Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/4 Printing date Revision: Version number 3 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PF 6250 blue 300% Registration number The ingredients of this ink have been pre-registered according to 1907/2006/EC (REACH) Relevant identified uses of the substance or mixture and uses advised against Currently no such applications are identified Application of the substance / the preparation pigmented highlighter ink Details of the supplier of the safety data sheet Manufacturer/Supplier: DOKUMENTAL GmbH & Co KG Schreibfarben Woellnerstraße 26 D Ludwigshafen Phone + 49(0)621/ Fax + 49(0)621/ www. dokumental.de Further information obtainable from: Technical Service, Dr. B. Polzin Tel.: Mobile bernd.polzin@dokumental.de Emergency telephone number: GBK Gefahrgut Büro GmbH ++49 (0) 6132 / Ingelheim, Deutschland * 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (German GefStoffV). Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Mixture of the following substances, containing non-hazardous substances and colouring agents. Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: EINECS: ,7-bis(diethylamino)phenoxazin-5-iumchloride T R25 Acute Tox. 3, H301 Additional information: For the wording of the listed risk phrases refer to section 16. 1,0% 4 First aid measures Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 2) EU

2 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/4 Printing date Revision: Version number 3 Trade name: PF 6250 blue 300% Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. of page 1) 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling No special measures required. Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling EU (Contd. on page 3)

3 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/4 Printing date Revision: Version number 3 Trade name: PF 6250 blue 300% (Contd. of page 2) * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Product specific Odour threshold: Not determined. Important information on protection of health and environment, and on safety. - - ph-value at 20 C: 8,1 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: 160 C Flammability (solid, gaseous): Not applicable. Ignition temperature: 400 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 0,9 Vol % Upper: Not determined. Vapour pressure at 20 C: 23 hpa Density at 20 C: 1,08 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Segregation coefficient (n-octanol/water): Not determined. Viscosity: Dynamic at 20 C: Kinematic: Solvent content: Organic solvents: 27,0 % Water: 17,3 % Not miscible or difficult to mix. 11 mpas Not determined. Solids content: 0,1 % Other information ST: 37,3 mn/m 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. (Contd. on page 4) EU

4 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/4 Printing date Revision: Version number 3 Trade name: PF 6250 blue 300% (Contd. of page 3) When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. * 12 Ecological information Toxicity Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Smaller quantities can be disposed of with household waste. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * 14 Transport information Land transport ADR/RID (cross-border) ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - Packaging group: - Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Technical instructions (air): Class Share in % I 1.0 NK Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H301 Toxic if swallowed. R25 Toxic if swallowed. * Data compared to the previous version altered. EU

5 Page 1/5 Printing date 07/07/2011 Reviewed on 07/07/2011 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PF 6250 blue 300% Relevant identified uses of the substance or mixture and uses advised against Currently no such applications are identified Application of the substance / the preparation pigmented highlighter ink Details of the supplier of the safety data sheet Manufacturer/Supplier: DOKUMENTAL GmbH & Co KG Schreibfarben Woellnerstraße 26 D Ludwigshafen Phone + 49 (0)621/ Fax + 49 (0)621/ www. dokumental.de Information department: Technical Service, Dr. B. Polzin Tel.: Mobile bernd.polzin@dokumental.de Emergency telephone number: GBK Gefahrgut Büro GmbH ++49 (0) 6132 / Ingelheim, Deutschland 24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) Composition/information on ingredients Chemical characterization: Mixtures Mixture of the following substances, containing non-hazardous substances and colouring agents. Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: ,7-bis(diethylamino)phenoxazin-5-iumchloride 1.0% Additional information: For the wording of the listed risk phrases refer to section 16. * 3 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 1 Reactivity = 0 4 First aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. (Contd. on page 2)

6 Page 2/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6250 blue 300% After swallowing: If symptoms persist consult doctor. (Contd. of page 1) 5 Firefighting measures Suitable extinguishing agents: Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture No further relevant information available. Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling No special measures required. Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Breathing equipment: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. * 9 Physical and chemical properties General Information Appearance: Form: Fluid Color: According to product specification Odor: Product specific (Contd. on page 3)

7 Page 3/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6250 blue 300% Odour threshold: Not determined. Important information on protection of health and environment, and on safety. - ph-value at 20 C (68 F): 8.1 Change in condition Melting point/melting range: Boiling point/boiling range: Undetermined. 100 C (212 F) Flash point: 160 C (320 F) Flammability (solid, gaseous): Not applicable. Ignition temperature: 400 C (752 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. (Contd. of page 2) Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 0.9 Vol % Upper: Not determined. Vapor pressure at 20 C (68 F): 23 hpa (17 mm Hg) Density at 20 C (68 F): 1.08 g/cm³ (9.013 lbs/gal) Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Segregation coefficient (n-octonol/water): Not determined. Viscosity: Dynamic at 20 C (68 F): Kinematic: Solvent content: Organic solvents: 27.0 % Water: 17.3 % Not miscible or difficult to mix. 11 mpas Not determined. Solids content: 0.1 % Other information ST: 37,3 mn/m 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. * 12 Ecological information Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water (Contd. on page 4)

8 Page 4/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6250 blue 300% (Contd. of page 3) Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Waste treatment methods Recommendation: Smaller quantities can be disposed of with household waste. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - Packaging group: - * 15 Regulatory information Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. (Contd. on page 5)

9 Page 5/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6250 blue 300% National regulations: Technical instructions (air): Class Share in % I 1.0 NK (Contd. of page 4) Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. * Data compared to the previous version altered.

10 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/4 Printing date Revision: Version number 2 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PF 6210 green 300% Registration number The ingredients of this ink have been pre-registered according to 1907/2006/EC (REACH) Relevant identified uses of the substance or mixture and uses advised against Currently no such applications are identified Application of the substance / the preparation pigmented highlighter ink Details of the supplier of the safety data sheet Manufacturer/Supplier: DOKUMENTAL GmbH & Co KG Schreibfarben Woellnerstraße 26 D Ludwigshafen Phone + 49(0)621/ Fax + 49(0)621/ www. dokumental.de Further information obtainable from: Technical Service, Dr. B. Polzin Tel.: Mobile bernd.polzin@dokumental.de Emergency telephone number: GBK Gefahrgut Büro GmbH ++49 (0) 6132 / Ingelheim, Deutschland 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous Materials (German GefStoffV). Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Mixture of the following substances, containing non-hazardous substances and colouring agents. Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: C.I. Basic Yellow 40 Xi R41 2,5% EINECS: Eye Dam. 1, H318 Additional information: For the wording of the listed risk phrases refer to section First aid measures Description of first aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 2) EU

11 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/4 Printing date Revision: Version number 2 Trade name: PF 6210 green 300% Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. of page 1) 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling No special measures required. Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures are to be adhered to when handling chemicals. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling EU (Contd. on page 3)

12 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/4 Printing date Revision: Version number 2 Trade name: PF 6210 green 300% (Contd. of page 2) * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Product specific Odour threshold: Not determined. Important information on protection of health and environment, and on safety. - - ph-value at 20 C: 6,5 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 290 C Flash point: 160 C Flammability (solid, gaseous): Not applicable. Ignition temperature: 400 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 0,9 Vol % Upper: Not determined. Vapour pressure at 20 C: 0,1 hpa Density at 20 C: 1,08 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Segregation coefficient (n-octanol/water): Not determined. Viscosity: Dynamic at 20 C: Kinematic: Solvent content: Organic solvents: 13,4 % Water: 0,1 % Not miscible or difficult to mix. 41 mpas Not determined. Solids content: 1,4 % Other information ST: 37mN/m 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version. (Contd. on page 4) EU

13 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/4 Printing date Revision: Version number 2 Trade name: PF 6210 green 300% (Contd. of page 3) When used and handled according to specifications, the product does not have any harmful effects to our experience and the information provided to us. 12 Ecological information Toxicity Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Smaller quantities can be disposed of with household waste. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * 14 Transport information Land transport ADR/RID (cross-border) ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - Packaging group: - Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: Technical instructions (air): Class Share in % NK Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H318 Causes serious eye damage. R41 Risk of serious damage to eyes. * Data compared to the previous version altered. EU

14 Page 1/5 Printing date 07/07/2011 Reviewed on 07/07/2011 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PF 6210 green 300% Relevant identified uses of the substance or mixture and uses advised against Currently no such applications are identified Application of the substance / the preparation pigmented highlighter ink Details of the supplier of the safety data sheet Manufacturer/Supplier: DOKUMENTAL GmbH & Co KG Schreibfarben Woellnerstraße 26 D Ludwigshafen Phone + 49 (0)621/ Fax + 49 (0)621/ www. dokumental.de Information department: Technical Service, Dr. B. Polzin Tel.: Mobile bernd.polzin@dokumental.de Emergency telephone number: GBK Gefahrgut Büro GmbH ++49 (0) 6132 / Ingelheim, Deutschland 24-hour-Emergency- Telephone-Number (GBK Contract ID: 94050): (001) Composition/information on ingredients Chemical characterization: Mixtures Mixture of the following substances, containing non-hazardous substances and colouring agents. Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: C.I. Basic Yellow % Additional information: For the wording of the listed risk phrases refer to section 16. * 3 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. Classification system: NFPA ratings (scale 0-4) Health = 0 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 1 Reactivity = 0 4 First aid measures General information: No special measures required. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. (Contd. on page 2)

15 Page 2/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6210 green 300% After swallowing: If symptoms persist consult doctor. (Contd. of page 1) 5 Firefighting measures Suitable extinguishing agents: Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixture No further relevant information available. Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections No dangerous substances are released. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling No special measures required. Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Breathing equipment: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling. * 9 Physical and chemical properties General Information Appearance: Form: Fluid Color: According to product specification Odor: Product specific (Contd. on page 3)

16 Page 3/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6210 green 300% Odour threshold: Not determined. Important information on protection of health and environment, and on safety. - ph-value at 20 C (68 F): 6.5 Change in condition Melting point/melting range: Boiling point/boiling range: Undetermined. 290 C (554 F) Flash point: 160 C (320 F) Flammability (solid, gaseous): Not applicable. Ignition temperature: 400 C (752 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. (Contd. of page 2) Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 0.9 Vol % Upper: Not determined. Vapor pressure at 20 C (68 F): 0.1 hpa Density at 20 C (68 F): 1.08 g/cm³ (9.013 lbs/gal) Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water: Segregation coefficient (n-octonol/water): Not determined. Viscosity: Dynamic at 20 C (68 F): Kinematic: Solvent content: Organic solvents: 13.4 % Water: 0.1 % Not miscible or difficult to mix. 41 mpas Not determined. Solids content: 1.4 % Other information ST: 37mN/m 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Acute toxicity: Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. * 12 Ecological information Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water (Contd. on page 4)

17 Page 4/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6210 green 300% (Contd. of page 3) Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. 13 Disposal considerations Waste treatment methods Recommendation: Smaller quantities can be disposed of with household waste. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - Packaging group: - * 15 Regulatory information Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. (Contd. on page 5)

18 Page 5/5 Printing date 07/07/2011 Reviewed on 07/07/2011 Trade name: PF 6210 green 300% National regulations: Technical instructions (air): Class Share in % NK (Contd. of page 4) Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. * Data compared to the previous version altered.

19 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/5 Printing date Revision: Version number 1 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: PF 6240 pink 300% Registration number The ingredients of this ink have been pre-registered according to 1907/2006/EC (REACH) Relevant identified uses of the substance or mixture and uses advised against Currently no such applications are identified Application of the substance / the preparation pigmented highlighter ink Details of the supplier of the safety data sheet Manufacturer/Supplier: DOKUMENTAL GmbH & Co KG Schreibfarben Woellnerstraße 26 D Ludwigshafen Phone + 49(0)621/ Fax + 49(0)621/ www. dokumental.de Further information obtainable from: Technical Service, Dr. B. Polzin Tel.: Mobile bernd.polzin@dokumental.de Emergency telephone number: GBK Gefahrgut Büro GmbH ++49 (0) 6132 / Ingelheim, Deutschland 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Risk phrases: 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: 60 This material and its container must be disposed of as hazardous waste. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Mixture of the following substances, containing non-hazardous substances and colouring agents. Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: EINECS: C.I. Basic Red 1 Xn R22; Xi R41; N R50/53 Acute Tox. 3, H301; Eye Dam. 1, H318; Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Additional information: For the wording of the listed risk phrases refer to section 16. 1,0% 4 First aid measures Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. (Contd. on page 2) EU

20 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/5 Printing date Revision: Version number 1 Trade name: PF 6240 pink 300% After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. of page 1) 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective clothing. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 3) EU

21 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/5 Printing date Revision: Version number 1 Trade name: PF 6240 pink 300% Eye protection: Goggles recommended during refilling (Contd. of page 2) * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Product specific Odour threshold: Not determined. Important information on protection of health and environment, and on safety. - - ph-value at 20 C: 6,6 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 290 C Flash point: 160 C Flammability (solid, gaseous): Not applicable. Ignition temperature: 400 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: 0,9 Vol % Upper: Not determined. Vapour pressure at 20 C: 0,1 hpa Density at 20 C: 1,08 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Segregation coefficient (n-octanol/water): Not determined. Viscosity: Dynamic at 20 C: Kinematic: Solvent content: Organic solvents: 15,0 % Water: 0,1 % Not miscible or difficult to mix. 37 mpas Not determined. Solids content: 0,8 % Other information ST: 35,1 mn/m 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: C.I. Basic Red 1 Oral LD mg/kg (rat) (Contd. on page 4) EU