Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Printed Revision ARAL Supralin, selbstmischend

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1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Name of product Manufacturer/distributor Aral AG Wittener Str. 45, D Bochum Internet : Advice Emergency advice Zentr. Kundenbetr./ Umweltschutz/Produktsicherheit Phone +49 (0) Giftnotruf Berlin Phone +49 (0) Recommended intended purpose(s) cleaner 2. HAZARDS IDENTIFICATION Information pertaining to special dangers for human and environment Non hazardous preparation according to Directive 1999/45/EC. 3. COMPOSITION/INFORMATION ON INGREDIENTS Description Aqueous solution Preparation of phosphate, anionic surfactant, complexing agent and solubilizer. Hazardous ingredients CAS No EC No Name [% weight] Classification according to 67/548/EEC Natriumxylolsulphonat 2,5-10 Xi R36/38 4. FIRST AID MEASURES General information Special measures do not occur In case of inhalation In case of illness, seek medical advice. Ensure of fresh air. In case of skin contact In case of contact with skin wash off with water. In case of eye contact In case of contact with eyes rinse thoroughly with plenty of water (at least 15 minutes) and seek medical advice. In case of ingestion Consult physician in the event of continuous problems Rinse out mouth and give plenty of water to drink. Page 1/5

2 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Product does not burn, fire-extinguishing activities according to surrounding. Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases Fire gas of organic material has to be classed invariably as respiratory poison. Special protective equipment for fire-fighters Fire-fighting operations, rescue and clearing work under effect of combustion and smoulder gases just may be done with breathing apparatus. Additional information Cool endangered containers with water spray jet. Fire residues and contaminated firefighting water must be disposed of in accordance with the local regulations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective clothing. Avoid contact with eyes. Environmental precautions Do not let in concentrated form into the drains/surface water/ground water. Methods for cleaning up Take up with absorbent material (e.g. sand, kieselguhr, acid binder, general-purpose binder, sawdust). After taking up the material dispose according to regulation. 7. HANDLING AND STORAGE Advice on safe handling Take the usual precautions when handling with chemicals. Advice on protection against fire and explosion No special measures necessary. Requirements for storage rooms and vessels Keep in closed original container. Further information on storage conditions Keep container tightly closed and store at cool and aired place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional advice on system design Sufficient ventilation and exhaustion. Respiratory protection not necessary Hand protection Glove material specification [make/type, thickness, permeation time/life, wetting resistance]: Nitrile; 0.1 mm; 480 min.; 60min.;for example "DERMATRIL L" from the company KCL, The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN374. The selection of a suitable glove depends and from manufacturer to manufacturer different not only on the material, but also on further quality criteria. The exact breakthrough time of the glove material is to be inquired from the protection glove manufacturer and must be strictly adhered to. Eye protection Eye protector in case of danger of spillage Page 2/5

3 Skin protection not necessary General protective measures Avoid contact with the eyes. Hygiene measures Observe general regulations concerning hygiene at work (see Chapter 15). 9. PHYSICAL AND CHEMICAL PROPERTIES Form liquid Colour colourless Odour Soapy. Important health, safety and environmental information Value Temperature at Method Remark ph value in delivery state 10,5 20 C determinated undiluted boiling point 100 C DIN Flash point Autoignition not applicable The product is not self-igniting. Vapour pressure 23 mbar 20 C Density 1,16 g/cm3 20 C Solubility in water Viscosity Fully miscible adj thin Explosive properties The product is not explosive 10. STABILITY AND REACTIVITY Conditions to avoid No hazardous reactions known. Materials to avoid Reactions with strong oxidising agents. Hazardous decomposition products No hazardous decomposition products known. Thermal decomposition Remark No decomposition if used as directed. Page 3/5

4 11. TOXICOLOGICAL INFORMATION Acute toxicity/irritability/sensitization Value/Validation Species Method Remark Irritability skin Irritability eye Skin sensitization Sensitization respiratory system non-irritant low irritant - no labeling duty non-sensitizing not sensitizing Additional information Other hazardous properties may not be excluded. The product is to be handled with the caution usual with chemicals. 12. ECOLOGICAL INFORMATION Data on elimination (persistence and degradability) Elimination rate Method of analysis Method Validation Biological degradability This product is easily biodegradable Behaviour in sewage plant When low concentrations are discharged correctly into adapted biological sewage treatment plants, interference with the degradation activity of activated sludge is not likely. Additional ecological information Value Method Remark COD 913 mg/l 1% solution. BOD 14 mg/l 1% solution AOX Contains no organically bonded halogen compounds. Contains following heavy metals and compounds of the 76/464/EWG no General regulation Undiluted and/or in larger quantities into the groundwater, in waters or into drains to arrive do not leave. The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. 13. DISPOSAL CONSIDERATIONS Waste code No. Name of waste detergents other than those mentioned in Recommendations for the product There are no harmonised regulations on the disposal of chemicals in the member states of the EU. In Germany, the Recycling and Waste Management Act 8 KrW-/AbfG) stipulates recycling as a requirement. Page 4/5

5 This means that a distinction must be made between "wastes for recycling" and "wastes for disposal". Particular aspects - in the main concerning delivery - are also governed by the Laender. Recommendations for packaging Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken fot reuse. Disposal in accordance with local regulations. Recommended cleansing agent Water, with cleaning agents if necessary. General information Small amounts may be diluted with plenty of water and washed away. Dispose of bigger amounts in accordance with Local Authority requirements. 14. TRANSPORT INFORMATION Land and inland navigation transport ADR/RID No hazardous material as defined by the transport regulations. Marine transport IMDG No hazardous material as defined by the transport regulations Air transport ICAO/IATA-DGR No hazardous material as defined by the transport regulations 15. REGULATORY INFORMATION Remarks for labelling The product does not require a hazard warning label in accordance with EC directives/german regulations on dangerous substances. Special labelling for certain preparations Safety data sheet available for professional user on request. VOC standard VOC content 0 % 16. OTHER INFORMATION Recommendend uses and restrictions National and local regulations concerning chemicals shall be observed. Further information The information contained herein is based on the state of our knowledge. It characterizes the product with regard to the appropriate safety precautions. It does not represent a guarantee of the properties of the product. Please observe the following disclaimer! --- Our safety data sheets have been compiled according to effective EUdirectives, WITHOUT taking into account the special national directives concerning the handling of hazardous substances. Each user is responsible for the implementation of the national special regulations. Wording of the R-phrases specified in chapter 3 (not the classification of the formulation!) R 36/38 Irritating to eyes and skin. Page 5/5