: Calcium Ammonium Nitrate white

Transcription

1 Date of issue: 8/7/2017 Revision date: 8/7/2017 Supersedes: 7/17/2014 Version: 2.00 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Calcium Ammonium Nitrate white Article number : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use of the substance/mixture : Fertilizer Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier EuroChem Agro GmbH Reichskanzler-Müller-Str Mannheim - Germany T F info.europe@eurochemgroup.com competent person sds@kft.de 1.4. Emergency telephone number Emergency number : National Response Center (international) TUIS-Emergency number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display EUH-statements : EUH210 - Safety data sheet available on request 2.3. Other hazards This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Comments : Fertilizer 8/7/2017 GB - en 1/7

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] ammonium nitrate (CAS-No.) (EC-No.) (REACH-no) xxxx Specific concentration limits: >=60-<80 Ox. Sol. 3, H272 Eye Irrit. 2, H319 Name Product identifier Specific concentration limits ammonium nitrate (CAS-No.) (EC-No.) (REACH-no) xxxx Full text of H-statements: see section 16 (C >= 80) Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Get medical advice/attention if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. : Carbon dioxide. extinguishing powder. Foam Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Carbon monoxide. Carbon dioxide (CO2). Ammonia. Nitrogen oxides Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment. Do not allow into drains or water courses Methods and material for containment and cleaning up Methods for cleaning up Other information : Mechanically recover the product. : Dispose of materials or solid residues at an authorized site Reference to other sections Information for safe handling. See section 7. Concerning personal protective equipment to use, see section 8. For further information refer to section 13. 8/7/2017 GB - en 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Do not eat, drink or smoke when using this product. Avoid dust formation. Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Keep away from any flames or sparking source. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions Information about storage in one common storage facility Storage area 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Store in a well-ventilated place. Keep cool. : Keep away from food, drink and animal feeding stuffs. Do not store with: Organic materials. : Protect from moisture. Store away from heat. ammonium nitrate ( ) DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - systemic effects, inhalation DNEL/DMEL (General population) Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC aqua (intermittent, freshwater) PNEC (STP) PNEC sewage treatment plant 5.12 mg/kg bodyweight/day 36 mg/m³ 2.56 mg/kg bodyweight/day 8.9 mg/m³ 2.56 mg/kg bodyweight/day 0.45 mg/l mg/l 4.5 mg/l 18 mg/l 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Wash hands before break and at end of works. Avoid dust formation. Hand protection: EN 374. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Nitrile rubber. Butyl rubber. Chloroprene rubber. Chemically resistant protective gloves Eye protection: Chemical goggles Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Dust production: dust mask with filter type P1 8/7/2017 GB - en 3/7

4 Environmental exposure controls: Avoid release to the environment. Other information: Do not eat, drink or smoke when using this product. Do not breathe dust. Wash hands before breaks and after work. Avoid contact with skin and eyes. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold : Solid : Granulate. : white. : none to slight. ph : 7 (100g/l; 20 ) Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature : : : Decomposition temperature : > 170 C Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : : Soluble. Water: Soluble : : Product is not explosive. : Non oxidizing. : 9.2. Other information Bulk density : 1000 kg/m³ SECTION 10: Stability and reactivity Reactivity No dangerous reactions known. Stable under normal conditions of use Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Organic materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. 8/7/2017 GB - en 4/7

5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) ammonium nitrate ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard 2950 mg/kg > 5000 mg/kg > 88.8 mg/l/4h ph: 7 (100g/l; 20 ) ph: 7 (100g/l; 20 ) SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity ammonium nitrate ( ) EC50 Daphnia 1 EC50 other aquatic organisms 1 EC50 72h algae (1) > 490 mg/l (48h; EC50 (Daphnia Magna)) 447 mg/l (48h; Cyprinus carpio (Common carp)) 1700 mg/l (10 d; algae) Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Calcium Ammonium Nitrate white This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations European List of Waste (LoW) code : Do not dispose of with domestic waste. Comply with local regulations for disposal. : * - agrochemical waste containing dangerous substances 8/7/2017 GB - en 5/7

6 SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: according to Regulation (EC) No. 453/2010. Abbreviations and acronyms: ADN ADR European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways European Agreement concerning the International Carriage of Dangerous Goods by Road CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008 DMEL Derived Minimal Effect level 8/7/2017 GB - en 6/7

7 Powered by TCPDF ( Calcium Ammonium Nitrate white DNEL IATA IMDG RID EC50 LC50 LD50 PNEC PBT vpvb Derived-No Effect Level International Air Transport Association International Maritime Dangerous Goods Regulations concerning the International Carriage of Dangerous Goods by Rail Median effective concentration Median lethal concentration Median lethal dose Predicted No-Effect Concentration Persistent Bioaccumulative Toxic Very Persistent and Very Bioaccumulative Data sources Department issuing data specification sheet: Contact person : Information provided by the manufacturer. : KFT Chemieservice GmbH Im Leuschnerpark Griesheim Postfach Griesheim Germany Phone: Fax: Service: : Barbara Stark Full text of H- and EUH-statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Ox. Sol. 3 Oxidising Solids, Category 3 H272 May intensify fire; oxidiser H319 Causes serious eye irritation EUH210 Safety data sheet available on request KFT SDS EU 11 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 8/7/2017 GB - en 7/7