Manganese 13% EDTA. Ethylenediaminetetraacetic acid, manganese disodium complex

Transcription

1 Safety Data Sheet SECTION 1. IDENTIFICATION Product Identifier Other Means of Identification Product Family Recommended Use Restrictions on Use Supplier Emergency Phone No. SDS No. Not classified under any GHS hazard classes. GHS Label Elements Ethylenediaminetetraacetic acid, manganese disodium complex Greenhouse Micronutrient Micronutrient fertilizer chelating agent.. TerraLink Horticulture Inc., 464 Riverside Road, Abbotsford, BC, V2S 7M1, CANUTEC, In the event of an emergency involving dangerous goods, call or *666 on a cellular phone SECTION 2. HAZARDS IDENTIFICATION GHS Classification Other Hazards SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. % Other Identifiers Manganate(2-), ((N,N'-1, 2-ethanediylbis(N-(carboxymethyl)glycinato))(4-)- N,N',O,O',ON,ON')-, disodium, (OC-6-21) Trisodium nitrilotriacetate Nitrilotriacetic acid SECTION 4. FIRST-AID MEASURES First-aid Measures Skin Contact Rinse with lukewarm, gently flowing water for 5 minutes. Clean clothing, shoes and leather goods. Get medical advice/attention if you feel unwell or are concerned. Eye Contact Rinse the contaminated eye(s) with lukewarm, gently flowing water for at least 15 minutes. If wearing contact lens(es), remove after 5 minutes and continue rinsing for at least 10 minutes. Ingestion Rinse mouth with water. Get medical advice/attention if you feel unwell or are concerned. First-aid Comments Get medical advice/attention if you feel unwell or are concerned. Product Identifier: Page 01 of 06

2 Most Important Symptoms and Effects, Acute and Delayed Immediate Medical Attention and Special Treatment Target Organs Special Instructions. Medical Conditions Aggravated by Exposure Skeletal conditions. SECTION 5. FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media Water, Fog, Foam, Dry Chemical, CO2. Unsuitable Extinguishing Media Specific Hazards Arising from the Chemical This product presents no unusual hazards in a fire situation. Nitrous gases may be produced. Special Protective Equipment and Precautions for Fire-fighters Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Fire-fighters should wear appropriate protective equipment and self contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures See Section 8. Environmental Precautions Avoid run off into streams, sewers and ditches that leads to waterways. Methods and Materials for Containment and Cleaning Up Prevent product from leaking into the environment. Flush spill area with water. Absorb the remainder with vermiculite or similar material. Other Information No other information was found. SECTION 7. HANDLING AND STORAGE Precautions for Safe Handling Avoid dust generation. Conditions for Safe Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION No information available. Consult local authorities for provincial exposure limits. Appropriate Engineering Controls General ventilation is usually adequate. Use local exhaust ventilation, if general ventilation is not adequate to control amount in the air. Product Identifier: Page 02 of 06

3 amount in the air. Individual Protection Measures Eye/Face Protection Not required but it is good practice to wear safety glasses or chemical safety goggles. Skin Protection Skin contact should be prevented through the use of suitable protective clothing, gloves and footwear, selected for conditions of use and exposure potential. Consideration must be given both to durability as well as permeation resistance. Respiratory Protection Not normally required if product is used as directed. In case of dust formation use dust mask. Dust exposure limits have to be respected. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Basic Physical and Chemical Properties Appearance Cloudy white crystalline powder. Odour Odourless Odour Threshold ph 6-7 (1% solution) Melting Point/Freezing Point (melting); (freezing) Initial Boiling Point/Range Flash Point Evaporation Rate Flammability (solid, gas) Upper/Lower Flammability or (upper); (lower) Explosive Limit Vapour Pressure Vapour Density (air = 1) Relative Density (water = 1) Solubility ~ 800 g/l in water; Not available (in other liquids) Partition Coefficient, Not available n-octanol/water (Log Kow) Auto-ignition Temperature Decomposition Temperature Viscosity Other Information Physical State Bulk Density Chemical Stability ~ 200 ºC (392 ºF) (kinematic); (dynamic) Solid kg/m3 (37-50 lb/ft3) SECTION 10. STABILITY AND REACTIVITY Reactivity Normally stable under recommended storage and handling conditions (see Section 7). Possibility of Hazardous Reactions Conditions to Avoid Product layer on hot surface might cause glowing or autoignition. Incompatible Materials Product Identifier: Page 03 of 06

4 SECTION 11. TOXICOLOGICAL INFORMATION Likely Routes of Exposure Inhalation; skin contact; eye contact. Acute Toxicity LC50: LD50 (oral): LD50 (dermal): Skin Corrosion/Irritation Not a skin irritant. Serious Eye Damage/Irritation Human experience shows very mild irritation. STOT (Specific Target Organ Toxicity) - Single Exposure Inhalation May be harmful Skin Absorption Not expected to be absorbed. Ingestion Not expected to be ingested. Aspiration Hazard Not known to be an aspiration hazard. STOT (Specific Target Organ Toxicity) - Repeated Exposure Respiratory and/or Skin Sensitization Not a respiratory sensitizer. Skin: Not sensitizing. Carcinogenicity Not known to cause cancer. Reproductive Toxicity Development of Offspring Sexual Function and Fertility Effects on or via Lactation Germ Cell Mutagenicity Not mutagenic. Interactive Effects SECTION 12. ECOLOGICAL INFORMATION Toxicity No experimental ecological data are available on the substances as such. Acute Aquatic Toxicity Chemical Name LC50 Fish EC50 Crustacea ErC50 Aquatic Plants ErC50 Algae Persistence Product Identifier: and Degradability Page 04 of 06

5 Manganate(2-), ((N,N'-1, mg/l 2-ethanediylbis(N- (Pimephales (carboxymethyl)glycinato)) promelas (fathead (4-)-N,N',O,O',ON,ON')-, minnow); 96-hour) disodium, (OC-6-21)- Persistence and Degradability No ingredient of this product or its degradation products is known to be highly persistent. Mobility in Soil Other Adverse Effects There is no information available. SECTION 13. DISPOSAL CONSIDERATIONS Disposal Methods mg/l (Daphnia magna (water flea); 48-hour) Dispose of according to local, provincial and federal government requirements. SECTION 14. TRANSPORT INFORMATION Not regulated under Canadian TDG regulations. Special Precautions for Transport User in Bulk According to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. REGULATORY INFORMATION Safety, Health and Environmental Regulations Canada Domestic Substances List (DSL) / Non-Domestic Substances List (NDSL) Not specifically listed. CEPA - National Pollutant Release Inventory (NPRI) Not specifically listed. USA Toxic Substances Control Act (TSCA) Section 8(b) Not specifically listed. SECTION 16. OTHER INFORMATION NFPA Rating SDS Prepared By Health - 0 Flammability - 0 Instability - 0 Regulatory and Technical Resources mg/l (Algae - Microcystis aerunginosa; 96-hour) Phone No Date of Preparation March 15, 2016 Key to Abbreviations ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association HSDB = Hazardous Substances Data Bank IARC = International Agency for Research on Cancer NFPA = National Fire Prevention Association NIOSH = National Institute for Occupational Safety and Health NTP = National Toxicology Program OSHA = US Occupational Safety and Health Administration RTECS = Registry of Toxic Effects of Chemical Substances References CHEMINFO database. Canadian Centre for Occupational Health and Safety (CCOHS). Supplier's Material Safety Data Sheet. Disclaimer Terralink Horticulture Inc. provides the information contained herein in good faith, but makes no Product Identifier: Page 05 of 06

6 Disclaimer Terralink Horticulture Inc. provides the information contained herein in good faith, but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. TERRALINK HORTICULTURE INC. MAKES NO REPRESENTATIONS OR WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, TERRALINK HORTICULTURE INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM THE USE OF OR RELIANCE UPON THIS INFORMATION. Product Identifier: Page 06 of 06