: 2,4,6-Trichlorophenol Standard_

Transcription

1 Date of issue: 04/03/2018 Revision date: : Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code Product group : Mixture : 2,4,6-Trichlorophenol Standard_ : AL : Trade product 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture : Laboratory Use : Industrial For professional use only : Certified reference material for laboratory use only Uses advised against 1.3. Details of the supplier of the safety data sheet Phenova 6390 Joyce Dr. Suite Golden, CO - United States T F info@phenova.com Emergency telephone number Emergency number : ChemTel Assistance (US/Canada) ChemTel Assistance (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Carc. 2 H351 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.3; R40 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) No labeling applicable GHS08 : Warning : H351 - Suspected of causing cancer : P280 - Wear protective gloves/protective clothing/eye protection/face protection P308+P313 - IF exposed or concerned: Get medical advice/attention P403+P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 04/03/2018 EN (English US) 1/8

2 2.3. Other hazards SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Methylene Chloride (Component) 2,4,6-trichlorophenol (Component) (CAS No) (EC-No.) (EC index no) (CAS No) (EC-No.) (EC index no) Carc. 2, H Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Carc. 2, H351 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. : Allow victim to breathe fresh air. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : Take up in absorbent material. Collect spillage Reference to other sections See Heading 8. Exposure controls and personal protection. 04/03/2018 EN (English US) 2/8

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. : Gently wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials 7.3. Specific end use(s) : Keep container closed when not in use. Keep container tightly closed and in a well-ventilated place. Keep away from any flames or sparking source. : Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Belgium Limit value (mg/m³) 177 mg/m³ (Chlorure de méthylène; Belgium; Timeweighted average exposure limit 8 h) Belgium Limit value (ppm) 50 ppm (Chlorure de méthylène; Belgium; Timeweighted average exposure limit 8 h) France VLE (mg/m³) 356 mg/m³ (Dichlorométhane; France; Short time value; VRC: Valeur réglementaire contraignante) France VLE (ppm) 100 ppm (Dichlorométhane; France; Short time value; VRC: Valeur réglementaire contraignante) France VME (mg/m³) 178 mg/m³ (Dichlorométhane; France; Time-weighted average exposure limit 8 h; VRC: Valeur réglementaire contraignante) France VME (ppm) 50 ppm (Dichlorométhane; France; Time-weighted average exposure limit 8 h; VRC: Valeur réglementaire contraignante) Italy - Portugal - USA ACGIH ACGIH TWA (ppm) 50 ppm (Dichloromethane (Methylene chloride); USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) United Kingdom WEL TWA (mg/m³) 350 mg/m³ Dichloromethane; United Kingdom; Timeweighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) United Kingdom WEL TWA (ppm) 100 ppm Dichloromethane; United Kingdom; Timeweighted average exposure limit 8 h; Workplace exposure limit (EH40/2005) United Kingdom WEL STEL (mg/m³) 1060 mg/m³ Dichloromethane; United Kingdom; Short time value; Workplace exposure limit (EH40/2005) United Kingdom WEL STEL (ppm) 300 ppm Dichloromethane; United Kingdom; Short time value; Workplace exposure limit (EH40/2005) 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Either local exhaust or general room ventilation is usually required. : Avoid all unnecessary exposure. Gloves. Protective clothing. Protective goggles. Safety glasses. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear chemically resistant protective gloves. Wear suitable gloves resistant to chemical penetration. : Chemical goggles or safety glasses. Safety glasses. : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin contact. : Wear appropriate mask. : Do not eat, drink or smoke during use. 04/03/2018 EN (English US) 3/8

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor ph Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Relative density Solubility Explosive properties Oxidizing properties Explosion limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Liquid : Colorless. : characteristic. : Non flammable. 2,4,6-trichlorophenol ( ) LD50 oral rat ATE CLP (oral) LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity 820 mg/kg (Rat; Literature study) 820 mg/kg body weight > 2000 mg/kg (Rat; Literature study) > 2000 mg/kg (Rabbit; Literature study) : Suspected of causing cancer. May cause cancer Reproductive toxicity 04/03/2018 EN (English US) 4/8

5 Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms :. SECTION 12: Ecological information Toxicity 2,4,6-trichlorophenol ( ) LC50 fish 1 EC50 Daphnia 2 Threshold limit algae mg/l (LC50; 96 h; Salmo gairdneri) 0.69 mg/l (EC50; 48 h; Daphnia magna) 3.5 mg/l (EC50; 96 h; Selenastrum capricornutum) LC50 fish mg/l (LC50; 96 h; Pimephales promelas) EC50 Daphnia mg/l (EC50; 48 h) Persistence and degradability 2,4,6-Trichlorophenol Standard_ Persistence and degradability 2,4,6-trichlorophenol ( ) Persistence and degradability Persistence and degradability Bioaccumulative potential 2,4,6-Trichlorophenol Standard_ Bioaccumulative potential Not established. Readily biodegradable in water. Readily biodegradable in the soil. No (test)data on mobility of the substance available. Not readily biodegradable in water. Biodegradable in the soil. Not established. 2,4,6-trichlorophenol ( ) BCF fish (BCF; 36 days; Poecilia reticulata) Log Pow (Literature) Bioaccumulative potential High potential for bioaccumulation (BCF > 5000). BCF fish (BCF) Log Pow 1.25 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Surface tension Ecology - soil Results of PBT and vpvb assessment N/m (20 C) May be harmful to plant growth, blooming and fruit formation Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) : 2810 UN-No. (IATA) : /03/2018 EN (English US) 5/8

6 UN-No. (IMDG) : 2810 UN-No. (ADN) : UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IATA) Proper Shipping Name (IMDG) Proper Shipping Name (ADN) Transport document description (ADR) Packing group : TOXIC LIQUID, ORGANIC, N.O.S. : Toxic liquid, organic, n.o.s. : TOXIC LIQUID, ORGANIC, N.O.S. : TOXIC LIQUID, ORGANIC, N.O.S. : UN 2810 TOXIC LIQUID, ORGANIC, N.O.S., 6.1, III, (E) Class (ADR) : 6.1 Classification code (ADR) : T1 Class (IATA) : 6.1 Class (IMDG) : 6.1 Class (ADN) : 6.1 Classification code (ADN) : T1 Hazard labels (ADR) : 6.1 Division (IATA) : 6.1 Hazard labels (IATA) : 6.1 Hazard labels (IMDG) : 6.1 Hazard labels (ADN) : Packing group Packing group (ADR) : III Packing group (IATA) : III Packing group (IMDG) : III Packing group (ADN) : III Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Hazard identification number (Kemler No.) : 60 Classification code (ADR) : T1 Orange plates : Special provision (ADR) : 274, 614 Transport category (ADR) : 2 Tunnel restriction code (ADR) : E Limited quantities (ADR) : 5l 04/03/2018 EN (English US) 6/8

7 Excepted quantities (ADR) EAC APP : E1 : 2X : B Transport by sea Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Properties and observations (IMDG) : Toxic if swallowed, by skin contact or by inhalation Air transport CAO packing instructions (IATA) : 663 CAO max net quantity (IATA) : 220L PCA packing instructions (IATA) : 655 PCA Limited quantities (IATA) : Y642 PCA limited quantity max net quantity (IATA) : 2L PCA max net quantity (IATA) : 60L PCA Excepted quantities (IATA) : E1 Special provision (IATA) : A3, A4, A137 ERG code (IATA) : 6L Inland waterway transport Special provision (ADN) : 274, 614, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 0 Carriage prohibited (ADN) : No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances National regulations Germany Water hazard class (WGK) : 2 - hazardous to water Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/ /03/2018 EN (English US) 7/8

8 Other information : None. PHV SDS EU Copyright 2015 Phenova, Inc. License granted to make paper copies for internal use. The information contained in this is based on our current knowledge. The information contained in this document should be used only as a guide for appropriate safety precautions and should not be considered to be all inclusive. Users should make their own investigation to determine the suitability of the information for their particular purposes. The document does not represent any guarantee of the properties of the product. Phenova, Inc. shall not be held liable for any damage resulting from the handling or use of this product. Visit the Terms and Conditions of Sale link at for additional terms and conditions of sale. 04/03/2018 EN (English US) 8/8