Version: 3.1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 3.1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Product Name: Laropal A 81 Page Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coating raw material for industrial purposes Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Composition/Information on Ingredients 2

2 Substance Mixture Page 2 Chemical Characterization: Urea Aldehyde resin Hazardous Ingredients: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air. Consult physician if symptoms persist. Wash off with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Symptomatic treatment (decontamination, vital functions), no specific antidote known. Extingishing powder, foam Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Carbon dioxide (CO2) Special hazards: Advice for Firefighters Protective equipment: In case of fire: hazardous vapors may be released. Development of fumes/aerosol. Wear self-contained respiratory protective device. Further information: 3

3 Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Page 3 Contaminated extinguishing water and debris should be disposed of according to local regulations. Avoid formation of dust: risk of dust explosion Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Keep spills and cleaning runoff out of municipal sewers and open bodies of water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Small spills: Clean up with suitable appliance and dispose adequately. Large spills: Contain with dust binding material and dispose accordingly. Avoid dust formation. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Respiratory protection when handling without exhaust system Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Store in tightly sealed containers in a dry and cool room. Requirements for storage areas and containers: Information on fire and explosion protection: Avoid dust formation. Take measures to prevent static electricity discharge. Storage class (VCI): Further Information: Specific End Use(s) Further information: 8. Exposure Controls/Personal Protection 4

4 8. 1. Parameters to be Controlled Page 4 Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: The usual precautionary measures are to be adhered to when handling chemicals. Suitable respiratory protection for lower concentration or shortterm effect: particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149, type P2 or FFP2). Chemical protective gloves (EN 374 (Europe), F739 (US)). The manufacturer s directions for use should be observed because of the great diversity of types. Recommended: Protective index 6, > 480 min. of permeation time accord. EN 374. Nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinyl chloride (0.7 mm). Safety glasses with protective shields (EN 166). Apron Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: pastilles bright yellow weak, characteristic ph-value: 5

5 Page 5 Melting temperature: C Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: This product is a non-volatile solid. not easily flammable no information available no information available This product is a non-volatile solid. 1.1 g/cm3 (20 C) insoluble Product is not auto-ignitable. Decomposition temperature: 190 C Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Product does not present an explosion hazard. not oxidizing kg/m3 Solid content: 6

6 Particle size: Page Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: No further information. Stable if used according to specifications. Stable if used according to specifications. None if handled and stored according to specifications. Avoid formation of dust. Strong acids. Oxidizing agents. None if stored and handled according to specifications. > 5000 mg/kg (rat) Not toxic after single oral exposure. Non irritating (rabbit) Non-irritating to eyes (rabbit) No information available Sensitization: No sensitizing effects known. 7

7 Mutagenicity: No mutagenic effects known. Page Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects No negative effects known. No cancerogenic effect known. Single exposure: no organospecific toxicity expected. Repeated exposure: no organospecific toxicity expected. Aspiration hazard: not determined EC50: > 100 mg/l (48h, Daphnia magna; OECD 202) Nominal concentration. Product is only slightly soluble in the test medium. An eluate was tested. No toxic effects in the range of solubility. not determined not determined The product in virtually insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plants. Bioaccumulation is not to be expected. Does not evaporate from the surface of the water to the atmosphere. According to Annex VIII to Regulation (EC) No. 1907/2006 (REACH): this product is neither a PBT (persistent/bioaccumulative/toxic) or vpvb (very persistent/very bioaccumulative/very toxic) substance nor does it contain a PBT or vpvb substance. Water hazard class: 1, slightly hazardous 8

8 Behaviour in sewage systems: Page 8 Further ecological effects: Due to the consistency of the product, it is not classified as environmentally hazardous AOX Value: Disposal Considerations Waste Treatment Methods Product: In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. European Waste Code (EWC): Uncleaned packaging: Uncontaminated packaging may be recycled. Packaging may be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. ADR/RID: 9

9 IMDG: Page IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not yet been carried out for this product. Regulation (EC) 1005/ Substances that Deplete the Ozone Layer: not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.