: MS fast adhesive - 290ml - white

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1 Revision date: 9/04/2018 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name : Mixture Product code : MSA 100 : MS fast adhesive - 290ml - white 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet Chemicar Europe NV Baarbeek Zwijndrecht T +32 (0) F +32 (0) info@chemicar.eu 1.4. Emergency telephone number Emergency number : +32 (0) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazardous ingredients EUH-statements Extra phrases : Contains N-(3-(trimethoxysilyl)propyl)ethylenediamine, dioctyltinbis(acetylacetonate), N-[3- (dimethoxymethylsilyl)propyl]ethylenediamine. May produce an allergic reaction. : EUH210 - Safety data sheet available on request. : May produce an allergic reaction. Scandinavian countries regulation Denmark MAL code : Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] trimethoxyvinylsilane (CAS-No.) (EC-No.) Full text of H-statements: see section Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332 11/9/2018 EN (English) 1/6

2 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. : No irritant effect. : Rinse opened eye for several minutes under running water. Then consult doctor. : Call a POISON CENTER/doctor if you feel unwell Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : If there is a fire close by, use suitable extinguishing agents Special hazards arising from the substance or mixture 5.3. Advice for firefighters Precautionary measures fire : Suitable respiratory equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel For emergency responders 6.2. Environmental precautions Prevent entry to sewers and public waters. : Ensure adequate ventilation Methods and material for containment and cleaning up For containment : Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents) Reference to other sections SECTION 7. SECTION 8. SECTION 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Use only in well-ventilated areas Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Hand protection: Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Please follow the instructions related to the permeability and the penetration time provided by the manufacturer Eye protection: Wear security glasses which protect from splashes Respiratory protection: 11/9/2018 EN (English) 2/6

3 In case of inadequate ventilation wear respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point : white. : characteristic. Boiling point : > 34 C Flash point : > 100 C Auto-ignition temperature : 420 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties : Not self-igniting : 1.58 g/m³ Lower explosive limit (LEL) : 0.1 vol % Upper explosive limit (UEL) : 0.2 vol % 9.2. Other information VOC content : 37.9 g/l SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Skin corrosion/irritation 11/9/2018 EN (English) 3/6

4 Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity Persistence and degradability MS fast adhesive - 290ml - white Persistence and degradability Not established Bioaccumulative potential MS fast adhesive - 290ml - white Bioaccumulative potential No bioaccumulation data available Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods European List of Waste (LoW) code SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN : * - waste adhesives and sealants containing organic solvents or other dangerous substances ADR IMDG IATA ADN UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available 11/9/2018 EN (English) 4/6

5 14.6. Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 37.9 g/l National regulations Germany Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands Waterbezwaarlijkheid Saneringsinspanningen SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling : 10 - Weinig schadelijk voor in het water levende organismen; kan in het aquatisch milieu op lange termijn schadelijke effecten veroorzaken. : A - In principe niet lozen; zo ja, dan toepassen van beste bestaande technieken Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 H226 H332 H400 H410 EUH210 Flammable liquid and vapour. Harmful if inhaled. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Safety data sheet available on request. 11/9/2018 EN (English) 5/6

6 SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 11/9/2018 EN (English) 6/6