Sustainable Solutions

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1 thyssenkrupp Industrial Solutions Sustainable Solutions June 27th 2018 Dr. Uwe Boltersdorf & Dr. Reinhold Achatz thyssenkrupp Industrial Solutions

2 2 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz 140 years of experience in coke plant technologies thyssenkrupp Industrial Solutions Coke Plant Technologies Sustainability Krupp Uhde Krupp Chemieanlagenbau 1961 Coke Oven Plants Division of Krupp Uhde Krupp Koppers 1974 Heinrich Koppers 1901 Uhde GmbH 2004 ThyssenKrupp EnCoke 1999 Takeover of Dr. C. Otto Dr. C. Otto & Comp Thyssen Still Otto Anlagentechnik 1993 Still Otto 1985 Firma Carl Still 1898 Didier OFU 1989 Didier Werke 1911 Develop innovative technologies for an environmentally friendly industry Maximizing yields on raw material, minimizing environmental impact Innovation Utilization of long-term experience and global cross-industry network allows for broad expertise to focus on integrated concepts to increase efficiency and operability Digitization of production process to further increase efficiency The pioneers

3 thyssenkrupp: utilizing coal as valuable raw material to various industries thyssenkrupp Industrial Solutions 3 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Product Integration Environmental Services Valuable Products OXISULF Cyclasulf Monoclaus CO 2 removal EnviBat Morphysorb Jet Loop Reactor Coke H 2 N 2 Sulfur Sulfuric Acid Ammonium sulfate Ammonia Ammonium Bi-Carbonate and many other technologies Crude Tar Aromatics (BTX) Energy Integration

4 4 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz sustainability: compliance with future regulations NOx reduction Compliance with NO x regulations Past years have shown high pressure on emission limits including continuously decreasing NO x limits NO x limits may decrease from 150mg to < 100mg (-33%) CAPEX optimization Optimal process parameters lead to minimum number of ovens per battery fulfill regulatory limits and decrease CAPEX

5 5 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz sustainability: efficient use of all available resources Vertical Chamber Oven covers a broader spectrum of applicable coal-types including: sub-bituminous coals brown coal/lignite s lean coals and anthracite s Acts on decrease in supply of good coking coal (for natural, technical, economical reasons) Alternative to thermal usage of coal Extension of applicable raw materials (coal)

6 6 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Digitization: next level of productivity targeted Automatic Coke Surface Temperature Measurement Heating-Flue Temperature Measurement Charging Car Coordination Automatic Chamber Wall Temperature Measurement Pushing Force Measurement As of today: Digitization Various automation systems available Model based training and simulation available Process optimization available Coke Guide Car Coordination Pusher Machine Coordination Combining engineering data with real time operation data Visualization of process conditions that noone can measure Automatic Battery Heating and Combustion Control Imagine a Digital Twin available short term

7 7 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Coke oven gas a source for platform molecules for different industries CO 2 Sulfur applications H2 Tar processing CO 2 removal Claus Units Sulfuric acid Hydrogen with different purities possible Pitches Light oils and aromatics Ammonia sulfate Methanol Fertilizers Gasoline Lighthouse project Carbon2Chem thyssenkrupp s aspiration: emission free plants and enabling integrated value chains

8 Carbon2Chem thyssenkrupp Industrial Solutions 8 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz

9 9 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Carbon2Chem Recycling of top gases from steel production through cross-industry collaboration Replacement of fossil fuels (oil and gas) for the production of artificial fuels, plastics and fertilizer Chemical Plant Fuel Plastics Fertilizer Water Electrolysis Methanol Synthesis Steel Production Renewable Energy Funded by Process Control Power Plant Coke Plant Blast Furnace Steel Making

10 10 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Carbon2Chem : Transform top gases into chemical products Replacement of fossil fuels (oil and gas) for the production of artificial fuels, plastics and fertilizer Feedstock Process Synthesis gas Chemical processes Products Methanol MTO Polymers Gas cleaning N 2 MTG Gasoline Gas separation Synthesi s gas CO 2 +H 2 Ammonia Fischer- Tropsch Urea Fertilizer Gasoline Lubricants Gas conditioning CO- Conversion Hydrogen Gas treatment has to be developed Syntheses must be adapted for new synthesis gas Methanation SNG

11 11 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Carbon2Chem The project and the partners L0 System Integration Carbon2Chem Labor Technikum Water electrolysis / network stability Sustainable methanol production Gas cleaning / catalysis Higher alcohols / polyalcohols Polymers OME L1 L2 L3 L4 L5 L6 MPI-CEC Umsicht Siemens ZBT (University Duisburg- Essen) ISE MPI-CEC RUB Umsicht Clariant thyssenkrupp RUB MPI-CEC Umsicht Clariant thyssenkrupp RUB RWTH-ITMC Umsicht thyssenkrupp MPI-CEC MPI-KOFO RWTH-ITMC RWTH-LTT RWTH-AVT RWTH-CAT Umsicht KIT-IKFT TU KL VW Eni Linde thyssenkrupp

12 12 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Carbon2Chem : From idea to commercial implementation Research in Carbon2Chem Carbon2Chem Pilot plant Commercial implementation Basics / Lab phase IP is created (closed level) Transfer Ideas to the pilot plant Operating experience Phase I: Proof of concept Start: 2015 End: 2020 Contribution to the commercial implementation Phase II: Industrial scale-up Start: from 2020 Industrial commercialization Start: from 2030

13 Carbon2Chem Pilot Plant (Technikum) thyssenkrupp Industrial Solutions 13 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz

14 Carbon2Chem Water Electrolysis - 2 MW thyssenkrupp Industrial Solutions 14 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz

15 15 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Modeling, Simulation and Analytics Modern IT-Technologies ensure performance Conceptual Design Model Simulation results based on Conceptual Design Model

16 16 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz Carbon2Chem - Technology modules can be offered for other CO 2 intense industries as well Carbon Example: capture Industrial and Solutions utilization (CCU) for cement production CO 2 Recycling Oxyfuel technology Fuel Clinker (pre-stage cement) Plastics Fertilizer Oxyfuel technology can be combined with any kind of modern cement production technology Cement production thyssenkrupp s outstanding position in cement production technology is a key lever for Oxyfuel technology roll-out

17 Q&A thyssenkrupp Industrial Solutions 17 June 27 th 2018 Sustainable solutions Boltersdorf/Achatz