SAFETY DATA SHEET FSC-10E

Transcription

1 1. Identification of the Substance/Preparation & of the Company/Undertaking. Product Name: FSC-10E Furmanite Product Code: Not allocated. Product Type & Use: Slow cure underwater injection resin, used for filling encapsulation clamps and injection of leaking flanges. To be used only in accordance with approved Furmanite procedures, by Furmanite trained personnel. NO OTHER ACCEPTABLE USES. Company Identification: Furmanite International Limited, Furman House, Shap Road, +44 (0) Kendal, Fax +44 (0) Cumbria. LA9 6RU eu-info.uk@furmanite.com Great Britain. eu-hqse.uk@furmanite.com For further information Monday to Friday 8:30 17:00: +44 (0) Emergency Telephone Number (outside office hours): +44 (0) Hazards Identification. GHS Classification of the mixture. May cause cancer. Harmful by inhalation. Dangerous for the environment Part B: GHS Label element. Harmful by inhalation. Harmful by inhalation. Under the Classification, Labelling and Packaging of Substances and Mixtures (CLP Regulation) (EC) No 1272/2008. Labelling requirements; Symbol: Warning Danger. Warning Dangerous for the environment Hazards H332 Harmful if inhaled. Statements: H350 May cause cancer. H411 Toxic to aquatic life with lasting effects. Precautionary P285 In case of insufficient ventilation, wear suitable respiratory equipment Part B. Symbol: Blend of polyether polyols and mineral fillers, also contains petroleum substances derived from Gas Oils (petroleum), steam-cracked. Warning Danger. Hazards H332 Harmful if inhaled. Statements: H315 Causes skin irritation. H319 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer. H372 Causes damage to organs through prolonged or repeated exposure. EUH204 isocyanates. May produce an allergic reaction. Precautionary P262 Do not get in eyes, on skin or on clothing. P271 Use only in a well ventilated area. P285 In case of inadequate ventilation wear respiratory protection. P305 IF IN EYES: Rinse immediately with plenty of water and seek medical advice. P302 IF ON SKIN: wash immediately with plenty of soap and water. Diphenylmethane-4.4'-diisocyanate. Date of Issue: 25 th March 2015 Revision Number: 0 Page 1 of 3

2 (Hazards Identification. Continued.) Symbol: Warning. Hazards H335 May cause respiratory irritation. Statements: Precautionary P285 In case of insufficient ventilation, wear suitable respiratory equipment. granular rubber and carbon black. 3. Composition & Information on Ingredients for the Mixture. Viscose polyurethane resin system. Blend of Polyether polyols and mineral fillers. petroleum substances which are a complex mixture of constituents of variable composition. Gas oils (petroleum), steam-cracked. CAS (1 30%) Part B: Diphenylmethane-4.4'-diisocyanate. CAS (60-100%). granular rubber and carbon black. 4. First-Aid Measures. Inhalation: Skin Contact: Eye Contact: Inhalation of vapour may cause nausea and irritation of the nose and throat. Remove to fresh air. If irritation persists, obtain medical attention. Splashes of the liquids will cause localised skin irritation. Wash with soap or with usual hand cleaner and water. If irritation persists, obtain medical attention. Splashes of the liquids will cause physical irritation. Immediately irrigate with water for at least 15 minutes. OBTAIN IMMEDIATE MEDICAL ATTENTION. Ingestion of the preparation will cause irritation, physical discomfort and nausea. Do not induce vomiting. Immediately give water or milk to drink. OBTAIN IMMEDIATE MEDICAL ATTENTION. 5. Fire-Fighting Measures. Extinguishing Media: Water spray, foam, CO 2, dry powder. Specific Hazards: Gives off toxic fumes, which may contain oxides of nitrogen and carbon and possible un-burnt hydrocarbons and cyanides. Special Protective Equipment and Precautions: Breathing apparatus should be worn in confined spaces. 6. Accidental Release Measures. Spilt material, either from the individual components or the mixed material, should be prevented from entering any watercourses and drains. Do not allow to enter the ground/soil. Any material spilt onto soil should be removed and any contaminated soil collected for disposal. See also section 12. Clean up using absorbent material and place into a metal container. Chemical resistant gloves to EN 338/374-3 must be worn when cleaning up this material. Dispose of as in section Handling and Storage. Handling: Chemical resistant gloves to EN 338/374-3 must be worn when handling the resin components. Storage: Store in original packaging, in dry, cool conditions (recommended minimum 5 o C to a maximum temperature of 20ºC) and away from direct sunlight or other UV sources. Expiry date, with above conditions will be a minimum of twelve months from the date of manufacture as shown on the labels. Date of Issue: 25 th March 2015 Revision Number: 0 Page 2 of 3

3 8. Exposure Controls/Personal Protection. Control parameters: Occupational Exposure Limit: None allocated. Exposure Controls: Respiratory Protection: Hand Protection: Eye Protection: If using in a poorly ventilated areas or in a confined space, forced ventilation should be provided. If not available or impractical, a face mask/respirator with organic vapour filter to A1 should be worn. If being used at temperatures above 40 o C and in a poorly ventilated area or a confined space, a respirator with organic mist filter to A1 must be worn or positive pressure breathing apparatus is recommended. A minimum of gloves to EN 338/374-3 must be worn when handling, mixing and using the resin. The resin is unlikely to be absorbed or breakthrough the specified gloves. Wear goggles to EN 166, when handling, mixing and using the resin. If filling a component above waist height, a visor to EN 166 is recommended. Safety glasses are recommended to be the minimum protection worn when handling the closed resin containers. Body Protection: Disposable coveralls to EN14605 Type 3; EN14605 Type 4; EN ISO Type 5 are recommended. 9. Physical and Chemical Properties. Part A Part B Part C Form: Dark Brown liquid. Yellow liquid. Black granules & powder Odour: Pitch like. None. None Specific gravity: g/cm 3 at 25ºC g/cm 3 at 25ºC Not determined. Boiling point: >200ºC >200ºC Not applicable. Melting point: Not determined Not determined Not applicable. Change in physical state: None likely to occur. May crystallise due to low temperatures. None likely to occur. Vapour pressure: Not determined Not determined Not determined Solubility in water: Insoluble Insoluble Insoluble ph value: Not applicable. Not applicable. Not applicable. Solubility: Some organic solvents, typically aromatic and ketones. Some organic solvents, typically aromatic and ketones. None known. Flash point: >200ºC >200ºC >200ºC Auto-ignition temperature: >200ºC. >200ºC. >200ºC. Explosive Limits: Not applicable Not applicable Not applicable Viscosity: Not applicable Flammability: Combustible liquid. Combustible liquid. Combustible solid. The cured material is a combustible solid, which requires a source of ignition. 10. Stability and Reactivity. Thermal Stability: Temperatures above 200ºC (392 o F) may evolve hazardous decomposition products, which may contain oxides of nitrogen and carbon and possible un-burnt hydrocarbons. Date of Issue: 25 th March 2015 Revision Number: 0 Page 3 of 3

4 11. Toxicological Information. Health Hazards: Localised skin irritation may occur. Repeated exposure may cause sensitisation. Repeated exposure may cause cancer. Irritating to eyes but unlikely to cause any long term damage. Inhalation (of vapour): Harmful by inhalation. Risk is low unless being used at temperatures above 40 o C when harmful vapours may be released. (See section 8.). Irritant. Unlikely to cause lasting harm. Part B: Inhalation (of vapour): Inhalation (of dust): Localised skin irritation may occur. Repeated exposure may cause sensitisation. Irritant. May cause damage to the cornea if not washed out immediately. Reacts with moisture to form a solid urea which may not be removed. Harmful by inhalation. Risk is low unless being used at temperatures above 40 o C when harmful vapours may be released. (See section 8.). Irritant. Unlikely to cause lasting harm, unless large quantities have been ingested which may react to form a solid mass of urea. Localised skin irritation may occur. Irritating to eyes but unlikely to cause any long term damage. May cause respiratory irritation but unlikely to cause lasting harm. Irritant. Unlikely to cause lasting harm. Special Effects: In its cured form the product is not classified as dangerous. During curing the extent of the hazard depends on the extent to which the curing reaction has progressed. 12. Ecological Information. Ecotoxicity. Ecological effects not fully determined. The mixed material is unlikely to be hazardous to air, water and/or soil. Unmixed Part A is likely to be hazardous to water and soil. Unmixed Part B is unlikely to be hazardous to water or soil, as it readily reacts to form an insoluble urea. Unmixed Part C is unlikely to be hazardous to water or soil. Mobility. The mixed material is unlikely to be transport to groundwater or far from the site of release. Unmixed materials are unlikely to be transport to groundwater or far from the site of release. Persistence and Degradability. The preparation is non degradable. Bioaccumulative Potential. Effects not determined. The mixed material and unmixed Part B and Part C are unlikely to accumulate in biota or to enter into the food chain. Unmixed Part A may accumulate in the biota and could enter into the food chain. Other adverse effects: No known significant effects or critical hazards. NOTE: In its cured form, the material will not pose a risk to the environment. 13. Disposal Considerations. React unused material. May be landfill or incinerate in accordance with local regulations. If this preparation in its uncured form becomes waste, it must be treated as Hazardous Waste (Special Waste in Scotland) and an approved specialist waste contractor consulted in accordance with the Hazardous Waste (England and Wales) Regulations 2005 or Special Waste Regulations in Scotland. Packaging, containing no uncured residues, should be recycled as metal waste or disposed of landfill in accordance with local regulations. Packaging, containing uncured residues, should be treated as Hazardous Waste (Special Waste in Scotland) and an approved specialist waste contractor consulted. Alternatively, arrangements can be made to return unused materials and their original packaging, to Furmanite International Limited, for disposal/recycling. Date of Issue: 25 th March 2015 Revision Number: 0 Page 4 of 3

5 14. Transport Information. PART A: Proper Shipping Name: Toxic Liquid, Organic, N.O.S. Polyether Polyol. (: Gas oils (petroleum), steamcracked; Phenanthrene; Napthalene; Pyrene; Benzo(a)pyrene ) PART A: UN Number: Proper Shipping Name: UN2810 Toxic liquid, Organic, N.O.S. Polyether Polyol. ADR/RID (Road) Class: 6.1 Hazard Index Number: 60 Label: 6.1 Designation of goods: Toxic liquid, Organic, N.O.S. Polyether Polyol. IMDG (Sea) Class: 6.1 UN Number: 2810 Packaging Group: III EMS Code: F-A-S-A. MFAG: None. Correct technical name: Toxic liquid, Organic, N.O.S. Polyether Polyol ICAO/IATA (Air): Class 6.1 UN/ID Number: 2810 Packaging Group: III Packing Instructions (Cargo): 663 Max. Qty/Pack: 220L Packing Instructions (Passenger): 655 Max. Qty/Pack: 60L Correct technical name: Toxic liquid, Organic, N.O.S. Polyether Polyol PART B: PART C: Not classified as hazardous for transportation. Not classified as hazardous for transportation. 15. Regulatory Information. This document has been prepared in accordance with European Community Regulation 1907/2006 (Registration, Evaluation, Authorisation and Restriction of Chemicals - REACH). Under the limited quantity exemption contained within REACH: (manufactured in quantities of less than 1 tonne per annum) this material does not require registration. 16. Other Information. This is a leak sealing compound, to be used only in accordance with approved Furmanite procedures, by Furmanite trained personnel. NO OTHER ACCEPTABLE USES. This document has been created to bring the information in line with the Globally Harmonized System of Classification and Labelling of Chemicals (GHS); there have been no changes in the safety aspects of the compound. According to our best knowledge and information, we believe this information to be accurate. Date of Issue: 25 th March 2015 Revision Number: 0 Page 5 of 3