specific management SSM Variable rate fertilizer application VRA AB-DTPA 0.5 mol/l NaHCO 3 ICP DOI: /j.cnki.tr

Size: px
Start display at page:

Download "specific management SSM Variable rate fertilizer application VRA AB-DTPA 0.5 mol/l NaHCO 3 ICP DOI: /j.cnki.tr"

Transcription

1 DOI: /j.cnki.tr (Soils), 2004, 36 (3): 243~ (AB-DTPA0.5 mol/l NaHCO mol/l CaCl 2 Kelowna - ) S151.9 [1] N [2] (5 ~ 10 ) Site ICP Mehlich-3 -DTPA specific management SSM Variable rate fertilizer applicationvra [3] mol/l NaHCO 3 N NO - 3 -N NH + 4 -N N P K NH + 4 -N N NO - 3 -N K K Na K 2:1 K 50 AB-DTPA Na K K [4] N [2] NO - 3 -N P K ICP N (KZCX2-404) 2001AA245013

2 N [5] [6] 6 Mehlich-3 [19] Mehlich-3 20:1 K Mehlich-3 Mehlich-1 [13] AB-DTPA AB-DTPA Mehlich-3 1 mol/l NH 4 HCO mol/l DTPA ph=7.6 ph(h 2 O)> mol/l CaCl 2 ph Na Ca [3] P NO - 3 -N K AB-DTPA ph P Bray-1K [20] NO - 3 -N [7] AB-DTPA K NH + 4 -NP K CaCl 2 [8] [6] AB-DTPA P K K K Mehlich-3 NH + 4 -N N NO - 3 -N [9] AB-DTPA P Olsen-PMehlich-3 CaCl 2 P Olsen P [24] P Mehlich-3 CaCl 2 P Olsen-P 0.2 mol/l HOAc-0.25mol/L NH 4 NO mol/l NH 4 F mol/l HNO mol/l EDTA [26] P PK [20,27] Mehlich-3 Bray-1 Mehlich-1 Mehlich-3 P Mehlich-2 [10,11] Bray-1 [12~14] Mehlich-1 [14] Olsen [15] K [20] CaCl 2 K [10~13,16,17] Mehlich-3 P [9] Mehlich-3 K Mehlich-2 [10,11] [12] K [15] Bray mol/l HOAc [14] Mehlich mol/l NH 4 F K [7,10,15] van Lierop [29] EDTA DTPA Qian [30] [13] Mehlich-1 PK [14] Mehlich-3 (, P [18] P K ) [29] mol/l CaCl 2 C N PKNaS [21, 22] [22, 23] Olsen [20] [25] CaCl 2 P 5 Ca P P [24, P 27] CaCl 2 K K [28] 0.01 mol/l CaCl 2 NO - 3 -N

3 mol/l SrCl mol/l [21,26] Sr Ca NO - 3 -NNO - 2 -NPO 3-4 K + ICP AlCa NH 4 NH + 4 -NNO - 3 -NPKCa Mg Mehlich-3 Padarauskas [38] NO - 3 -N NH + 4 -N NH + 4 -N NO - 3 -N 2 mol/l KCl [31] Mehlich-3 15cmol/kg - K [32] - P Olsen Bray-1Mehlich-3 Bray mol/l HCl - P Olsen Mehlich-3 P - Olsen Mehlich-3 3 P P - [33] [21] [37] P [19] [24,34] [39] P 0.01 mol/l CaCl ~ 10 mg/l [40] [35] Zbiral [39] Mehlich-3 Mehlich-3 K 2 % ICP ~ 8 % 0.01 mol/l CaCl 2 K 0.06 ~ 20 mg/l [41] Na Cs NO - 3 -N 0.5 mg/kg [42] NO - 3 -NNO - 2 -N P Cl [43] NO - 3 -N CaCl 2 [44] Coated wire electrodecwe NO - 3 -N (Aliquate 336s)NO - 3 -N [36] A NO - 3 -N P P P [45]

4 Chen [46] NP K P P Co 3 (PO 4 ) 2 ph 1mol/L ~ mol/l K K Na + H + + NH 4 PVC K K ph NH + 4 [47] 0.5 mol/l BaCl 2 K NH + 4 [48] (1) ISFET (2) (3) (4) [49] ISFET (5) long-term drift NPK ICP-AES ISFET (6) ISFET/FIA (Ion-selective field effect transistor/ (7) Flow injection analysis) [50] NO - 3 -N 1.25 s [51] Ca NaKNO N NH 4 Arce [52] - 10 min Skotnikov [53] Automated unit for soil sample preparation and processing AUSSPP

5 Mantylahti [54] h ph McGrath Skotnikov [55] NP K Mantylahti [54] 38 [56, 20 h 57] h 1 Hergert GW. A futuristic view of soil and plant analysis and nutrient recommendations. Commun. Soil Sci. Plant Anal., 1998, 29: 1441 ~ van Raij B. New diagnostic techniques, universal soil extractants. Commun. Soil Sci. Plant Anal., 1994, 25: 799 ~ Jones JB Jr. Universal soil extractants: their composition and use. Commun. Soil Sci. Plant Anal., 1990, 21:1091 ~ Simonis AD. Effect of ph and solvent/soil ration on 5 ~ 10 min extraction of Potassium by various extracting solutions (100 ± 10) compared to neutral molar ammonium acetate. Commun. % Soil Sci. Plant Anal., 1996, 27: 919 ~ Fox RH, Piekielek WP. A rapid method for estimating the Nitrogen-supplying capability of soil.soil Sci. Soc. Am. J.

6 , 42: 751 ~ , Anal., 1992, 23: 2015 ~ , (4): 45 ~ 48 7 Hanlon EA, Johnson GV. Bray/Kurtz, Mehlich III, AB/D ammonium acetate extractions of P, K and Mg in four Oklahoma soils. Commun. Soil Sci. Plant Anal., 1984, 15: 277 ~ Lucena JJ, Bascones I. AB-DTPA cation extraction in Spanish soil samples. Commun. Soil Sci. Plant Anal.,1993, 24: 2427 ~ ,,,. 22 van Erp PJ, Houba VJG, Beusichem MLV. One hundredth., 1988, 20 (5): 247 ~ Zbiral J, Nemec P. Comparison of Mehlich II and Mehlich III extraction for determination of available Phosphorus, Potassium, Magnesium and Calcium in soils of the Czech Republic. Rostlinna Vyroba, 1999, 45 (1):1 ~ 7 11 Zbiral J, Nemec P. Integrating of Mehlich 3 extractant into the Czech soil testing scheme. Commun. Soil Sci. Plant Anal., 2000, 31: 2171 ~ Eckert DJ, Watson ME. Integrating the Mehlich 3 extractant into existing soil test interpretation schemes. Commun. Soil Sci. Plant Anal., 1996, 27: 1237 ~ Mylavarapu RS, Sanchez JF, Nguyen JH, Bartos JM. Evaluation of Mehlich 1 and Mehlich 3 extraction procedures for plant nutrients in acid mineral soils of Florida. Commun. Soil Sci. Plant Anal., 2002, 33: 807 ~ Gartley KL, Sims JT, Olsen CT, Chu P. Comparison of soil test extractants used in mid-atlantic United States. Commun. Soil Sci. Plant Anal., 2002, 35: 873 ~ Schmisek ME, Cihacek LJ, Swenson LJ. Relationships between the Mehlich 3 soil test extraction procedure and standard soil test methods in North Dakota. Commun. Soil Sci. Plant Anal., 1998, 29: 1719 ~ ,. Mehlich 3., 29 van Lierop W, Gouch NA. Extraction of Potassium and 1995, 32 (2): 132 ~ , multiple element extractant. Can. J. Soil Sci., 1989, 69: , (1): 44 ~ Tucker MR, Hight PT. A comparison of the results from three soil testing laboratories using the Mehlich 3 extractant on southeastern coastal plain soils. Commun. Soil Sci. Plant Anal., 1990, 21: 2197 ~ Jones JB Jr, Kalra YP. Soil testing plant analysis activities: The United States and Canada. Commun. Soil Sci. Plant 20 Simonis AD, Setatou HB. Assessment of available Phosphorus and Potassium in soils by the calcium chloride extraction method. Commun. Soil Sci. Plant Anal., 1996, 27: 685 ~ Hylander LD, Svensson H, Siman G. Comparison of different methods for determination of Phosphorus in calcium chloride extracts for prediction of availability to plants. Commun. Soil Sci. Plant Anal., 1995, 26: 913 ~ 925 molar calcium chloride extraction procedure. Part I: A review of soil chemical, analytical, and plant nutritional aspects. Commun. Soil Sci. Plant Anal., 1998, 29: 1603 ~ ,, Houba VJG, Novozamsky I mol/l CaCl 2 N., 1991, 28 (1): 32 ~ 39 24, Madoff FR.., 2003, 40 (1): 140 ~ Humphreys J, Tunner H, Duggan P. Soil Phosphorus determination using three extraction procedures, the effect of sampling depth and comparison of Phosphorus fertilizer recommendations for grassland. Irish Journal of Agricultural and Food Research, 1998, 37: 29 ~ Hylander LD, Svensson H, Siman G. Different methods for determination of plant available soil Phosphorus. Commun. Soil Sci. Plant Anal., 1996, 27: 1501 ~ Fotyma M, Gosek S, Szewezyk M. Preliminary experience with calcium chloride method in Poland. Commun. Soil Sci. Plant Anal., 1996, 27: 1387 ~ Baier I, Baierova V. Hundredth molar calcium chloride extraction procedure. Part IV: Calibration with conventional soil testing methods for Potassium. Commun. Soil Sci. Plant Anal., 1998, 29: 1641 ~ 1648 Sodium from acid and calcareous soils with the Kelowna ~ Qian P, Schoenaru JJ, Karamanos RE. Simultaneous extraction of available P and K with a new soil test: A Modification of Kelowna extraction. Commun. Soil Sci. Plant Anal., 1994, 25: 627 ~ Simard RR, Deschenes M. Strontium chloride - citric acid

7 3 249 extraction procedure for agricultural and environmental purposes. Commun. Soil Sci. Plant Anal., 1992, 23: 2207 ~ Simard RR, Zizka J. Evaluating plant available Potassium with strontium citrate. Commun. Soil Sci. Plant Anal., 1994, 25: 1779 ~ Simard RR, Tran TS, Zizka J. Strontium chloride-citric acid extraction evaluated as a soil-testing procedure for Phosphorus. Soil Sci. Soc. Am. J., 1991, 55: 414 ~ Lin C. Characteristics of Phosphorus in some eastern Australian acid sulfate soils. Pedosphere, 2002, 12(3): 229 ~ Houba VJG, Novazamsky I, van Der Lee JJ. Status and future of soil and plant analysis. Commun. Soil Sci. Plant Anal., 1994, 25: 753 ~ Nieto KF, Frankenberger WT Jr. Single column ion chromatography I. Analysis of inorganic anions in soils. Soil Sci. Soc. Am. J., 1985, 49: 587 ~ Karlson U, Frankenberger WT Jr. Single column ion chromatography III. Determination of orthophosphate in soils. Soil Sci. Soc. Am. J., 1987, 51: 72 ~ Padarauskas A, Olsauskaite V, Paliulionyte V. Simultaneous determination of inorganic anions and cations in waters by capillary electrophoresis. J Chromat. A., 1998, 829: 359 ~ Zbiral J. Analysis of Mehlich III soil extracts by ICP- AES. Rostlinna Vyroba, 2000, 46(4): 141 ~ Novozamsky I, van Dijk D, van Der Lee JJ, Houba VJG. Automated determination of trace amounts of phosphate in soil extracts using malachite green. Commun. Soil Sci. Plant Anal., 1993, 24: 1065 ~ Mazafar A, Oertli JJ, Tuor D, Roesch T. Calibration of ICP to reduce the interference of Na with the determination of K. Commun. Soil Sci. Plant Anal., 1990, 21: 1607 ~ Li S, Smith KA. The rapid determination of nitrate at low concentrations in soil extracts: comparison of ion-selective electrode with continuous-flow analysis. Commun. Soil Sci. Plant Anal., 1984, 15(12): 1437 ~ van Lierop W. Soil nitrate determination using the Kelowna multiple element extractant. Commun. Soil Sci. Plant Anal., 1986, 17: 1311 ~ Munter RC. Advances in soil testing and plant analysis analytical technology. Commun. Soil Sci. Plant Anal., 1990, 21: 1831 ~ Goodroad LL, Shuaman LM. Nitrate-N determination in soils using coated wire electrodes. Commun. Soil Sci. Plant Anal., 1990, 21: 1559 ~ Chen ZL, Adams MA, Grierson P. Direct determination of phosphate in soil extracts by potentiometric flow injection using a Cobalt wire electrode. Ana. Chim. Acta., 1998, 363 (2 ~ 3): 191 ~ Farrell RE, Scott AD. Ion-selective electrode determinations of exchangeable Potassium in soils. Soil Sci. Soc. Am. J., 1987, 51: 594 ~ Wang JJ, Scott.AD. Determination of exchangeable potassium in soil using ion-selective electrodes in soil suspension. European J. Soil Sci., 2001, 52: 143 ~ Birrell SJ, Hummel JW. Membrane selection and ISFET configuration evaluation for soil nitrate sensing. Transactions of the ASAE, 2000, 43(2): 197 ~ Haemmerli A, Janata J, Brown HM. A flow injection system for measurement of chemical response time of micro electrodes. Ana. Chim. Acta., 1982, 144, 115 ~ Birrell SJ, Hummel JW. Real-time multi ISFET/FIA soil analysis system with automatic sample extraction. Computers and Electronics in Agriculture, 2001, 32, 45 ~ Arce L, Rios A, Valcarcel M. Direct multiparametric determination of anions in soil samples by integrating on- line automated extraction/filtering with capillary electrophoresis. Fresenius J Anal Chem., 1998, 360: 697 ~ Skotnikov A. Automated unit for soil sample preparation and processing. Commun. Soil Sci. Plant Anal., 1998, 29: 2015 ~ Mantylahti Y. Automatic soil analysis system in Finland. Commun. Soil Sci. Plant Anal., 1996, 27: 513 ~ McGrath D, Skotnikov A. Possibility of different soil sampling techniques with automated soil sampler. Commun. Soil Sci. Plant Anal., 1996, 27: 1779 ~ :, 2000, 573 ~ ,,,.,, 2003, 34 (5): 483 ~ 488

8 MODERNIZATION OF SOIL NUTRIENT ANALYSIS LI Li-ping ZHANG Jia-bao XING Wei-qin ZHANG Jun XIN Xiu-li ( Institute of Soil Science,Chinese Academy of Sciences, Nanjing ) Abstract Development of agriculture and the need for better environment require more soil samples being analyzed in shorter time for soil nutrient information, as a result, modernization of soil nutrient analysis is the way we must choose. This paper reviewed progress in application of universal extractants (such as AB-DTPA, 0.5 mol/l sodium bicarbonate, 0.01 mol/l calcium chloride, Kelowna, strontium-citric acid solution and water), application of instrumental analysis (such as flow analysis, capillary electrophoresis, liquid chromatography, atomic emission spectrometry and electrode) for soil nutrient analysis, and automation of soil sample collection and analysis in the last 20 years. However, mixing of soil sample and soil moisture determination are still two problems in the automation of soil nutrient analysis. To compromise between the analysis speed and the accuracy is recommended as the solution. Key words Soil nutrient, Analysis, Universal extractant, Instrumental analysis, Automation ************************************************************************************************ :,1993, 217 ~ 239, 1993, 39 ~ 41 4,..,. :. 2001, 22 (4): 216 ~ 219. :, 2001, 35 ~ :,, 2001, 33 (6): 300 ~ : 9,,,., 2001, 7 ~ : 7,, 8,,.,, 2002, 34 (6): 293 ~ 302 PROTECTION AND SUSTAINABLE UTILIZATION OF CULITIVATE LAND RESOURCE IN HUNAN PROVINCE LIU Hai-jun TAN Kun LUO Zun-chang ( Hunan Soil and Fertilizer Research Institute, Changsha ) Abstracts According to the intensified contradiction between population and cultivated land in Hunan Province, the current situation, problems and their causee were analyzed. The countermove and measure adopted to realize sustainable utilization or land resource were put forward in the respects of policy and law, land leveling, management, monitoring and preservation, correlated ecosystem protection, and adjusting of agricultural structure. Key words Culitivate land resource, Protection, Sustainable utilization, Hunan Province