Safety Data Sheet in compliance with Indian Manufacture, Storage and Import of Hazardous Chemicals Rules 1989, Rule 17, Schedule 9

Transcription

1 Safety Data Sheet in compliance with Indian Manufacture, Storage and Import of Hazardous Chemicals Rules 1989, Rule 17, Schedule 9 Page 1 of 5 MSDS-No. : Revision: printing date: Identification of the substance/preparation and of the company/undertaking Product name: Material: Product category: Release agent Identification of manufacturer, importer or distributor Importer: Henkel Adhesives Technologies India Pvt. Ltd. D3/D4, MIDC, Jejuri India. TEL : / 18 FAX : , Website : Emergency information: Section 2. Composition / information on ingredients Declaration of ingredients according to (EC) No 1907/2006: Hazardous components CAS-No. Dibutyl ether Reaction product of tris(nmethylamino)methylsilane (TMAS) and silanol terminated polydimethylsiloxane (PDMS) EINECS content Classification >= 50 - <= 100 % R10 Xi - Irritant; R36/37/38 R52/53 >= 0,1 - < 5 % F - Highly flammable; R14/15 F+ - Extremely flammable; R12 F - Highly flammable; R17 Xn - Harmful; R20 Xi - Irritant; R37/38, R41, R43 Section 3. Hazards identification Hazard classification: Health Effects: Xi - Irritant R10 Flammable. R15 Contact with water liberates extremely flammable gases. R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Section 4. First aid measures Inhalation: Skin contact: Move to fresh air. If symptoms persist, seek medical advice. Rinse with running water and soap. Obtain medical attention if irritation persists.

2 Page 2 of 5 Eye contact: Ingestion: Flush eyes with plenty of water for at least 5 minutes. If irritation persists seek medical attention. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Section 5. Fire fighting measures Particular danger in case of fire: Suitable extinguishing media: Special protection equipment for firefighters: Hazardous combustion products: Can form explosive gas/air mixtures. carbon dioxide, foam, powder, water spray jet, fine water spray Alcohol-resistant foam Wear self-contained breathing apparatus. Keep personnel upwind of fire. Irritating organic vapours. See section 10. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Wear protective equipment. Keep unprotected persons away. Remove sources of ignition. Ensure adequate ventilation. Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems. Prevent further leakage or spillage if safe to do so. Remove mechanically. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Handling: Storage: Ventilate working rooms throughly. Avoid naked flames, sparking and sources of ignition. Switch off electrical devices. Do not smoke, do not weld. Take measures to prevent the build-up of electrostatic charges. Do not spray onto flames or red-hot objects. See advice in section 8 Avoid skin and eye contact. Store in sealed original container protected against moisture. Close the container carefully after use and store it at a good ventilated place. plastics which are soluble in organic solvents Do not store together with oxidants. Keep container tightly sealed. Must be stored in a room with spill collection facilities. Keep away from heat and direct sunlight. Do not store near sources of heat or ignition, or reactive materials. Section 8. Exposure controls / personal protection Ingredient Type ppm mg/m 3 Remarks

3 Page 3 of 5 Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Use filter A-P2 if vapours/aerosols occur which may be inhaled. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: General protection measures: Hygienic measures: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Wear suitable protective clothing. Ensure good ventilation/extraction. The workplace should be equipped with an emergency shower and eye-rinsing facility. Keep away from food, beverages and animal feed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Good industrial hygiene practices should be observed. Section 9. Physical and chemical properties Appearance: Colorless Liquid Odor: mild, Solvent Relative vapour density: Heavier than air Specific gravity: 0,769 Boiling point: > 142 C (> F) Flash point: 25 C (77 F) Vapor pressure: 4,8 mm hg Density: 0,77 g/cm3 Solubility: Solvent: Water, Insoluble Section 10. Stability and reactivity Conditions to avoid: Exposure to air or moisture over prolonged periods. Vapours may form explosive mixture with air. Spray mist may be flammable at temperatures below the flash point. Heat, flames, sparks and other sources of ignition. No decomposition if stored and applied as directed.

4 Page 4 of 5 Materials to avoid: Reaction with oxidants. Reaction with water. Peroxides can be formed. Reaction with strong bases Reaction with strong acids. Hazardous decomposition products: Irritating vapors. Hydrocarbons carbon oxides. See section 5. Section 11. Toxicological information General toxicological information: No experimental toxicological data on the preparation as such is available. Section 12. Ecological information General ecological information: Do not empty into drains / surface water / ground water. Section 13. Disposal considerations Product Method of disposal: Packaging Disposal for uncleaned package: Dispose of in accordance with local and national regulations. Dispose of in accordance with local and national regulations. Section 14. Transport information Road transport ADR: Hazard ident. number: 30 Railroad transport RID: Hazard ident. number: 30

5 Page 5 of 5 Inland water transport ADN: Hazard ident. number: Marine transport IMDG: EmS: F-E,S-E Seawater pollutant: - Proper shipping name: Air transport IATA: Packing instructions (passenger) 355 Packing instructions (cargo) 366 Proper shipping name: Resin solution Section 15. Regulations - classification and identification Indication of danger: Risk phrases: Safety phrases: Dibutyl ether Xi - Irritant R10 Flammable. R15 Contact with water liberates extremely flammable gases. R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S7/8 Keep container tightly closed and dry. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. In case of fire, use... S60 This material and its container must be disposed of as hazardous waste. OECD. Program to investigate the potential hazards of high production volume chemicals (HPV), including decisions on the need for further work. Issue date: Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.