Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein. Helioseal Clear. Light-curing fissure sealant

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1 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 1 of 5 Company Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein Commercial product name and supplier Commercial product name / Designation Application / Use Producer Supplier TOX emergency number Light-curing fissure sealant Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Fürstentum Liechtenstein Emergency-Call: +423 / or Ivoclar Vivadent AG, FL-9494 Schaan, Liechtenstein Composition Chemical characterization Hazardous components CAS No CAS No Mixture of Bis-GMA, dimethacrylate, initiators and stabilizers < 60 % Bis-GMA Xi: Irritant. R36: Irritating to eyes. R38: Irritating to skin. < 40 % Triethylene glycoldimethacrylate Xi: Irritant. R36/37/38: Irritating to eyes, respiratory system and skin. 3 Hazards identification Uncured material may cause slight, reversible irritation. Avoid contact with skin, mucous membrane, and eyes. The material is contraindicated if a person is known to be allergic to any of the ingredients of the product First aid measures Eye contact Skin contact Ingestion Inhalation Flush with plenty of water. Consult a physician if irritation persists. Wash thoroughly with soap and water. No hazards anticipated from swallowing small amounts incidentally to normal handling. Remove to fresh air. If you feel unwell, seek medical advice (show this safety data sheet) Fire-fighting measures Suitable extinguishing media Water fog, carbon dioxide, foam, dry chemicals.

2 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 2 of Extinguishing media to avoid None known 6 Accidental release measures Clean up mechanically. Dispose of according to local and national regulations Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Only adequately trained personnel should handle this product. Keep out of reach of children. Usual hygienic measures for dental practice. When using, do not eat, drink or smoke. Store at 2-28 C / F Avoid exposure to light. Not required. 8 Exposure controls / Personal protection Technical measures Control of threshold limits Personal protective equipment Respiratory protection Hand protection Eye protection Other Good general ventilation should be sufficient. None established. Respiratory Protection. Gloves. Safety goggles Physical and chemical properties Appearance Colour liquid transparent 9.3 Odour Practically odourless 9.4 Change of physical state Test method: 9.5 Density 1.14 g/cm³ (20 C) Vapour pressure Viscosity not determined

3 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 3 of Solubility Solubility in < 0.1 % 9.9 ph not determined Flash point Ignition temperature Explosion limits > 200 C 9.13 not determined Lower: Upper: Stability and reactivity Thermal decomposition None, if used in accordance to instructions Hazardous decomposition products None under normal conditions of storage and use Hazardous reactions Avoid exposure of product to light Toxicological information Acute toxicity Subacute / Chronic toxicity Oral LD50 for rats: > 5000 mg/kg Uncured material: prolonged or frequently repeated skin contact may cause allergic skin reactions in some individuals In the aqueous medium formation of insoluble and chemically inert polyureas will occur. 12 Ecological information No ecological problems to be anticipated if properly handled and used. nearly insoluble 13 Disposal considerations Take to a waste incineration plant, under conditions approved by the local authority EU waste key Transport information 14.1 Transport at land ADR RID

4 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 4 of 5 UN Number Kemler Number Proper shipping name 14.2 Transport at sea ADNR IMDG UN Number EMS MFAG Proper shipping name 14.3 Air transport ICAO / IATA-DGR UN Number Proper shipping name Passenger airplane Cargo Airplane Subsidiary Risk Labels Packing Instructions max. Packing Instructions max Product is not classified for any mode of transportation Regulatory information UN number National regulations The product is a medical device according to the EC-directive 93/42. This product does not require classification according to the criteria of the EC EU number Hazard symbols Hazard designation 15.6 Risk phrases 15.7 Safety phrases 15.8 MAK value ml/m³ (ppm) 15.9 BVD classification (CH) VbF (D)

5 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 5 of 5 16 Other information Version: 3 Changes: 2.2 / 13.1 The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-4104 Oberwil, Switzerland 91/155/EEC

6 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 1 of 5 Company Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Principality of Liechtenstein Commercial product name and supplier Commercial product name / Designation Application / Use Producer Supplier TOX emergency number Etching gel Ivoclar Vivadent AG, Bendererstrasse 2, FL Schaan Fürstentum Liechtenstein Emergency-Call: +423 / or Ivoclar Vivadent AG, FL-9494 Schaan, Liechtenstein Composition Chemical characterization Hazardous components CAS No Phosphoric acid - Gel 37 % Phosphoric acid, Solution in Water C: Corrosive. R34: Causes burns. 3 Hazards identification Corrosive First aid measures Eye contact Skin contact Ingestion Inhalation Consult a physician or transport to emergency facility immediately. Wash thoroughly with soap and water. After ingestion call a physician immediately and show this safety data sheet. Do not induce vomiting. Give large amounts of water. Remove to fresh air. If respiratory irritation is experienced, call a physician. Remove contaminated clothing Fire-fighting measures Suitable extinguishing media Extinguishing media to avoid Non-combustible product. Not required since not combustible. Cool containers in the vicinity of the blaze using a water spray.

7 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 2 of 5 6 Accidental release measures Clean up with absorbent material. Dispose of according to local and national regulations. Clean area with large amounts of water. Prevent skin and eye contact Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Only adequately trained personnel should handle this product. Use only in a well ventilated area. Usual hygienic measures for dental practice. Practice care and caution to avoid skin and eye contact. Keep out of reach of children. Store at 2-28 C / F Cool storage of (2-8 C / F) is indicated for larger stock. Do not store in open sunshine. Keep away from heat source. Not combustible. 8 Exposure controls / Personal protection Technical measures Control of threshold limits Personal protective equipment Respiratory protection Hand protection Eye protection Other Use only with adequate ventilation. MAK-Value = TLV (USA): 1 mg/m3 Respiratory Protection. Rubber gloves. Eye wash fountain should be located in immediate work area. Safety goggles or face-shield. Remove contaminated clothing immediately, wash skin area with water, and launder clothing Physical and chemical properties Appearance Colour liquid blue 9.3 Odour Practically odourless 9.4 Change of physical state Test method: Density Vapour pressure not determined

8 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 3 of Viscosity Solubility Solubility in not known soluble 9.9 ph < Flash point Ignition temperature Explosion limits 9.13 not flammable Lower: Upper: Stability and reactivity Thermal decomposition None, if used in accordance to instructions Hazardous decomposition products None under normal conditions of storage and use Hazardous reactions Avoid excessive heat and direct sunlight Toxicological information Acute toxicity Subacute / Chronic toxicity May cause severe eye irritation. Eye Contact: (see 4.1., First aid measures). Ingestion may cause burns of mouth and throat. Oral LD50 for rats: 4135 mg/kg Due to the ph of this material, it is assumed that exposure will cause skin burns. not known Ecological information The product must not enter effluent, ground water, surface water or the soil. German "Wassergefaehrdungs Klasse (WGK)": 1

9 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 4 of 5 13 Disposal considerations Take to a special waste incineration plant, in line with local regulations EU waste key Transport information 14.1 Transport at land ADR 8 RID 8 UN Number 1805 Kemler Number Proper shipping name III Phosphoric acid, liquid 14.2 Transport at sea ADNR 8 IMDG UN Number 1805 EMS F-A, S-B MFAG 700 III Proper shipping name Phosophorsäure, flüssig 14.3 Air transport ICAO / IATA-DGR Klasse 8 UN Number 1805 Proper shipping name Phosphoric acid, solution Passenger airplane Cargo Airplane Subsidiary Risk Labels Corrosive III Packing Instructions 819 max. 5 L Packing Instructions 821 max. 60 L 14.4 Sample shipment not allowed by mail Regulatory information UN number 1805 National regulations The product is a medical device according to the EC-directive 93/42. This product requires classification according to the criteria of the EC EU number Hazard symbols C

10 Date of issue / Reference hot Replaces version of Date of printing Sheet No Page 5 of Hazard designation C: Corrosive. Contains Phosphoric acid, Solution in Water Risk phrases Safety phrases R: 34 Causes burns MAK value 1 mg/m3 ml/m³ (ppm) 15.9 BVD classification (CH) VbF (D) Other information Version: 3 Changes: 13.1 / S: /2-37/39 2 Keep out of the reach of children. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advise. 45 In case of accident or if you feel unwell, seek medical advise immeditely (show the label where possible). 1/2 Keep locked up and out of reach of children. 37/39 Wear suitable gloves and eye/face protection. The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-4104 Oberwil, Switzerland 91/155/EEC