Ballast Water Online Chlorine Monitoring Solutions

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1 Ballast Water 2011 Online Chlorine Monitoring Solutions 3170 Metro Parkway, Ft. Myers, Florida USA Phone: (239) Fax (239) Toll free: Web Site:

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3 Our Mission... "To improve the quality of the world's water supply by providing innovative solutions through the design, manufacture and distribution of quality laboratory, field and on-line products." Simply stated, we consider the work we perform to be of critical importance to the preservation of a healthy planet. Our scientists, engineers and technicians are continually looking for ways in which we can enhance and expand our product line to better serve our customers worldwide. It is in this spirit that HFscientific approaches the threat of aquatic invasive species around the globe. We have taken our expertise in water quality instrumentation and applied our engineering innovation to provide a line of products for the marine and shipping industry. Rugged, dependable, and easy to use instrumentation will provide accurate measurement of the quality of ballast water, desalination or wastewater treatment equipment onboard, either up top or below deck. For three decades HFscientific has developed specialized expertise in measurements for water quality. Over the years our expertise expanded to include devices for monitoring parameters such as Free and Total Chlorine, Streaming Current and UV% Transmission. We are now excited to expand our product offering with the addition of our new AdvantEDGE Series of measurement electrodes. These electrode systems have been designed to reduce equipment and installation costs while improving reliability. Measurement parameters include ph, ORP, Free Chlorine, Raw Water Turbidity, Dissolved Oxygen, Optical Dissolved Oxygen, Dissolved Ozone, Contacting Conductivity and Toroidal Conductivity. Numerous integrated communications protocols are supported, including Modbus RTU, RS-232, RS-485 ASCII, Profibus, CANOpen, DeviceNet, Ethernet IP, and USB. Contact us directly or call the HFscientific representative serving your area to learn how we can provide you with the measurement solutions specific to your needs. HF scientific 3170 Metro Parkway, Ft. Myers, FL toll free: fax: HFinfo@watts.com

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5 Table of Contents: CLX Online Chlorine Monitor Specifications... 1 Dimensions and connections... 2 Competitive analysis... 5 CLX-XT Online Chlorine Monitor Specifications... 7 Layout... 8 Temperature testing data... 9 Dimensions and connections CLX-EX Online Chlorine Monitor (explosion proof model) Specifications Layout Dimensions and connections TrUV Intensity Sensor... 17

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7 Ordering Information OnLine Residual Chlorine Monitor The HF scientific OnLine Residual Chlorine Monitor is an economical and low maintenance instrument for chemical or industrial processes that require continuous monitoring and control of residual Free or Total Chlorine levels. User selectable cycle times, 4-20mA and RS-485 with Modbus output that can be used to control feed pumps and user selectable alarms allow complete manual or automatic control of chlorine dosing. The instrument is housed in a strong, shatterproof case with easy access to all service functions and reagents. Extended range to Standard Features Specifications 15ppm (option)! Free or Total chlorine Range: 0-10 mg/l Can be used for Free or Total Chlorine measurements Cycle Time: Low operating costs Low Reagent use translates into low operating cost Simple operation Designed for unattended operation up to 30 days Colorimetric DPD chemistry Uses inexpensive DPD chemistry rather than expensive electrodes User selectable cycle times Cycle times can vary between 110 seconds to 10 minutes (optional 60 seconds to 10 minutes) Microprocessor based technology Microprocessor based technology ensures high quality at the industry s lowest price Alarms Two User Selectable Alarms for Sample Concentration Drinking Water, Wastewater and more 4-20mA and RS-485 with Modbus USEPA accepted methodology Standard Method 4500-Cl G, DPD colorimetric method Certifications Lloyds Register Test Specification for Vibration and 22 Degree Tilt Test En 60954: 2002 Section 8.2, 8.4, 8.7, Specification test No1: Section 14 IEC 6-parameter Environmental Marine Test for high humidity, high temperature (86 C), low temperature (-5 C), salt spray Certified by ABS (American Bureau of Shipping) for marine use NEW! - Extended range to 15ppm (option) ± 10% accuracy Cat. No. Description OnLine Chlorine Residual Monitor for Free or Total Chlorine. Complete with Operating Manual. Reagents must be purchased separately. If the application combines high humidity with cold sample water, purchase a #09944 Desiccant Cartridge separately. Accessories Replacement tubing/cuvette kit 25018S Flow through cuvette (spare) Accuracy: Resolution: Method: Standard Outputs: User Alarms: Operating Temperature: Input Pressure: User Selectable: 110 seconds - 10 minutes Optional: 60 seconds - 10 minutes 0-6 mg/l - ±5% or 0.03 mg/l of Cl 2 whichever is greater 6-10 mg/l - ±10% 0.01 mg/l USEPA accepted DPD method of analysis for measuring Free or Total Residual Chlorine 4-20 ma and RS-485 with Modbus 2 User Selectable Alarms for Sample Concentration See note below* 0.3 bar bar (5-150psi) Enclosure: ABS Plastic, IP66 Power: VAC Auto Switchable 47-63hz Certifications: CE,UL, CSA, (ETL, ETLc) Shipping Dimensions: 16 x 16 x 10 (41cm x 41cm x 26cm) Shipping Weight: 8lbs (3.6kg) Flow Rate to Waste: ml/min Specifications subject to change without notice. * Operating temperature of CLX Monitor 0-55 C Operating temperature for 30-day reagent life 0-40 C Reagent life will be <30 days operating monitor above 40 C Kit Reagents Cat. No. J.A.W.* Dry** Liquid Free Chlorine 30 day supply X Total Chlorine 30 day supply X Free Chlorine 60 day supply N/A Total Chlorine 60 day supply N/A Free Chlorine 12 month supply X Total Chlorine 12 month supply X *Just Add Water (and supplied DPD reagent) **User must add Sulfuric Acid, Sodium Hydroxide and DPD reagent before use 1 with cover removed showing reagent bottles

8 All dimensions are in millimeters (inches) (12.82) (12.25) (8.625) Front View These 4 holes will accept up to 8 MM (5/16 inch) hardware (5.06) (11.75) Rear View Side View 2

9 LCD Display Power Latch Backlit sample cuvettereaction fully visible even with cover in place Alarm Relays RS-485 & 4-20 ma Pressure Regulator Buffer Reagent Bottle Indicator Solution Drain Bottle 1/2 inch I.D. drain tubing Inlet Tube 1/4" NPT with cover removed 3

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11 Comparative Review vs Hach CL 17* HF scientific CLX Hach CL-17 Range: Accuracy: 0-10 mg/l (PPM) Free or Total residual chlorine. 0-5 mg/l Free or Total residual chlorine. Any value above 5.0 will be displayed as 5.0. ± 5% of reading or ±0.03 mg/l (PPM), whichever is ±5% of reading or ±0.035 PPM whichever is greater. greater, for range of 0-6 mg/l (PPM). ±10% of reading for range of mg/l (PPM). Resolution: 0.01 mg/l (PPM) PPM. Selectable, 110 Seconds to 10 Minutes (defaults to minutes. Cycle Time: minutes. Optional 60 seconds to 10 minutes. Alarms: Outputs: Max Inlet Pressure: Two unpowered, programmable, VAC 2A Form C (SPDT ) Relays. One 4-20 ma with true isolation. Also RS-485 with Modbus Protocol. Integral Pressure regulator PSI. Optional low pressure adapter. Two unpowered SPDT relays each rated at 5 A resistive, 240 VAC maximum. One galvanically isolated recorder output, 4-20 ma. 1 to 5 psig is optimum. Exceeding 5 psig can cause sample tubing failure unless sample conditioning is used. Flow Rate: 200 to 400 ml/min. 200 to 500 ml/min. Reagent Usage: 1/2 liter Buffer & 1/2 liter Indicator per Month. 1/2 liter Buffer & 1/2 liter Indicator per month. Operating Temperature: 0 to 40 Degrees C (32 to 104 Degrees F). 5 to 40 Degrees C (41 to 104 Degrees F). Sample Temperature 0 to 40 Degrees C (32 to 104 Degrees F). 5 to 40 Degrees C (41 to 104 Degrees F). Range: Power Supply: VAC, AUTO switching, Hz, 150 VA /230 VAC (selection switch inside instrument). Enclosure: Designed to meet NEMA 4X / IP66. IP62-rated with the gasketed door latched. Regulatory: CE Approved, ETL Listed to UL , ETL Certified to CSA 22.2 No Shipping Weight: 8.6 lbs. (3.9 kg). 25 lbs. (1.3 kg). Instrument Dimensions 11.75" x 11.75" x 5.25" 13.5" x 16.5" x 7.5" Shipping Dimensions: 16.25" x 16.25" x 9.5".?? Warranty: 18 Months. 12 Months Display: LCD, Adjustable Backlit. LCD. Wetted Materials PVC, Borosilicate Glass, Reslyn (FFKM), Viton, (FKM), Polypropylene, Stainless Steel, Acetal, Noryl, Silicone.?? CE Approved. ETL Listed to UL ETL Certified to CSA 22.2 No Insulating Rating Environmental Conditions: Double Insulated, Pollution Degree 2, Overvoltage Category II. Up to 95% RH ( non-condensing).?? Humidity 90% at 40 Degrees C (90% at 104 Degrees F). *Hach is a registered trademark of the Hach Company 5

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13 -XT OnLine Residual Chlorine Monitor The HF scientific -XT OnLine Residual Chlorine Monitor is an economical and low maintenance instrument for shipboard ballast water, potable water or wastewater applications that require continuous monitoring and control of residual Total Chlorine levels. This marine grade chlorine monitor allows for up to 90 days of unattended operation. User selectable cycle times, 4-20mA and RS-485 with Modbus output that can be used to control feed pumps and user selectable alarms allow complete manual or automatic control of chlorine dosing. The instrument is housed in a strong, shatterproof IP66 case (fan IP54) with easy access to all service functions and reagents. Standard Features Extended range to 15ppm (option)! Specifications Optimized for high temperature marine applications Use in areas of high ambient temperatures up to 55 Total chlorine Can be used for Total Chlorine measurements Low operating costs Simple operation Designed for unattended operation up to 90 days (depending on cycle time) Colorimetric DPD chemistry Cycle times Cycle times can vary between 110 seconds to 10 minutes (optional 60 seconds to 10 minutes) Alarms Two user selectable alarms for sample concentration Ballast Water Treatment, Drinking Water, Wastewater and More 4-20mA and RS-485 with Modbus USEPA accepted method Certified to: Lloyds Register Test Specification for Vibration and 22 Degree Tilt Test En 60954: 2002 Section 8.2, 8.4, 8.7, Specification test No1: Section 14 NEW! - Extended range to 15ppm (option) ± 10% accuracy Range: Cycle Time: Accuracy: Resolution: Method: Standard Outputs: User Alarms: Operating Temperature: Input Pressure: Enclosure: Power: Certifications*: Flow Rate to Waste: Installed Dimensions: Specifications subject to change without notice mg/l User selectable: 110 seconds - 10 minutes Optional: 60 seconds - 10 minutes 0-6 mg/l - ±5% or 0.03 mg/l of Cl 2 whichever is greater 6-10 mg/l - ±10% 0.01 mg/l USEPA accepted DPD method of analysis for measuring Total Residual Chlorine 4-20 ma and RS-485 with Modbus 2 user selectable alarms for sample concentration 0-55 C (32 to 131 F) 0.3 bar bar (5-150psi) IP66 (except fan IP54) VAC Auto Switchable 47-63hz CE,UL, CSA, (ETL, ETLc) ml/min 15.7 x 18.3 x 8.5 (40cm x 46.5cm x 21.6cm) Reagent Kit Cat. No. Total Chlorine reagent for CLX-XT 12 month supply (based on estimated BWTS operational cycles) Ordering Information Cat. No. Description CLX-XT OnLine Chlorine Residual Monitor for Total Chlorine complete with operating manual. Reagents must be purchased separately. If the application combines high humidity with cold sample water, purchase a #09944 (desiccant cartridge) separately. Accessories Replacement tubing/cuvette kit 25018S Flow through cuvette (spare) CLX-XT with door open 7

14 CLX-XT Monitor CLX-XT Monitor with door open 8

15 9 This test data represents an instrument that was operated in a constant ambient air temperature of 55 C (131 F) for 90 days. The integral Peltier Cooling System was proven to maintain a reagent temperature below 25 C (77 F), which will extend the reagent life from one (1) month to three (3) months. This reagent life claim was substantiated in a separate controlled experiment described on page 10.

16 12 Weeks: CLX JAW Reagent 25 o C 10 Control 12 Weeks % ppm Cl % % Jaw 25 C Jaw 25 C Jaw 25 C Data shows that the accuracy of the CLX stays within specifications (±5%) for 12 weeks when the reagent temperature is controlled to a maximum of 25 degrees C. Testing was performed to determine the effect of temperature on the CLX JAW reagents. Reagents were prepared and held at 25 C in an environmental chamber for the duration of the testing. The temperature controlled reagents were installed into a CLX weekly and the data collected was compared to control data. The control consisted of a fresh reagent set that was prepared immediately prior to data collection. Test data proved that by controlling the temperature at 25, the life of the reagent was extended from 30 days to 90 days with all Cl 2 measurements within specification (±5% 0-6ppm and ±10% 6-10ppm). 10

17 OPTICAL BLOCK VENT REAGENT VENT-BUFFER [215,39] POWER IN INSTRUMENT SIGNAL OUT 4-20MA RS-485/Modbus SIGNAL OUT ALARMS INSTRUMENT DRAIN [398,92] [464,24] INSTRUMENT WATER INLET POWER IN CHILLER [363,34] REAGENT VENT-INDICATOR [414,14] [457,45] AIR INTAKE CHILLER EXHAUST AIR CHILLER REVISION HISTORY RE ECR DESCRIPTION OF CHANGE DATE BY APP 1 Drawing Origin 8/24/10 JCZ * UNLESS OTHERWISE SPECIFIED ALL DIMENSIONS ARE IN INCHES: INCH TOLERANCES ARE: METRIC TOLERANCES ARE: FRACTION: `1/64 DECIMALS: X,X `0,25MM DECIMALS: X.X `0.1 X,XX `0,13 MM X.XX `0.01 X.XXX `0.005 ANGLES: `0.5 ANGLES: `0.5 INDICATES 100% Q.A. CHECK *NOTICE* THIS DRAWING CONTAINS PROPRIETARY INFORMATION. NO DISCLOSURE, USE, OR REPRODUCTION MAY BE MADE OF THE INFORMATION CONTAINED IN THIS DRAWING WITHOUT THE EXPRESS WRITTEN CONSENT OF HFscientific DO NOT SCALE DRAWING NEXT ASSY. MODEL NO. DRAWING # 20040XT FILE: Ballast Water CLX Larger Enclosure.iam SCALE: 3170 METRO PARKWAY FORT MYERS, FLORIDA PHONE: FAX: HFINFO@WATTS.COM WEBSITE: CLX XT W/ INTEGRAL COOLER REV. # Z :4 SIZE:B Sheet 1 of 1 11

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19 -EX (Explosion Proof) OnLine Residual Chlorine Monitor The HF scientific -EX OnLine Residual Chlorine Monitor is a rugged, safe, and low maintenance instrument for shipboard ballast water treatments systems that require continuous monitoring and control of residual Total Chlorine levels. User selectable cycle times, 4-20mA and RS-485 with Modbus output that can be used to control feed pumps and user selectable alarms allow complete manual or automatic control of chlorine dosing. Extended range to 15ppm (option)! Standard Features Optimized for marine applications Use in explosive atmospheres where combustible fuel vapors may be present Housing certified for Class 1, Division 1, ATEX, and Class 1,Zone 1 Total chlorine Can be used for Total Chlorine measurements Able to operate in ambient temperatures up to 55 C Low operating costs Low Reagent use translates into low operating cost Simple operation Designed for unattended operation up to 90 days Colorimetric DPD chemistry Cycle times Cycle times can vary between 110 seconds to 10 minutes (optional 60 seconds to 10 minutes) Alarms Two User Selectable Alarms for Sample Concentration Ballast water treatment, Drinking water, Wastewater and more 4-20mA and RS-485 with modbus ATEX certified explosion proof (pending) Suitable for Class 1, Division 1 environments USEPA accepted method Certified to: Lloyds Register Test Specification for Vibration and 22 Degree Tilt Test En 60954: 2002 Section 8.2, 8.4, 8.7, Specification test No1: Section 14 NEW! - Extended range to 15ppm (option) ± 10% accuracy Ordering Information Specifications Range: Cycle Time: Accuracy: Resolution: 0-10 mg/l User Selectable: 110 seconds - 10 minutes Optional: 60 seconds - 10 minutes 0-6 mg/l - ±5% or 0.03 mg/l of Cl 2 whichever is greater 6-10 mg/l - ±10% 0.01 mg/l Method: USEPA accepted DPD method of analysis for measuring Total Residual Chlorine Standard Outputs: 4-20 ma and RS-485 with Modbus User Alarms: 2 User Selectable Alarms for Sample Concentration Operating Temperature: 0-55 C (32 to 131 F) Sample Pressure: 0.3 bar bar (5-150psi) Air Pressure: 5-7 bar ( psi) Enclosure: Nema 4X, IP66 Power: 240 VAC Certifications: CE,UL, CSA, (ETL, ETLc), ATEX, IP66 Flow Rate to Waste: ml / min Installed Dimensions: 18.5 x 16 x 9.9 (47cm x 40.6cm x 25.1cm) Specifications subject to change without notice. Reagent Kits Catalog number Total Chlorine reagent for CLX-EX 12 month supply (based on estimated BWTS operational cycles) Cat. No. Description CLX-EX OnLine Chlorine Residual Monitor 240VAC for Total Chlorine complete with operating manual. Reagents must be purchased separately. Accessories Replacement tubing/cuvette kit 25018S Flow through cuvette (spare) 13

20 CLX-EX (Explosion Proof) Monitor 14

21 2.000 [50,80] [151,78] [97,71] [50,80] [273,81] [625,09] [414,77] [254,00] [304,80] [114,21] [153,63] [450,85] [406,40] Ø.375 THRU WATER INLET, FOR 1/4" OD STAINLESS STEEL TUBING WATER OUTLET, FOR 1/2" OD STAINLESS STEEL TUBING [121,79] [35,46] 15

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23 TrUV Intensity Sensor for Ballast Water Treatment Systems Mounted outside of a UV reactor and looking through a quartz viewing port, the TrUV Intensity Sensor from HF scientific monitors the UV energy to provide the status of the life of the UV lamps. The signal output can be sent to a PLC or workstation to continuously monitor the lamp s intensity. The lightweight, compact design of rugged and corrosion resistant PVC enables the TrUV Sensor to provide reliable service in the harshest of conditions. Information needed to determine if cleaning or replacement is necessary is always at the operator s fingertips. With HF scientific s TrUV Sensor you can be confident of the proper dosing of UV for your Ballast Water Treatment system. image Standard Features Rugged - for shipboard use Corrosion resistant PVC construction Low maintenance design Adjustable sensitivity Specifications Ordering Information Cat. No. Description Sensor with two meter cable Body material: PVC Detector: Photodiode Spectral peak: 254nm Optical filter: Teflon Output signal: 0-5 VDC Sensitivity: Adjustable Power source: 12 VDC Mounting: Threaded fitting ¾ Connection: Turck pico-fast series cable Dimensions: Length 3.4 (86 mm) Diameter 1.2 (30.5mm) Shipping weight: 6.7 oz (190g) Cable length: Available in 1 or 2 meter lengths Specifications subject to change without notice. 17

24 HF scientific 3170 Metro Parkway, Ft. Myers FL ph: (239) fax: (239) toll free: Rev 0.3