: Hard Water Rinse Aid

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Trade name Hard Water Rinse Aid Date of issue: 03/09/2017 Revision date: 03/16/2017 Supersedes: 03/15/2017 Version: 2.1 : Mixtures Product code : Recommended use and restrictions on use Recommended use 1.3. Supplier Synthetic Labs 24 Victory Lane Dracut, MA United States T F info@syntecpro.com Emergency telephone number : Hard Water Rinse Aid : Rinse aid (includes drying aids) Emergency number : SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 1A Serious eye damage/eye irritation Category 1 Causes severe skin burns and eye damage Causes serious eye damage 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS05 : Causes severe skin burns and eye damage Causes serious eye damage : Do not breathe dust/fume/gas/mist/vapors/spray Wash hands, forearms and face thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection If swallowed: rinse mouth. Do NOT induce vomiting If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower If inhaled: Remove person to fresh air and keep comfortable for breathing If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center/doctor/ Specific treatment (see... on this label) Wash contaminated clothing before reuse Store locked up Dispose of contents/container to Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) 03/16/2017 EN (English US) Page 1

2 SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Glycolic Acid (CAS-No.) Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Inhalation:vapour), H331 Skin Corr. 1A, H314 Eye Dam. 1, H318 Ethylene Glycol Monobutyl Ether (CAS-No.) Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 3 (Inhalation:vapour), H331 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact Symptoms/effects after eye contact : Irritation. : Mild eye irritation Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Water spray. Dry powder. Foam. Carbon dioxide Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section /16/2017 EN (English US) 2/7

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool. ACGIH ACGIH TWA (ppm) 20 ppm (2-Butoxyethanol (EGBE); USA; Timeweighted average exposure limit 8 h; TLV - Adopted Value) 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Blue Odor : characteristic Odor threshold ph : 2 ph solution : 2-3 Melting point : Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) :. Vapor pressure Relative vapor density at 20 C 03/16/2017 EN (English US) 3/7

4 Relative density Specific gravity / density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties : 1.05 g/m³ 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat ATE US (oral) ATE US (vapors) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (gases) ATE US (vapors) ATE US (dust, mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity 1950 mg/kg mg/kg body weight mg/l/4h 1746 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) 2.2 mg/l/4h (Rat; Experimental value) 450 ppm/4h (Rat; Experimental value) mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h : Causes severe skin burns and eye damage. ph: 2 : Causes serious eye damage. ph: 2 03/16/2017 EN (English US) 4/7

5 Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/effects after skin contact Symptoms/effects after eye contact SECTION 12: Ecological information Toxicity Ecology - general 3 - Not classifiable : Irritation. : Mild eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. LC50 fish 1 > 5000 mg/l (LC50; 96 h) EC50 Daphnia mg/l (EC50; 48 h) Threshold limit algae 1 44 mg/l (EC50; 72 h) LC50 fish 1 EC50 Daphnia 1 Threshold limit algae 1 Threshold limit algae ppm (LC50; OECD 203: Fish, Acute Toxicity Test; 96 h; Oncorhynchus mykiss; Static system; Fresh water; Experimental value) 1550 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) 911 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella subcapitata; Static system; Fresh water; Experimental value) 88 mg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella subcapitata; Static system; Fresh water; Experimental value) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) ThOD BOD (% of ThOD) 0.28 Readily biodegradable in water. No (test)data on mobility of the components available g O₂/g substance 0.63 g O₂/g substance Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air Bioaccumulative potential Log Pow Bioaccumulative potential Bioaccumulation: not applicable. Log Pow 0.81 (Test data; 20 C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4) Mobility in soil Surface tension N/m (20 C; Calculated value) Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. 03/16/2017 EN (English US) 5/7

6 SECTION 13: Disposal considerations Disposal methods Waste treatment methods SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transportation of Dangerous Goods Transport by sea Not regulated : Dispose of contents/container in accordance with licensed collector s sorting instructions. Air transport Not regulated SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations US State regulations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 03/16/ /16/2017 EN (English US) 6/7

7 Full text of H-phrases: H227 H302 H312 H314 H315 H318 H319 H331 Combustible liquid Harmful if swallowed Harmful in contact with skin Causes severe skin burns and eye damage Causes skin irritation Causes serious eye damage Causes serious eye irritation Toxic if inhaled HMIS III Rating Health Flammability Physical : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 03/16/2017 EN (English US) 7/7