SAFETY DATA SHEET Stainaway no.1

Transcription

1 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Product name Product use Removes stains from textiles left by coffee, tea, cocoa, ketchup, fruit, mustard, jam, red wine, moisture, ink, as well as vegetables and fruit juice, urine, perspiration, curry and various perfumes. Company/undertaking identification Manufacturer HG International b.v. Telephone No. +31 (0) Address Damsluisweg 70 Fax +31 (0) EJ Almere Internet Country Netherlands Importer HG UK Address Unit 11 Grange Way Business Park Whitehall Road Industrial Estate Uk Colchester Essex CO2 8HF 2. Telephone No. Fax Country United Kingdom (UK) Composition/information on ingredients Substance/preparation United Kingdom (UK) Preparation See section 16 for the full text of the R Phrases declared above * Occupational Exposure Limit(s), if available, are listed in Section 8 CAS number EC Number % Classification sodium percarbonate O; R8 Xn; R22 Xi; R41 triphosphoric acid, pentasodium salt Xi; R36/37/38 3. Hazards identification The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification O; 8 Xn; 22 Xi; 41 Physical/chemical hazards Contact with combustible material may cause fire. Human health hazards Harmful if swallowed. Risk of serious damage to eyes. See section 11 for more detailed information on health effects and symptoms. Page 1/6

2 4. First aid measures First aid measures Inhalation Ingestion Skin Contact Eye contact Notes to physician Specific treatments If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Obtain medical attention. In case of contact, immediately flush skin copiously with water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain medical attention immediately. In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Obtain medical attention immediately. See section 11 for more detailed information on health effects and symptoms. 5. Fire-fighting measures Extinguishing media Special exposure hazards Special protective equipment for fire-fighters Use an extinguishing agent suitable for surrounding fires. No specific hazard. Fire fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal Precautions Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Do not touch or walk through spilled material. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, carefully scoop up spilled materials and use a nonsparking or explosion proof means to transfer material to an appropriate container for disposal by incineration. Avoid creating dusty conditions and prevent wind dispersal. Note see section 8 for personal protective equipment and section 13 for waste disposal. 7. Handling and storage Handling Storage Packaging materials Recommended Specific uses Do not ingest. Avoid contact with eyes, skin and clothing. Store in tightly-closed container. Avoid contact with combustible materials. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalis, reducing agents and combustibles. Use original container. Page 2/6

3 8. Exposure controls/personal protection Exposure limit values United Kingdom (UK) Occupational exposure limits 9. Exposure controls Occupational exposure controls Respiratory protection Hand protection Eye protection Skin protection Product does not contain relevant quantities of materials with exposure values that have to be monitored. Use local exhaust ventilation or handle in a ventilated enclosure. RecommendedA respirator is not needed under normal and intended conditions of product use. Chemical-resistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hour(s) (breakthrough time) Butyl rubber gloves. splash goggles Work uniform or laboratory coat. Physical and chemical properties General information Appearance Physical state Colour Odour ph Flash point Flammability (solid, gas) Explosive properties Oxidising properties Relative density Solubility Solid. (Powder) White. Odourless. Important health, safety and environmental information Melting point Boiling point Other information (Conc. (% w/w) 1) [Basic.] >1000 C (1832 F) based on data for silicic acid, magnesium salt. Weighted average C ( F) Not applicable. Not applicable. Applicable. Stability and reactivity 0.93 g/cm3 (20 C / 68 F) Easily soluble in hot water. Soluble in cold water. Stability Conditions to Avoid Materials to avoid The product is stable. Not stable under influence of light. moisture Vermijd bewaring bij hoge temperatuur (bv. auto in de zon) Reactive with metals. Page 3/6

4 11. Toxicological information Potential acute health effects Inhalation Ingestion Skin Contact Eye contact Acute toxicity sodium percarbonate triphosphoric acid, pentasodium salt Harmful if swallowed. Severely irritating to eyes. Test Result Route Species 1034 mg/kg 2200 mg/kg >2000 mg/kg Dermal Rat Mouse Rabbit 3120 mg/kg 3100 mg/kg >4640 mg/kg Dermal Rat Mouse Rabbit Carcinogenicity Mutagenicity Reproductive toxicity Over-exposure signs/symptoms 12. Inhalation Ingestion Skin Other adverse effects Ecological information Ecotoxicity data sodium percarbonate Other adverse effects 13. Disposal considerations Species Period Result Fish (LC50) 96 hour(s) 70.7 mg/l Daphnia (EC50) 48 hour(s) 4.9 mg/l Methods of disposal Waste classification Hazardous waste The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Not applicable. The classification of the product may meet the criteria for a hazardous waste Page 4/6

5 14. Transport information International transport regulations Regulatory information ADR/RID Class UN number Proper shipping name Class Packing group Label Additional Information UN, "dangerous goods in limited quantities of class ", III, ADR III Hazard identification number 50 Reportable quantity 30 Remarks Dangerous goods in limited quantities ADN Class UN, "dangerous goods in limited quantities of class ", III, ADNR III Remarks Dangerous goods in limited quantities IMDG Class "dangerous goods in limited quantities of class " UN, PG III III Emergency schedules (EmS) F-A, S-Q Remarks Dangerous goods in limited quantities IATA-DGR Class "dangerous goods in limited quantities of class " UN, PG III III Regulatory information EU Regulations Hazard symbol(s) Risk Phrases Safety Phrases Oxidising, Harmful R8- Contact with combustible material may cause fire. R22- Harmful if swallowed. R41- Risk of serious damage to eyes. S2- Keep out of the reach of children. S13- Keep away from food, drink and animal feeding stuffs. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37- Wear suitable gloves. S46- If swallowed, seek medical advice immediately and show this container or label. S64- If swallowed, rinse mouth with water (only if the person is conscious). Page 5/6

6 Contains Other EU regulations Product use Other EU regulations Tactile warning of danger EC Statistical classification (Tariff Code) sodium percarbonate Classification and labelling have been performed according to EU directives 67/548/EEC, 1999/45/EC, including amendments and the intended use. - Consumer applications. Yes, applicable Ingredients identification information 30% and more oxygen-based bleaching agents. 5% or over but less than 15% phosphates;optical brighteners. 16. Other information Full text of R phrases referred to in sections 2 and 3 - United Kingdom (UK) Full text of classifications referred to in sections 2 and 3 - United Kingdom (UK) History Date of printing Version Verified by T. Rutgers. R8- Contact with combustible material may cause fire. R22- Harmful if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. R41- Risk of serious damage to eyes. O - Oxidising Xn - Harmful Xi - Irritant Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version 5.05 Page 6/6