Safety Data Sheet according to Regulation (EC) No1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No1907/2006 LOCTITE 34A Page 1 of 10 SDS No. : Revision: printing date: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier LOCTITE 34A Contains: Chemical frits (containing lead) 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Grinding compound 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) Fax-no.: +49 (211) Emergency telephone number Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Toxic to reproduction H360Df May damage the unborn child. Suspected of damaging fertility. Category 1A Classification (DPD): Toxic for reproduction - category 1. R61 May cause harm to the unborn child. R33 Danger of cumulative effects Label elements Label elements (CLP): Hazard pictogram: Signal word: Danger

2 Hazard statement: LOCTITE 34A Page 2 of 10 H360Df May damage the unborn child. Suspected of damaging fertility. Supplemental information Restricted to professional users. Precautionary statement: Prevention Precautionary statement: Response P201 Obtain special instructions before use. P281 Use personal protective equipment as required. P308+P313 IF exposed or concerned: Get medical advice/attention. Label elements (DPD): T - Toxic Risk phrases: R61 May cause harm to the unborn child. R33 Danger of cumulative effects. Safety phrases: S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water and soap. S35 This material and its container must be disposed of in a safe way. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S51 Use only in well-ventilated areas. S53 Avoid exposure - obtain special instructions before use. Additional labeling: Restricted to professional users. Contains: Chemical frits (containing lead) 2.3. Other hazards None if used properly. General chemical description: Grinding compound SECTION 3: Composition/information on ingredients

3 LOCTITE 34A Page 3 of 10 Declaration of the ingredients according to CLP (EC) No 1272/2008: Chemical frits (containing lead) EC Number REACH-Reg No. content Classification > 10- < 20 % Acute toxicity 4; Oral H > 1- < 3 % Acute toxicity 4; Oral H302 Acute toxicity 4; Inhalation H332 Toxic to reproduction 1A H360Df Specific target organ toxicity - repeated exposure 2 H373 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Chemical frits (containing lead) EC Number content Classification REACH-Reg No > 10 - < 20 % Xn - Harmful; R > 1 - < 3 % Toxic for reproduction - category 1.; T - Toxic; R61 Toxic for reproduction - category 3.; Xn - Harmful; R62 Xn - Harmful; R20/22 R33 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available Description of first aid measures SECTION 4: First aid measures Inhalation: Move to fresh air. If symptoms persist, seek medical advice. Skin contact: Rinse with running water and soap. Obtain medical attention if irritation persists. Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor Most important symptoms and effects, both acute and delayed Prolonged or repeated contact may cause skin irritation. Prolonged or repeated contact may cause eye irritation Indication of any immediate medical attention and special treatment needed See section: Description of first aid measures 5.1. Extinguishing media Suitable extinguishing media: Carbon dioxide, foam, powder SECTION 5: Firefighting measures

4 LOCTITE 34A Page 4 of Special hazards arising from the substance or mixture Oxides of carbon, oxides of nitrogen, irritating organic vapors Advice for firefighters Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Additional information: In case of fire, keep containers cool with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid skin and eye contact. Ensure adequate ventilation Environmental precautions Do not let product enter drains Methods and material for containment and cleaning up For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal Reference to other sections See advice in section Precautions for safe handling Use only in well-ventilated areas. Vapours should be extracted to avoid inhalation. Prolonged or repeated skin contact should be avoided Avoid skin and eye contact. See advice in section 8 Hygiene measures: Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. SECTION 7: Handling and storage 7.2. Conditions for safe storage, including any incompatibilities Store in a cool, well-ventilated place. Keep away from heat and direct sunlight Specific end use(s) Grinding compound

5 LOCTITE 34A Page 5 of 10 SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for South Africa Ingredient ppm mg/m 3 Type Category Remarks SILICON CARBIDE, TOTAL 10 Time Weighted Average ZA REL INHALABLE DUST (TWA): SILICON CARBIDE, RESPIRABLE DUST Time Weighted Average (TWA): ZA REL ETHANE-1,2-DIOL, VAPOUR 1,2-DIHYDROXYETHANE, VAPOUR ETHYLENE GLYCOL, VAPOUR ETHANE-1,2-DIOL, PARTICULATE ETHYLENE GLYCOL, PARTICULATE 1,2-DIHYDROXYETHANE, PARTICULATE ETHANE-1,2-DIOL, VAPOUR ETHYLENE GLYCOL, VAPOUR 1,2-DIHYDROXYETHANE, VAPOUR 125 Short Term Limit (STEL): 10 Time Weighted Average (TWA): 60 Time Weighted Average (TWA): ZA REL ZA REL ZA REL Predicted No-Effect Concentration (PNEC): Name on list Environmental Compartment aqua (freshwater) aqua (marine water) sediment (freshwater) STP aqua (intermittent releases) soil period Value mg/l ppm mg/kg others 10 mg/l 1 mg/l 20,9 mg/kg 199,5 mg/l 10 mg/l 1,53 mg/kg Remarks Derived No-Effect Level (DNEL): Name on list Application Area Route of Health Effect worker Dermal Long term exposure - systemic effects worker inhalation Long term exposure - local effects general Dermal Long term population exposure - systemic effects general population inhalation Long term exposure - local effects Time Value 106 mg/kg bw/day 35 mg/m3 53 mg/kg bw/day 7 mg/m3 Remarks

6 LOCTITE 34A Page 6 of 10 Biological Indices: None 8.2. controls: Engineering controls: Ensure good ventilation/suction at the workplace. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing. Skin protection: Wear suitable protective clothing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance paste grey Odor characteristic Odour threshold ph Initial boiling point Flash point Decomposition temperature Vapour pressure Density Bulk density Viscosity Viscosity (kinematic) Explosive properties Solubility (qualitative) Solidification temperature Melting point Flammability Auto-ignition temperature Explosive limits Partition coefficient: n-octanol/water Evaporation rate Vapor density Oxidising properties 9.2. Other information

7 LOCTITE 34A Page 7 of 10 SECTION 10: Stability and reactivity Reactivity Reacts with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid No decomposition if used according to specifications Incompatible materials See section reactivity Hazardous decomposition products Irritating organic vapours Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Danger of cumulative effects. Oral toxicity: May cause irritation to the digestive tract. Inhalative toxicity: May cause irritation to respiratory system. Skin irritation: Prolonged or repeated contact may cause skin irritation. Eye irritation: Expected to cause eye irritation by abrasive action of tiny metal particles Prolonged or repeated contact may cause eye irritation. Reproductive toxicity: May damage the unborn child. Suspected of damaging fertility. Acute oral toxicity: Value type Value Route of application time Species Method Acute 500 mg/kg oral Expert judgement toxicity estimate (ATE) LD50 > mg/kg rat EU Method B.1 (Acute Toxicity (Oral))

8 LOCTITE 34A Page 8 of 10 Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / time with and without Species Method SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation 1272/2008/EC. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following Toxicity Ecotoxicity: Do not empty into drains / surface water / ground water. Value type Value Acute Toxicity Study time Species Method LC mg/l Fish 96 h Pimephales promelas OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC mg/l Fish 28 d Oryzias latipes OECD Guideline 204 (Fish, Prolonged Toxicity Test: 14-day Study) EC mg/l Daphnia 48 h Ceriodaphnia sp. OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > mg/l Algae Microcystis aeruginosa OECD Guideline 201 (Alga, Growth Inhibition Test) NOEC mg/l chronic Daphnia 7 d Ceriodaphnia sp. OECD 211 (Daphnia magna, Reproduction Test) Persistence and degradability Persistence and Biodegradability: The product is not biodegradable. Result Route of application Degradability Method readily biodegradable aerobic % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) Bioaccumulative potential / Mobility in soil Mobility: Cured adhesives are immobile. Bioaccumulative potential: No data available. LogKow Bioconcentration factor (BCF) -1,36 time Species Temperature Method

9 LOCTITE 34A Page 9 of Results of PBT and vpvb assessment PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: Dispose of in accordance with local and national regulations. Disposal of uncleaned packages: Disposal must be made according to official regulations. Waste code Other solvents and solvent mixtures The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packaging group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content < 1 % (1999/13/EC)

10 LOCTITE 34A Page 10 of Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed. R33 Danger of cumulative effects. R61 May cause harm to the unborn child. R62 Possible risk of impaired fertility. H302 Harmful if swallowed. H332 Harmful if inhaled. H360Df May damage the unborn child. Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.