Safety Data Sheet SABO STAB UV 119

Transcription

1 Safety Data Sheet dated 24/2/2014, version 4 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Mixture identification: Trade name: Trade code: SAUV Relevant identified uses of the substance or mixture and uses advised against Recommended use: Antioxidant/stabilizer SU3-SU5-SU8-SU9-SU10 Industrial use 1.3. Details of the supplier of the safety data sheet Company: SABO SpA Via Caravaggi Levate BG Sabo Spa Tel fax Competent person responsible for the safety data sheet: sds@sabo.com 1.4. Emergency telephone number Sabo Spa Tel fax SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof: Properties / Symbols: Xi Irritant N Dangerous for the environment R Phrases: R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. EC regulation criteria 1272/2008 (CLP): Warning, Skin Sens. 1, May cause an allergic skin reaction. Warning, STOT RE 2, May cause damage to organs through prolonged or repeated exposure. Aquatic Chronic 2, Toxic to aquatic life with long lasting effects. Adverse physicochemical, human health and environmental effects: No other hazards 2.2. Label elements Symbols: Xi Irritant N Dangerous for the environment R Phrases: Page n. 1 of 9

2 R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S Phrases: S24 Avoid contact with skin. S37 Wear suitable gloves. S56 Dispose of this material and its container to hazardous or special waste collection point. S57 Use appropriate container to avoid environmental contamination. S60 This material and its container must be disposed of as hazardous waste. Contents: 4,7-diazadecane-1,10-diamine Symbols: Warning Hazard statements: H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Precautionary statements: P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P391 Collect spillage. P501 Dispose of contents/container in accordance with applicable regulations. Special Provisions: Contents: 4,7-diazadecane-1,10-diamine Special provisions according to Annex XVII of REACH and subsequent amendments: 2.3. Other hazards vpvb Substances: - PBT Substances: Other Hazards: Risk of explosion if an air-dust mixture forms SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Product type and use: Hindered Amine Light Stabilizer (HALS) for plastics and coatings Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related classification: 80% - 90% 4,7- diazadecane-1,10-diamine REACH No.: , Index number: , CAS: , EC: Xi,N; R /1 Skin Sens. 1 H317 Page n. 2 of 9

3 3.9/2 STOT RE 2 H /C2 Aquatic Chronic 2 H411 SECTION 4: First aid measures 4.1. Description of first aid measures In case of skin contact: Immediately take off all contaminated clothing. Areas of the body that have - or are only even suspected of having - come into contact with the product must be rinsed immediately with plenty of running water and possibly with soap. Wash thoroughly the body (shower or bath). Remove contaminated clothing immediately and dispose off safely. In case of eyes contact: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of Ingestion: Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY. In case of Inhalation: Remove casualty to fresh air and keep warm and at rest Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). Treatment: SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media: Water. Carbon dioxide (CO2). Extinguishing media which must not be used for safety reasons: in particular Special hazards arising from the substance or mixture Do not inhale explosion and combustion gases. Burning produces heavy smoke Advice for firefighters Use suitable breathing apparatus. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and Environmental precautions Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it. In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities. Suitable material for taking up: absorbing material, organic, sand Page n. 3 of 9

4 6.3. Methods and material for containment and cleaning up Wash with plenty of water Reference to other sections See also section 8 and 13 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid contact with skin and eyes, inhalation of vapours and mists. Don't use empty container before they have been cleaned. Before making transfer operations, assure that there aren't any incompatible material residuals in the containers. Contamined clothing should be changed before entering eating areas. Do not eat or drink while working. See also section 8 for recommended protective equipment Conditions for safe storage, including any incompatibilities Keep away from food, drink and feed. Incompatible materials: in particular. Instructions as regards storage premises: Adequately ventilated premises Specific end use(s) Danger! Explosion risk Risk of explosion if an air-dust mixture forms. Avoid creating dusty deposition; closed system ;electrical device and lighting must be dust proof. Seek expert advice SECTION 8: Exposure controls/personal protection 8.1. Control parameters No occupational exposure limit available DNEL Exposure Limit Values 4,7-diazadecane-1,10-diamine - CAS: Worker Professional: 0.36 mg/m3 - Exposure: Human Inhalation Long Term, systemic effects Worker Professional: 0.05 mg/kg - Exposure: Human Dermal Long Term, systemic effects Consumer: mg/kg - Exposure: Human Dermal Long Term, systemic effects Consumer: mg/kg - Exposure: Human Oral Long Term, systemic effects PNEC Exposure Limit Values 4,7-diazadecane-1,10-diamine - CAS: Target: Fresh Water - Value: 0.06 mg/l Target: Marine water - Value: mg/l Target: 10 - Value: mg/l Target: Freshwater sediments - Value: 28.3 mg/kg Target: Marine water sediments - Value: 2.83 mg/kg 8.2. Exposure controls Eye protection: Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Protection for skin: Chemical protection clothing. Protection for hands: Hand protection: Chemical resistant protective gloves (EN 374) Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374) Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Particle filter with Page n. 4 of 9

5 medium /high efficiency for solid particles (e.g. EN 143 or 149, Type P2 or FFP2) Thermal Hazards: Environmental exposure controls: SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance and colour: Slightly yellow pastilles Odour: slightly aminic Odour threshold: ph: ND Melting point / freezing point: C (softening range) Initial boiling point and boiling range: NA Solid/gas flammability: ND Upper/lower flammability or explosive limits: Vapour density: ND Flash point: > 275 C Evaporation rate: Vapour pressure: ND Relative density: 1.03 Solubility in water: </= 2.0 mg/l (20 C) Solubility in oil: ND Partition coefficient (n-octanol/water): ND Auto-ignition temperature: ND Decomposition temperature: Viscosity: Explosive properties: ND Oxidizing properties: ND 9.2. Other information Miscibility: Fat Solubility: Conductivity: Substance Groups relevant properties SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Stable under normal conditions Incompatible materials in particular Hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Toxicological information of the mixture: Toxicological information of the main substances found in the mixture: Page n. 5 of 9

6 4,7-diazadecane-1,10-diamine - CAS: a) acute toxicity: Test: LD50 - Route: Oral - Species: Rat > 5000 mg/kg Test: LD50 - Route: Skin - Species: Rat > 2000 mg/kg b) skin corrosion/irritation: Test: Skin Irritant - Route: Skin - Species: Rabbit Negative c) serious eye damage/irritation: Test: Eye Irritant - Species: Rabbit Negative d) respiratory or skin sensitisation: Test: Skin Sensitization - Species: Mouse Positive - Source: OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) e) germ cell mutagenicity: Test: Mutagenesis Negative f) carcinogenicity: Test: Carcinogenicity Negative g) reproductive toxicity: Test: Reproductive Toxicity - Species: Rat 400 Ppm If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as : a) acute toxicity; b) skin corrosion/irritation; c) serious eye damage/irritation; d) respiratory or skin sensitisation; e) germ cell mutagenicity; f) carcinogenicity; g) reproductive toxicity; h) STOT-single exposure; i) STOT-repeated exposure; j) aspiration hazard. SECTION 12: Ecological information Toxicity Adopt good working practices, so that the product is not released into the environment. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4,7-diazadecane-1,10-diamine - CAS: a) Aquatic acute toxicity: Endpoint: LC50 - Species: Fish > 119 mg/l - Duration h: 96 Endpoint: EC50 - Species: Dafnia Magna = 7.3 mg/l - Duration h: 24 b) Aquatic chronic toxicity: Endpoint: EC50 - Species: Dafnia Magna = 100 mg/l - Notes: 21 days e) Plant toxicity: Endpoint: EC50 - Species: Algae = 5.7 mg/kg - Duration h: Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment vpvb Substances: - PBT Substances: Other adverse effects Page n. 6 of 9

7 SECTION 13: Disposal considerations Waste treatment methods Recover if possible. In so doing, comply with the local and national regulations currently in force. SECTION 14: Transport information UN number ADR-UN Number: 3077 IATA-UN Number: 3077 IMDG-UN Number: UN proper shipping name ADR-Shipping Name: IATA-Shipping Name: IMDG-Shipping Name: Transport hazard class(es) ADR-Class: 9 ADR - Hazard identification number: 90 IATA-Class: 9 IATA-Label: 9 IMDG-Class: Packing group ADR-Packing Group: III IATA-Packing group: III IMDG-Packing group: III Environmental hazards ADR-Enviromental Pollutant: IMDG-Marine pollutant: Special precautions for user ADR-Subsidiary risks: - ADR-S.P.: ADR-Tunnel Restriction Code: (E) IATA-Passenger Aircraft: 956 IATA-Subsidiary risks: - IATA-Cargo Aircraft: 956 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT STABILIZER.) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT STABILIZER.) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (HIGH MOLECULAR WEIGHT HINDERED AMINE LIGHT STABILIZER.) Yes Marine Pollutant IATA-S.P.: A97 A158 A179 IATA-ERG: 9L IMDG-EmS: F-A, S-F IMDG-Subsidiary risks: - IMDG-Storage category: Category A IMDG-Storage notes: Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Page n. 7 of 9

8 Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances) Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations) Dir. 98/24/EC (Risks related to chemical agents at work) Dir. 2000/39/EC (Occupational exposure limit values) Dir. 2006/8/EC Regulation (EC) n. 1907/2006 (REACH) Regulation (EC) n. 1272/2008 (CLP) Regulation (EC) n. 790/2009 (ATP 1 CLP) Regulation (EU) n. 453/2010 (Annex I) Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006 (REACH) and subsequent modifications: Volatile Organic compounds - VOCs = 0.00 g/l Volatile CMR substances = 0.00 % Halogenated VOCs which are assigned the risk phrase R40 = 0.00 % Organic Carbon - C = 0.00 Where applicable, refer to the following regulatory provisions : Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent amendments. Regulation (EC) nr 648/2004 (detergents). 1999/13/EC (VOC directive) Chemical safety assessment No SECTION 16: Other information Text of phrases referred to under heading 3: R43 May cause sensitization by skin contact. R51 Toxic to aquatic organisms. R53 May cause long-term adverse effects in the aquatic environment. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. SECTION 3: Composition/information on ingredients SECTION 9: Physical and chemical properties SECTION 11: Toxicological information SECTION 12: Ecological information This document was prepared by a competent person who has received appropriate training. Main bibliographic sources: ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European Communities SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold CCNL - Appendix 1 Insert further consulted bibliography The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and constitutes no guarantee of particular quality. It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended. This MSDS cancels and replaces any preceding release. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road. Page n. 8 of 9

9 CAS: CLP: DNEL: EINECS: GefStoffVO: GHS: IATA: IATA-DGR: ICAO: ICAO-TI: IMDG: INCI: KSt: LC50: LD50: LTE: PNEC: RID: STE: STEL: STOT: TLV: TWATLV: WGK: : N.D.: Chemical Abstracts Service (division of the American Chemical Society). Classification, Labeling, Packaging. Derived No Effect Level. European Inventory of Existing Commercial Chemical Substances. Ordinance on Hazardous Substances, Germany. Globally Harmonized System of Classification and Labeling of Chemicals. International Air Transport Association. Dangerous Goods Regulation by the "International Air Transport Association" (IATA). International Civil Aviation Organization. Technical Instructions by the "International Civil Aviation Organization" (ICAO). International Maritime Code for Dangerous Goods. International Nomenclature of Cosmetic Ingredients. Explosion coefficient. Lethal concentration, for 50 percent of test population. Lethal dose, for 50 percent of test population. Long-term exposure. Predicted No Effect Concentration. Regulation Concerning the International Transport of Dangerous Goods by Rail. Short-term exposure. Short Term Exposure limit. Specific Target Organ Toxicity. Threshold Limiting Value. Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard). German Water Hazard Class. Page n. 9 of 9