: Cationic Demulsifier

Transcription

1 Date of issue: 06/01/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : DWT 6285 Cationic Demulsifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Dober Chemical Corp 543 Forest Road Humboldt Industrial Park Hazle Township, PA US T F regulatory@dobergroup.com Emergency telephone number : Cationic Demulsifier Emergency number : / ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification Calcium chloride (CAS No) Acute Tox. 4 (Oral), H302 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest Most important symptoms and effects, both acute and delayed Symptoms/injuries : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : Not expected to present a significant hazard under anticipated conditions of normal use. 07/07/2015 EN (English) Page 1

2 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters DWT 6285 Cationic Demulsifier ACGIH : Sources of ignition. Direct sunlight. OSHA ACGIH OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. 07/07/2015 EN (English) 2/1

3 Hand protection Eye protection Respiratory protection Other information : Wear protective gloves/protective clothing/eye protection/face protection protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Colour : light yellow Odour : characteristic Odour threshold ph : 6.50 Relative evaporation rate (butylacetate=1) Melting point Freezing point : C Boiling point Flash point : Not Applicable. Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : 1.68 kpa Relative vapour density at 20 C : 1 Relative density : Density : g/ml Solubility : Water: 100 % Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic : 700 cp Explosive properties Oxidising properties Explosive limits 9.2. Other information VOC content : 23 % SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. 07/07/2015 EN (English) 3/1

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat ATE US (oral) ATE US (dermal) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms 1000 mg/kg 2630 mg/kg mg/kg bodyweight mg/kg bodyweight ph: 6.50 ph: 6.50 : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity EC50 Daphnia mg/l (Exposure time: 48 h - Species: Daphnia magna) Persistence and degradability DWT 6285 Cationic Demulsifier Persistence and degradability Bioaccumulative potential DWT 6285 Cationic Demulsifier Bioaccumulative potential BCF fish 1 (no bioaccumulation) Mobility in soil Other adverse effects Effect on the global warming Other information : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information UN-No.(DOT) : Non Regulated 07/07/2015 EN (English) 4/1

5 14.2. UN proper shipping name Proper Shipping Name (DOT) : Transport hazard class(es) Department of Transportation (DOT) Hazard Classes : : Packing group Packing group (DOT) : Environmental hazards SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm SECTION 16: Other information Other information : None. Full text of H-phrases:: Acute Tox. 4 (Oral) Acute toxicity (oral), Category H302 Harmful if swallowed NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : NA - Not Applicable 07/07/2015 EN (English) 5/1

6 HMIS III Rating Health Flammability : 0 Physical : 0 Personal Protection Dober SDS US : 0 - No significant risk to health : A To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 07/07/2015 EN (English) 6/1