SECTION 1: Identification of the substance/mixture and of the company/undertaking

Transcription

1 Date of issue: 2/13/2017 Revision date: 2/13/2017 Supersedes: 11/4/2016 Version: 4.01 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : DAP Chemical name EC No : , CAS No : , Article number : 8022 : ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3- tricarboxylate 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Fertilizer Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier EuroChem Agro GmbH Reichskanzler-Müller-Str Mannheim - Germany T F info.europe@eurochemgroup.com competent person sds@kft.de 1.4. Emergency telephone number Emergency number : National Response Center (international) TUIS-Emergency number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances Chemical name : ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3-2/13/2017 GB - en 1/7

2 tricarboxylate CAS No : , EC No : , Name Product identifier % diammonium hydrogenorthophosphate (CAS No) >=70 (EC No) (REACH-no) xxxx ammonium dihydrogenorthophosphate (CAS No) >=10 (EC No) (REACH-no) xxxx ammonium sulphate (Impurity) (CAS No) (EC No) magnesium sulphate (Impurity) (CAS No) (EC No) calcium sulphate (Impurity) (CAS No) (EC No) Full text of H-statements: see section Mixtures SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : carbon dioxide (CO2), powder, alcohol-resistant foam. : Strong water jet Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Ammonia. Carbon monoxide. Carbon dioxide (CO2) Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Do not allow into drains or water courses Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. Other information : Dispose of materials or solid residues at an authorized site. 2/13/2017 GB - en 2/7

3 6.4. Reference to other sections Information for safe handling. SECTION 7. Concerning personal protective equipment to use, see section 8. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid dust formation. Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Keep away from any flames or sparking source. Protect from moisture. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials Information about storage in one common storage facility Storage area Packaging materials 7.3. Specific end use(s) : Store in a well-ventilated place. Keep cool. Protect from moisture. Decomposition starting from >70%. : combustible materials. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Keep away from food, drink and animal feeding stuffs. Do not store with: Organic materials. : Store away from heat. Protect from moisture. Material is hygroscopic. : Paper. Polyethylene. Polypropylene. diammonium hydrogenorthophosphate ( ) DNEL/DMEL (Workers) 34.7 mg/kg bodyweight/day Long-term - systemic effects, inhalation 6.1 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 2.1 mg/kg bodyweight/day Long-term - systemic effects, inhalation 1.8 mg/m³ 20.8 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 1.7 PNEC aqua (marine water) 0.17 PNEC (STP) PNEC sewage treatment plant 10 mg/l DNEL/DMEL (Workers) 34.7 mg/kg bodyweight/day Long-term - systemic effects, inhalation 6.1 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 2.1 mg/kg bodyweight/day Long-term - systemic effects, inhalation 1.8 mg/m³ 20.8 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 1.7 mg/l PNEC aqua (marine water) 0.17 mg/l PNEC aqua (intermittent, freshwater) 17 mg/l PNEC (STP) PNEC sewage treatment plant 10 mg/l ammonium sulphate ( ) DNEL/DMEL (Workers) mg/kg bodyweight/day Long-term - systemic effects, inhalation mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 6.4 mg/kg bodyweight/day Long-term - systemic effects, inhalation 1.67 mg/m³ 12.8 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) mg/l PNEC aqua (marine water) mg/l 2/13/2017 GB - en 3/7

4 PNEC (Sediment) PNEC sediment (freshwater) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant 8.2. Exposure controls mg/kg dwt 62.6 mg/kg dwt mg/l Appropriate engineering controls: Ensure good ventilation of the work station. Wash hands before break and at end of works. Avoid dust formation. Hand protection: Chemically resistant protective gloves. EN 374. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Please follow the instructions related to the permeability and the penetration time provided by the manufacturer Eye protection: Chemical goggles Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of inadequate ventilation wear respiratory protection. Particle filter. P1 Environmental exposure controls: Avoid release to the environment. Other information: Do not eat, drink or smoke when using this product. Do not breathe dust. Wash hands before breaks and after work. Avoid contact with skin and eyes. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) : Solid : Granulate. Melting point : 155 C Freezing point Boiling point Flash point Auto-ignition temperature : Grey. Yellow-brown. Black. Various. : none to slight. ammonia odour. : : : Decomposition temperature : > 155 C Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C : Not flammable : Pa Relative density : 1.62 Solubility : Water: > 100 g/l (20 ) Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : : : Product is not explosive. : Non oxidizing. : 2/13/2017 GB - en 4/7

5 9.2. Other information Bulk density Other properties Particles size : 1000 kg/m³ : Material is hygroscopic. : 2mm - 5mm SECTION 10: Stability and reactivity Reactivity No dangerous reactions known. Stable under normal conditions of use Chemical stability Stable under normal conditions. Decomposes when moist. Decomposition starting from >70% Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials alkalis. Strong acids. copper Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. Thermal decomposition generates : Ammonia. Phosphorus oxides. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity diammonium hydrogenorthophosphate ( ) LD50 oral rat > 2000 mg/kg (OECD 425 method) LD50 dermal rat > 5000 mg/kg bodyweight (OECD 402 method) LC50 inhalation rat (mg/l) > 5 mg/l/4h LD50 oral rat > 2000 mg/kg LD50 dermal rat > 5000 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Dust Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general : No known adverse effects on the functioning of water treatment plants under normal use conditions as recommended. Avoid undiluted product to come into sewer or superficial water. diammonium hydrogenorthophosphate ( ) LC50 fish mg/kg (96h; LC50 fish 1) EC50 Daphnia mg/l (24h; EC50 Daphnia 1) EC50 72h algae (1) > 100 mg/l (72h; Selenastrum capricornutum) LC50 fish 1 > 85.9 mg/l Oncorhynchus mykiss (Rainbow trout) EC50 Daphnia mg/l daphnia EC50 72h algae (1) > 97.1 mg/l 2/13/2017 GB - en 5/7

6 12.2. Persistence and degradability ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate ( , ) Persistence and degradability for inorganic substances. Persistence and degradability Bioaccumulative potential Log Pow Log Kow Mobility in soil Results of PBT and vpvb assessment ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate ( , ) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Empty containers should be taken for recycling, recovery or waste in accordance with local regulation. Comply with local regulations for disposal. European List of Waste (LoW) code : sludges from on-site effluent treatment other than those mentioned in SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport 2/13/2017 GB - en 6/7

7 Powered by TCPDF ( DAP Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate is not on the REACH Candidate List ammonium dihydrogenorthophosphate, diammonium hydrogen 2-hydroxypropane-1,2,3-tricarboxylate is not on the REACH Annex XIV List National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Section Changed item Change Comments 7 Additional information Added 9 Additional information Added 10 Additional information Added Abbreviations and acronyms: ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways ADR European Agreement concerning the International Carriage of Dangerous Goods by Road CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DMEL Derived Minimal Effect level DNEL Derived-No Effect Level IATA International Air Transport Association IMDG International Maritime Dangerous Goods PBT Persistent Bioaccumulative Toxic RID Regulations concerning the International Carriage of Dangerous Goods by Rail vpvb Very Persistent and Very Bioaccumulative Department issuing data specification sheet: : KFT Chemieservice GmbH Im Leuschnerpark Griesheim Postfach Griesheim Germany Contact person Phone: Fax: Service: : Barbara Stark This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2/13/2017 GB - en 7/7