Issue Date 23-May-2014 Revision Date 01-Jan-2016 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Transcription

1 SAFETY DATA SHEET Issue Date 23-May-2014 Version 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name CITRAZOV POWDER WITH DE-ZOV-ALL Other means of identification Product Code 8089 Synonyms ne Recommended use of the chemical and restrictions on use Recommended Use Powder Carpet Pre-Spray Uses advised against Details of the supplier of the safety data sheet Manufacturer Address Harvard Chemical Research, Inc., 3595 Zip Industrial Blvd., Atlanta, GA Emergency telephone number Company Phone Number Hour Emergency Phone Number Emergency Telephone Chemtrec Classification 2. HAZARDS IDENTIFICATION OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR ) Serious eye damage/eye irritation Category 2 Label elements Warning Emergency Overview Hazard statements Causes serious eye irritation Page 1 / 7

2 Appearance White Powder Physical state Granular Odor Citrus Hazards not otherwise classified (HNOC) Other Information May be harmful if swallowed Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS. Weight-% Trade Secret Sodium Carbonate <20 * First aid measures *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Eye contact Skin Contact Inhalation Ingestion Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Rinse with clear water. Remove to fresh air. If breathing does not return to normal, seek medical attention. Immediately drink large quantities of water. Get medical attention. Most important symptoms and effects, both acute and delayed Symptoms. Indication of any immediate medical attention and special treatment needed te to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical. Page 2 / 7

3 Explosion data Sensitivity to Mechanical Impact ne. Sensitivity to Static Discharge ne. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Methods for cleaning up Prevent further leakage or spillage if safe to do so. Shovel up into open head drum. Ph adjust and dispose in accordance with federal and state regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible materials Keep container tightly closed in a dry and well-ventilated place. Keep out of reach of children. Do not freeze. Follow label instructions. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Skin and body protection Tight sealing safety goggles. Wear Neoprene or protective rubber gloves. Drenching safety shower and eye wash station. Page 3 / 7

4 Respiratory protection General Hygiene Considerations If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Granular Appearance White Powder Odor Citrus Color White Odor threshold Property Values Remarks Method ph 12 (2oz per gallon dilution) Melting point/freezing point Boiling point / boiling range Flash point Evaporation rate NA Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure NA Vapor density Specific Gravity 0.12 Water solubility completely soluble Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity Explosive properties Oxidizing properties Other Information Softening point Molecular weight VOC Content (%) Density 1.0 Bulk density Reactivity data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions ne under normal processing. 10. STABILITY AND REACTIVITY Hazardous polymerization Hazardous polymerization does not occur. Page 4 / 7

5 Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Strong acids. Hazardous Decomposition Products Carbon dioxide (CO2). Carbon monoxide. heat. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye contact Skin Contact Ingestion data available Causes irritation of respiratory tract and mucous membranes. Severely irritating to eyes. data available. Gastric pain and vomiting. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium Carbonate = 4090 mg/kg ( Rat ) - = 2300 mg/m 3 ( Rat ) 2 h Information on toxicological effects Symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Numerical measures of toxicity - Product Information Unknown Acute Toxicity The following values are calculated based on chapter 3.1 of the GHS document. Ecotoxicity 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Crustacea Sodium Carbonate : 120 h Nitzschia mg/l EC50 300: 96 h Lepomis macrochirus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 static 265: 48 h Daphnia magna mg/l EC50 Page 5 / 7

6 Persistence and degradability. Bioaccumulation. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Do not reuse container. Chemical Name Sodium Carbonate California Hazardous Waste Status Corrosive 14. TRANSPORT INFORMATION DOT t regulated International Inventories TSCA DSL/NDSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS 15. REGULATORY INFORMATION Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of tified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances Page 6 / 7

7 US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide Registration Number t Applicable 16. OTHER INFORMATION NFPA Health hazards 0 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 1 Flammability 0 Physical hazards 1 Personal protection X Prepared By Moira Blackflower Issue Date 23-May-2014 Revision Date 01-Jan-2016 Revision te Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7