MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Lemon Cream Cleaner RAPIDO 1.2. Relevant identified uses of the substance or mixture and uses advised against To be used for cleaning kitchen work surfaces, gas and electric cookers, refrigerators, bathtubs, shower trays, washbasins, sinks, tiles and terracotta, as well as aluminium, chrome, copper, enamel, and glazed surfaces. Do not use on lacquered surfaces Details of the supplier of the safety data sheet Manufacturer: Zakłady Chemiczne "UNIA" Spółdzielnia Pracy Address: ul. Główna 14, Poznań, Poland Telephone number: Fax number: address of the person responsible for the MSDS: 1.4. Emergency phone number Mon. to Fri., 6 45 AM PM SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Pursuant to the provisions in force, the product is not classified as hazardous Label elements S2 Keep out of the reach of children Other hazards Skin contact: Prolonged contact with skin may cause irritation and dry skin. Contact with eyes: Possible eye irritation. Ingestion: May cause nausea and vomiting SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Aqueous suspension of mild abrasives, surfactants, and fragrance agents and additives. Hazardous component: Classification according to Regulation (EC) No. 1272/2008 of 16 December 2008 on classification, labelling and packaging (CLP) Name % weight CAS no. EC no.(einecs) Index no. Registration no. cocamide DEA c> Classification compliant with the Council Directive 67/548/ECC Name % weight CAS EC no.(einecs) Index no. Hazard symbol Classification according to Regulation 1272/2008/EC Eye damage 1, H318 Skin irrit. 2, H315 Risk phrase cocamide DEA c> Xi R38-41 Allergens in fragrance agents - Lemon - Limonene SECTION 4: First aid measures 4.1. Description of first aid measures Remove the injured from the place of exposure to open air. Consult a medicine doctor. Skin contact Immediately remove contaminated clothing. Rinse the skin with plenty of running water with soap. In the event of major irritation ensure medical assistance immediately. Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 1 of 5

2 Contact with eyes: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes with eyelids kept open. In the case of persistent symptoms, provide assistance of an eye doctor. Ingestion: If swallowed, do not induce vomiting. Provide immediately medical assistance Most important symptoms and effects, both acute and delayed Undetermined 4.3. Recommendations for immediate first-aid treatment and further treatment of the injured: Undetermined SECTION 5: Firefighting measures 5.1. Extinguishing media Extinguish fire in the presence of the substance with media suitable for burning materials 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Containers exposed to high temperature should be cooled with water from a safe distance, and if possible, removed from the hazardous area. Wear self-contained breathing apparatuses, protective gloves and clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid prolonged contact with skin. Avoid contact with eyes. Observe occupational health & safety rules and regulations governing the handling of chemical substances Environmental precautions Do not allow the product to enter sewage system, sewers, surface- and groundwater and soil. In the case of release of large quantities of product, inform the competent authorities Methods and material for containment and cleaning up Collect the spilled product using absorbent materials - rags, sand, sawdust, universal binder. Rinse the contaminated area thoroughly with water Reference to other sections - SECTION 7: Handling and storage 7.1. Precautions for safe handling Utilisation of the substance does not require special precautions. When working with large quantities of the substance, wear safety goggles or face cover, rubber gloves and protective clothing Conditions for safe storage, including any incompatibilities Store in sealed commercial containers at C in dry, ventilated rooms. The product should be protected from sunlight and heat sources Specific end use(s). SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure controls When working with the product observe general occupational health & safety rules applicable when handling chemicals. Respiratory protection: Under normal conditions, it is not required. Eye/face protection Should the risk occur that the product could splash into your eyes, it is recommended to wear safety glasses. Hand protection: Hand protection is not required in normal use. In the case of prolonged contact with hand skin use protective gloves. Technical means of protection General room ventilation or local exhaust ventilation. Other protection equipment: Under normal conditions, it is not required. In an emergency situation, if the concentration of the substance at the workstation is not known, use personal protective equipment of the highest recommended protection class. An employer shall ensure that the used personal protective equipment, clothing and footwear have protective properties and it shall ensure their proper cleaning, maintenance, repair and decontamination. Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 2 of 5

3 SECTION 9: Physical and chemical properties 9.1. Information on the basic physical and chemical properties a) Appearance: yellow or light green, viscous suspension (acceptable small stratification) b) Odour: characteristic for the used fragrance agent c) Odour threshold: undetermined d) ph: approx. 9 e) Melting point/freezing point undetermined f) Initial boiling point and boiling range approx. 100 O C g) Flash point not applicable h) Evaporation rate undetermined i) Flammability (solid, gas) non-combustible j) Upper/lower flammability or explosive limits not applicable k) Vapour pressure undetermined l) Vapour density undetermined m) Relative density approx. 1.2 g/cm 3 n) Solubility in water unlimited (suspension) o) Partition coefficient: n-octanol/water undetermined p) Auto-ignition temperature not applicable q) Decomposition temperature undetermined r) Viscosity undetermined s) Explosive properties not applicable t) Oxidising properties not applicable 9.2. Other information. SECTION 10: Reactivity and stability Reactivity No dangerous reactions are known Chemical stability At temp o C the mixture is stable Hazardous reactions Reacts with acids releasing carbon dioxide Conditions to avoid Under normal conditions of storage and use of the mixture unknown Incompatible materials Strong acids Hazardous decomposition products Under normal conditions of storage and use unknown Information on toxicology effects for: - Cocamide DEA LD 50 (orally) 2000 mg/kg SECTION 11: Toxicological information Local effects of the mixture: - Inhalation - no reports on significant effects or critical hazards - Ingestion - no reports on significant effects or critical hazards - Skin contact - no reports on significant effects or critical hazards - Eye contact - no reports on significant effects or critical hazards Toxicity: SECTION 12: Ecological information Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 3 of 5

4 The product is not hazardous to the environment Persistence and degradability Cocamide DEA biodegradability>92,5% after 28 days (OECD 301 B) The surfactants in the product are biodegradable Bioaccumulative potential The substances in the product are not subject to bioaccumulation (literature data) Mobility in soil Results of PBT and vpvb assessment Other hazardous effects SECTION 13: Disposal considerations Waste treatment methods The product should be completely used up. Empty containers can be disposed in containers for collection of plastic packaging. Do not mix with other types of waste; destroy in accordance with applicable regulations on disposal of waste. Waste code (from European Waste Catalogue): Waste not otherwise specified Plastic packaging (for bottles) Paper and cardboard packaging (for cardboard) SECTION 14: Transport information UN no. - not applicable UN proper shipping name - not applicable Transport hazard class(es) - not applicable Packaging group - not applicable Environmental hazards - none, according to the regulations in force Special precautions for users - not required Transport in bulk according to Annex II to MARPOL 73/78 and the IBC Code - not applicable SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture - Regulation (EC) No. 648/2004 of the European Parliament and the Council of 31 March 2004 on detergents - Commission Regulation (EC) No. 907/2006 of 20 June 2006 amending Regulation (EC) No. 648/2004 of the European Parliament and the Council on detergents, in order to adapt its Annexes III and VII - Regulation (EC) No. 1907/2006 of the European Parliament and the Council of 18 December 2006 concerning the registration, evaluation, authorisation and restriction of chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. - Regulation (EC) No. 1272/2008 of 16 December 2008 on classification, labelling and packaging (CLP) Chemical safety assessment Chemical safety assessment has not been performed for the substance of the mixture. SECTION 16: Other information The information herein applies only to the title product, reflecting the state of knowledge and experience. The information contained herein should be considered only as an aid to safe conduct in transport, distribution, handling and storage. Safety data sheet is not a certificate of product quality. The user of the product is required to comply with all applicable standards and regulations, and shall be responsible for improper use of information contained in the sheet. List of phrases used in point 3 Eye Damage 1 Serious eye damage, cat. 1 Skin Irrit. 2 - Skin irritation, cat. 2 H318 - Causes serious eye damage H315 - Causes skin irritation Xi - Irritant R41 - Risk of serious damage to eyes R38 - Irritating to skin Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 4 of 5

5 Trainings: Persons participating in the trade of hazardous substances should be trained in the handling, safety and hygiene. The safety data sheet is based on valid regulations and safety data sheets and supplier's data sheets. Amendments have been made in points: - Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 5 of 5