flow Diagram for Lauroyl Chloride: Lauric Acid Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Lauroyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 10 COOH + SOCL 2 CH 3 (CH 2 ) 10 COCL + SO 2 + HCL Lauric Thionyl Lauroyl Chloride Acid Chloride Mass Balance: INPUT (M.T) OUTPUT (M.T) Lauric Acid 9.15 Lauroyl Chloride 9.95 Residue 0.05 Thionyl Chloride 5.44 Bye-Product Sodium Hydroxide 3.66 Hydrochloric Acid 25% to 30% 5.56 Water Sodium Sulphite 20 to 25% Total Page 28 of 48

29 12) Phenyl Acetyl Chloride Manufacturing Process: Phenyl Acetic Acid is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the Party. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the party. The crude Phenyl Acetyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Phenyl Acetyl Chloride. Process Flow Diagram for Phenyl Acetyl Chloride: Phenyl Acetic Acid Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Phenyl Acetyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 14 COOH + SOCL 2 CH 3 (CH 2 ) 14 COCL + SO 2 + HCL Phenyl Thionyl Phenyl Acetyl Chloride Acetic Acid Chloride Mass Balance: INPUT (M.T) OUTPUT (M.T) Phenyl Acetic Acid 8.66 Phenyl Acetyl Chloride 9.95 Residue 0.05 Thionyl Chloride 3.07 Bye-Product Sodium Hydroxide 2.56 Hydrochloric Acid 25% to 30% 4.20 Water 26.0 Sodium Sulphite 20 to 25% Total Page 29 of 48

30 13) Palmitoyl Chloride Manufacturing Process: Palmitic Acid is allowed to react with sufficient excess of Thionyl Chloride. At the time of reaction hydrochloric acid gas and/or sulfur dioxide gas gets generated. Hydrogen Chloride Gas is srubbed in Primary Glass Scrubber and Secondary Scrubber. The Hydrochloric Acid of about 25% to 30% concentration is produced and sold out to the Party. Sulphur Dioxide Gas is scrubbed in sulphur Dioxide Scrubber using Caustic Solution as Scrubbing Media. Sodium Sulfite of about 20% to 25% concentration is Produced and sold out to the party. The crude Palmitoyl Chloride so obtained is further subjected to distillation under vacuum to obtain pure Palmitoyl Chloride. Process Flow Diagram for Palmitoyl Chloride: Palmitic Acid Thionyl Chloride SO 2 gas scrubbed with NaOH in SO 2 scrubber HCL gas scrubbed with water in Pri & sec. HCL scrubber Chlorination Distillation Palmitoyl Chloride Residue to Incinerator Chemical Reaction: CH 3 (CH 2 ) 14 COOH + SOCL 2 CH 3 (CH 2 ) 14 COCL + SO 2 + HCL Palmitic Thionyl Palmitoyl Chloride Acid Chloride Mass Balance: INPUT(M.T) OUTPUT(M.T) Palmitic Acid 8.66 Palmitoyl Chloride 9.95 Residue 0.05 Thionyl Chloride 3.07 Bye-Product Sodium Hydroxide 2.56 Hydrochloric Acid 25% to 30% 4.20 Water 26.0 Sodium Sulphite 20 to 25% Total Page 30 of 48

31 ANNEXURE-IV WATER CONSUMPTION AND WASTEWATER GENERATION Water Consumption & Wastewater Generation Sr. No. Usage Water Consumption (KL/Day) Wastewater Generation (KL/Day) Existing Additional Total Existing Additional Total 1. Domestic Gardening NIL NIL NIL 3. Industrial a. Process NIL 0.14 b. Boiler NIL 0.13 c. Cooling NIL 0.13 d. Washing 0.2 NIL NIL 0.2 Total Industrial NIL 0.6 Total Page 31 of 48

32 Water Balance Diagram (Total) Water: 22.3 KL/Day Domestic: 1.0 KL/Day Industrial: 20.3 KL/Day Gardening: 1.0 KL/Day Process: 19.1 KL/Day Boiler: 0.5 KL/Day Cooling: 0.5 KL/Day Washing: 0.2 KL/Day 0.9 KL/Day: Septik Tank & Soak Pit Process: 0.14 KL/Day Boiler: 0.13 KL/Day Cooling: 0.13 KL/Day Washing: 0.2 KL/Day ETP 0.6 KL/Day 0.6 KL/Day Common CETP (M/s. PETL) for further treatment & disposal Page 32 of 48

33 ANNEXURE-V DETAILS OF EFFLUENT TREATMENT SCHEME Effluent Treatment Plant (ETP) First all non-toxic and biodegradable streams of wastewater shall be collected in Equalization cum Neutralization Tank (ENT-01) where the continuous addition and stirring of Caustic solution is done to maintain neutral ph of wastewater from Caustic Dosing Tank (LDT-01) as per requirement by gravity. Mixer is provided at bottom of the ENT-01 to keep all suspended solids in suspension and to provide proper mixing by Mixing Mechanism (M- 01). Then after, neutralized wastewater shall be pumped to Primary Settling tank (PST-01). Alum and Polyelectrolyte shall be dosed from Alum Dosing Tank (ADT-01) and Polyelectrolyte Dosing Tank (PEDT-1) respectively by gravity into PST-01 to carry out coagulation by using a Mixer. Then after, coagulated wastewater shall be settled in Primary Settling tank (PST-01). Clear supernatant from PST-01 shall be collected in treated effluent Sump (TES-01) before sent to PETL for further treatment. Effluent from the PETL tank transferred to M/s. PETL by tankers for future treatment and disposal. Sludge settled in PST-01 shall be sent to Sludge Drying Beds (SDBs-A/B) where, dewatering shall be carried out before storage in HWSA and ultimate disposal to TSDF. Leachate from SDBs-A/B shall be pumped back to ENT-01 for further treatment. Effluent from the PETL tank transferred to M/s. PETL by tankers for further treatment and disposal. Effluent Treatment Plant (Dimension): S.N. Name of unit Size (m x m x m) No. MOC/ Remark Flow = 0.6 KLD 1 Equalization cum Neutralization Tank (ENT-01) 1.0 x 1.0 x RCC M25 2 Mixer (M-01) 0.5x 0.5 x 1.0 LD 1 MSEP 3 Primary Settling Tank(PST-01) 1.5 x 1.0 x MSEP 4 Treated Effluent Sump (TES-01) 1.0 x 1.0 x RCC M25 5 Lime Dosing Tank (LDT-01) 250 lit 1 HDPE 6 Alum Dosing Tank (ADT-01) 250 lit 1 HDPE Page 33 of 48

34 7 Poly Dosing Tank (PDT-01) 100 lit 1 HDPE 8 Sludge Drying Beds (SDBs-A/B) 1.0 x 1.0 x Bk. Mas. With PCC Bedding+ filling Media RCC M25 PCC HDPE BK.MAS. = REINFORCED CEMENT CONCRETE (M 25 GRADE) = PLAIN CEMENT CONCRETE = HIGH DENSITY POLY ETHELINE = BRICK MASONARY Flow Diagram: EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE & AFTER TREATMENT Sr. Characteristics CETP Inlet Norms Parameter No. (mg/l) (mg/l) Untreated Treated 1. ph 2 to 10 7 to to SS 300 to to COD 2800 to to BOD to to Page 34 of 48

35 ANNEXURE-VI DETAILS OF HAZARDOUS / SOLID WASTE GENERATION, HANDLING AND DISPOSAL Cat. No. Hazardous Waste Existing 5.1 Used Oil 12 Lit/Year 33.1 Discarded Container/ Bags/Liners 120 Nos./Year 35.3 ETP Sludge 1.2 MT/Year Total after proposed expansion 20 Lit/Year 2400 Nos./Year 24 MT/Year 20.3 Distillation Residue NIL 3 MT/Year -- Hydrochloric Acid (25% to 30%) -- Sodium Sulphite (20% to 25%) NIL 1200 MT/Year NIL 3600 MT/Year Method of Disposal Collection, Storage, Transportation & disposal by sale to registered reprocessors Collection, Storage, Transportation, Decontamination & Sell to authorized vendors Collection, Storage, Transportation & disposal at nearest TSDF Site (M/s. BEIL) Collection, Storage, Transportation & disposal at common incineration site (M/s. BEIL) or given for coprocessing in cement industries Collection, Storage, Transportation & sell to end user Collection, Storage, Transportation & sell to end user DETAILS OF DISPOSAL OF SOLID WASTES Industry is a member of TSDF site of M/s. Bharuch Enviro Infrastructure Limited, Bharuch for suitable treatment & disposal of hazardous wastes from time to time. Page 35 of 48

36 ANNEXURE-VII DETAILS OF HAZARDOUS CHEMICALS STORAGE & HANDLING Sr. No. Raw Materials Storage Capacity Type of Storage No. of Vessel Vessel Capacity Type of Hazard 1. Cetyl Alcohol 10 MT Bags kg Corrosive 2. Thionyl Chloride 10 MT SS Tank 1 15 MT Toxic 3. Sodium Hydroxide 1 MT Bags kg Corrosive 4. Lauryl Alcohol 2 MT Drums liter Flammable 5. Stearic Acid 1 MT Bags kg Corrosive 6. Decyl Alcohol 1 MT Drums liter Flammable 7. Myristyl Chloride 1 MT Drums liter Corrosive 8. Lauric Acid 1 MT Bags kg Corrosive 9. Phenyl Acetyl Chloride 2 MT Bags kg Corrosive 10. Palmitoyl Chloride 3 MT Bags kg Corrosive Page 36 of 48

37 ANNEXURE-VIII DETAILS OF AIR POLLUTION CONTROL SYSTEM (STACK & VENT) EXISTING: 1. Details of Flue Gas Stack; Stack Attached To Steam Boiler Sr. No. Stacks Attached To 1 Steam Boiler (300 kg/hr.) Stack Height Fuel Permissible Limit 11 meter Natural Gas Particulate Matter = 150 mg/nm 3 SO 2 = 100 ppm NOx = 50 ppm ADDITIONAL: 1. Details of Flue Gas Stack; Stack Attached To Steam Boiler Sr. No. Stacks Attached To 1 Steam Boiler (600 kg/hr.) Stack Height Fuel Permissible Limit 11 meter Natural Gas Particulate Matter = 150 mg/nm 3 SO 2 = 100 ppm NOx = 50 ppm 2. Details of Process Vents Sr. Stack attached Stack Air Pollution Parameter Permissible No. to Height Control System Limit 1 Process Vent 15 m Two Stage Water & Alkali Scrubber HCl & SO 2 20 mg/nm 3 40 mg/nm 3 TOTAL AFTER PROPOSED EXPANSION: 1. Details of Flue Gas Stack; Stack Attached To Steam Boiler Sr. No. Stacks Attached To 1 Steam Boiler (600 kg/hr.) Stack Height Fuel Permissible Limit 11 meter Natural Gas Particulate Matter = 150 mg/nm 3 SO 2 = 100 ppm NOx = 50 ppm Page 37 of 48

38 2. Details of Process Vents Sr. Stack attached Stack Air Pollution No. to Height Control System 1 Process Vent 15 m Two Stage Water & Alkali Scrubber Parameter HCl & SO 2 Permissible Limit 20 mg/nm 3 40 mg/nm 3 Page 38 of 48

39 ANNEXURE-IX SOCIO - ECONOMIC IMPACTS 1) Employment Opportunities The manpower requirement for the proposed project is being expected to generate some permanent jobs and secondary jobs for the operation and maintenance of plant. This will increase direct / indirect employment opportunities and ancillary business development to some extent for the local population. This phase is expected to create a beneficial impact on the local socio-economic environment. 2) Industries Required raw materials and skilled and unskilled laborers will be utilized maximum from the local area. The increasing industrial activity will boost the commercial and economical status of the locality, to some extent. 3) Public Health The company regularly examines, inspects and tests its emission from sources to make sure that the emission is below the permissible limit. Hence, there will not be any significant change in the status of sanitation and the community health of the area, as sufficient measures have been taken and proposed under the EMP. 4) Transportation and Communication Since the existing factory is having proper linkage for the transport and communication, the development of this project will not cause any additional impact. In brief, as a result of the proposed expansion project there will be no adverse impact on sanitation, communication and community health, as sufficient measures have been proposed to be taken under the EMP. The proposed project is not expected to make any significant change in the existing status of the socio - economic environment of this region. Page 39 of 48

40 ANNEXURE-X PROPOSED TERMS OF REFERENCE FOR EIA STUDIES 1. Project Description Justification of project. Promoters and their back ground Project site location along with site map of 10 km area and site details providing various industries, surface water bodies, forests etc. Project cost Project location and Plant layout. Water source and utilization including proposed water balance. Product spectrum (proposed products along with production capacity) and process List of hazardous chemicals. Mass balance of each product Storage and Transportation of raw materials and products. 2. Description of the Environment and Baseline Data Collection Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 10 km area. Existing environmental status Vis a Vis air, water, noise, soil in 10 km area from the project site. For SPM, RSPM, SO 2, NOx. Ground water quality at 8 locations within 10 km. Complete water balance 3. Socio Economic Data Existing socio-economic status, land use pattern and infrastructure facilities available in the study area were surveyed. 4. Impacts Identification And Mitigatory Measures Identification of impacting activities from the proposed project during construction and operational phase. Impact on air and mitigation measures including green belt Impact on water environment and mitigation measures Soil pollution source and mitigation measures Noise generation and control. Solid waste quantification and disposal. 5. Environmental Management Plan Details of pollution control measures Environment management team Proposed schedule for environmental monitoring including post project Page 40 of 48

41 6. Risk Assessment Objectives and methodology of risk assessment Details on storage facilities Process safety, transportation, fire fighting systems, safety features and emergency capabilities to be adopted. Identification of hazards Consequence analysis through occurrence & evaluation of incidents Disaster Management Plan. 7. Information for Control of Fugitive Emissions 8. Post Project Monitoring Plan for Air, Water, Soil and Noise. 9. Information on Rain Water Harvesting 10. Green Belt Development plan Page 41 of 48