MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SARET IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY Product name: Saret 517 Product Label Name: 1,3-diphenylguanidine Intended Use preparations and compounds; [PROC8b] Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities; [ERC11a] Wide dispersive indoor use of long-life articles and materials with low release; [AC10] Rubber articles; preparations and compounds; [PROC14] Production of preparations or articles by tabletting, compression, extrusion, pelletisation; [ERC2] Formulation of preparations; [AC10] Rubber articles; preparations and compounds; [PROC8a] Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities; [ERC10b] Wide dispersive outdoor use of long-life articles and materials with high or intended release (including abrasive processing); [AC10] Rubber articles; preparations and compounds; [PROC4] Use in batch and other process (synthesis) where opportunity for exposure arises; [ERC2] Formulation of preparations; [AC10] Rubber articles; preparations and compounds; [PROC5] Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant 1 of 6

2 Supplier contact); [ERC6d] Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers; [AC10] Rubber articles; preparations and compounds; [PROC9] Transfer of substance or preparation into small containers (dedicated filling line, including weighing); [ERC2] Formulation of preparations; [AC10] Rubber articles; Castle Chemicals Ltd, Peak House 6 Oxford Road, Altrincham, Cheshire WA14 2DY Tel: Fax: Info@castlechemicals.com 2. HAZARD IDENTIFICATION Classification 67/548/EEC N; R51/53 Main Hazards Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Classification EC 1272/2008 Aquatic Chronic 2: H411; Hazard Statement Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects. Precautionary Statement: Prevention P273 - Avoid release to the environment. Precautionary Statement: Response P391 - Collect spillage. Precautionary Statement: Disposal P501 - Dispose of contents/container to Other hazards 3. COMPOSITION INFORMATION ON INGREDIENTS Substances; 67/548/EEC / 1999/45/EC Chemical Name Index No. CAS No. EINECS No. Conc. (%w/w) Classification TRIMETHACRYLATE % N; R51/53 EC 1272/2008 Chemical Name Index No. CAS No. EINECS No. Conc. (%w/w) Classification TRIMETHACRYLATE % Aquatic Chronic 2: H411; 2 of 6

3 4. FIRST AID MEASURES Inhalation Eye contact Skin contact Ingestion Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Indication of any immediate medical attention and special treatment needed Inhalation Eye contact Skin contact Ingestion 5. FIREFIGHTING MEASURES Extinguishing media Special hazards arising from the substance or mixture Advice for firefighters Carbon dioxide (CO2). Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and material for containment and cleaning up Ensure adequate ventilation of the working area. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. 3 of 6

4 7. HANDLING AND STORAGE Precautions for safe handling Conditions for safe storage, including any incompatibilities Specific end use(s) Suitable packaging Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Adopt best manual handling considerations when handling, carrying and dispensing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure controls Appropriate engineering controls Ensure adequate ventilation of the working area. Eye / face protection Approved safety goggles. Skin protection / Hand protection Chemical resistant gloves (PVC). Respiratory protection Wear:. Suitable respiratory equipment. 9. PHYSICAL AND CHEMICAL PROPERTIES State Colour Odour Flash point Vapour pressure Vapour density Water solubility Autoignition temperature Solubility Liquid Yellow Characteristic 130 o C Pa g/cmñ 20.1 g/cmñ 360 o C Soluble in water 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of haz. Reactions Conditions to avoid Incompatible materials Hazardous decomp. Products Stable under normal conditions. 11. TOXICOLOGICAL INFORMATION Toxicological Information TRIMETHACRYLATE Dermal Rat LD50 = > 2000 mg/kg Oral Rat LD50 = > 2000 mg/kg 4 of 6

5 12. ECOLOGICAL INFORMATION Toxicity TRIMETHACRYLATE Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Daphnia EC50/48h = 9.22 mg/l Algae IC50/72h = mg/l Fish LC50/96h = 2 mg/l Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS General information Dispose of in compliance with all local and national regulations. 14. TRANSPORT INFORMATION UN number UN proper shipping name Transport hazard class(es) ADR/RID 9 IMDG 9 Subsidiary risk - IATA 9 Subsidiary risk - Packing group Environmental hazards Marine pollutant Special precautions for user UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( TRIMETHACRYLATE) III Yes Yes Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Further information The product is not classifed as dangerous for carriage. ADR/RID Hazard ID 90 Tunnel Category E IMDG EmS Code F-A S-F IATA Packing Instruction (Cargo) 914 Maximum quantity 450 L Packing Instruction (Passenger) 914 Maximum quantity 450 L 5 of 6

6 15. REGULATORY INFORMATION Regulations COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. REGULATION (EC) No 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. 16. OTHER INFORMATION Other information Text of risk phrases in Section 3 Text of Hazard Statements in Section 3 Further information R51/53 - Toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment. Aquatic Chronic 2: H411 - Toxic to aquatic life with long lasting effects. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. MSDS DOCUMENT NO: SARET 517 ISSUE: 1 ISSUE DATE: of 6