: Ninety-Plus. SECTION 1: Identification. SECTION 2: Hazard(s) identification. SECTION 3: Composition/information on ingredients. 1.1.

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Product name Ninety-Plus Date of issue: 05/07/2015 Supersedes: 04/12/2014 Version: 1.0 : Mixture : Ninety-Plus 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet MarVista Resources 745 North Ave. Corcoran, Ca USA T Emergency telephone number Emergency number SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Acute toxicity (oral) Category 4 Serious eye damage/eye irritation Category 2B H302 H320 Full text of H statements : see section Label elements GHS-US labeling Hazard pictograms (GHS-US) : : Adjuvant, Spreader, Sticker : 24 Hour Emergency HAZMAT Response: (800) : EPA National Response Center: (800) Signal word (GHS-US) Contains Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : : H302 - Harmful if swallowed H320 - Causes eye irritation : P264 - Wash face, clothing thoroughly after handling P270 - Do not eat, drink or smoke when using this product P301+P312 - If swallowed: Call a doctor if you feel unwell P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P330 - Rinse mouth P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 01/11/2016 EN (English US) Page 1

2 Name Product identifier % Classification (GHS-US) * (CAS No) Trade Secret Eye Irrit. 2B, H320 Aquatic Chronic 2, H411 * (CAS No) Trade Secret 3-20 Acute Tox. 4 (Inhalation:dust,mist), H332 Eye Irrit. 2B, H320 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Irritation of the respiratory tract. Symptoms/injuries after skin contact : May cause moderate irritation. Symptoms/injuries after eye contact : mild eye irritation. Symptoms/injuries after ingestion : Irritation of the gastric/intestinal mucosa. Irritation of the oral mucous membranes. Chronic symptoms : Cracking of the skin. Dry skin. Itching Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide Special hazards arising from the substance or mixture Explosion hazard :. Reactivity : The product is non-reactive under normal conditions of use, storage and transport Advice for firefighters Firefighting instructions Protection during firefighting : In case of fire: Stop leak if safe to do so. Avoid (reject) fire-fighting water to enter environment. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8 Exposure controls/personal protection" " Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment : Collect spillage. Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 8 : Exposure-controls/personal protection"". 01/11/2016 EN (English US) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Special rules on packaging : Store in a well-ventilated place. Keep cool. : Oxidizing agent. : Store in a closed container. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : Ensure good ventilation of the work station. : Protective gloves. : Safety glasses. : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Yellow liquid. Color : Amber Odor : mild Odor threshold ph : % Emulsion ph solution : 10 % Melting point : < C Freezing point : < 24 F Boiling point : > 218 F Flash point : Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Specific gravity / density : 1 g/ml Solubility : Insoluble in water. Log Pow Auto-ignition temperature Decomposition temperature 01/11/2016 EN (English US) 3/6

4 Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials strong acids. Strong bases. Oxidizing agent Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Ninety-Plus ATE US (oral) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (gases) : Oral: Harmful if swallowed mg/kg body weight mg/kg mg/kg 1.15 ppm/4h mg/kg body weight mg/kg body weight ppmv/4h LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (ppm) 0 ATE US (gases) ppmv/4h ATE US (dust, mist) mg/l/4h Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity ph: % Emulsion : Causes eye irritation. ph: % Emulsion IARC group Reproductive toxicity Specific target organ toxicity (single exposure) 3 - Not Classifiable 01/11/2016 EN (English US) 4/6

5 Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion Chronic symptoms SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 Threshold limit algae 1 LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) : Irritation of the respiratory tract. : May cause moderate irritation. : mild eye irritation. : Irritation of the gastric/intestinal mucosa. Irritation of the oral mucous membranes. : Cracking of the skin. Dry skin. Itching. : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 5 mg/l (96 h; Gasterosteus aculeatus; Intermittent flow) >= 9-21 mg/l 48 h 500 mg/l (Selenastrum capricornutum; Chronic) 7 mg/l (96 h; Leuciscus idus) 500 mg/l (Selenastrum capricornutum; Cell numbers) 1-10 mg/l Similar material mg/l 48 h similar material 1-10 mg/l Persistence and degradability Persistence and degradability Not readily biodegradable in water Bioaccumulative potential BCF fish 1 0 (5.9-48) Log Pow > 4 BCF fish 1 Not Estabilished Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations Waste disposal recommendations SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport TDG : Prevent liquid from entering sewers, watercourses, underground or low areas. : Avoid release to the environment. Recycle/reuse. Use appropriate containment to avoid environmental contamination. 01/11/2016 EN (English US) 5/6

6 Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations Ninety-Plus SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e., Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)) Listed on the United States TSCA (Toxic Substances Control Act) inventory EPA TSCA Regulatory Flag P - P - indicates a commenced PMN substance XU - XU - indicates a substance exempt from reporting under the Inventory Update Reporting Rule, i.e., Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(C)) International regulations CANADA EU-Regulations National regulations US State regulations SECTION 16: Other information Full text of H-phrases: H302 Harmful if swallowed H320 Causes eye irritation H332 Harmful if inhaled H401 Toxic to aquatic life H411 Toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) All information contained in this is furnished free of charge and is intended for your evaluation. In our opinion the information is, as of the date of this, reliable, however, it is your responsibility to determiine the suitability of the information for your use. You are advised not to construe the information as absolutely complete since additonal information may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or government regulations. Therefore, you should use this information only as a supplement to other informations gathered by you, and you must make independent determinations of the suitability and completeness of the information from all souces to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee is expressed or implied as to the results to be obtained based upon your use of the information. 01/11/2016 EN (English US) 6/6